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1. 发明申请

WO1997032840A1 PROCESS FOR PREPARING AMINES BY SIMULTANEOUS HYDROFORMYLATION AND HYDROGENATING AMINATION 审中-公开
标题翻译：用于生产AMINES法同步氢甲酰化和氢化胺
公开(公告)号：WO1997032840A1
公开(公告)日：1997-09-12
申请号：PCT/EP1997001080
申请日：1997-03-04
申请人： BASF AKTIENGESELLSCHAFT , KNEUPER, Heinz-Josef , KORMANN, Claudius , RÖPER, Michael
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C209/60
CPC分类号： B01J31/04 , B01J27/10 , B01J31/20 , B01J31/2234 , B01J31/2291 , B01J31/4046 , B01J37/342 , B01J38/00 , B01J2231/321 , B01J2231/346 , B01J2531/822 , B03C1/01 , C07C209/26 , Y02P20/584
摘要： The invention concerns a process for preparing amines having more than four carbon atoms by simultaneous hydroformylation and hydrogenating amination of corresponding olefins containing one carbon atom less in the presence of at least equivalent amounts of ammonia or a low-molecular amine or polyamine with at least one primary or secondary amino group by means of an unmodified rhodium catalyst dissolved homogeneously in the reaction medium at high pressure and high temperature. The rhodium catalyst is separated out of the liquid reaction mixture by separating the homogeneously dissolved unmodified rhodium catalyst from the reaction medium by means of a magnetizable inorganic pigment which is suitable for the complex or adsorptive bonding of rhodium and is uncoated or coated with a binder. This pigment is separated from the liquid reaction medium after it has been charged with the rhodium present in the reaction medium by the application of an external magnetic field.
摘要翻译：一种制备胺与通过同时加氢甲酰化和相应的一个碳原子少含有烯烃在至少等量的氨或低分子量的胺或多胺的具有至少一个伯或仲氨基基团的存在下的均匀溶解在反应介质中的装置“的氢化胺化超过4个碳原子的过程裸“铑催化剂在升高的压力下和在升高的温度和通过分离均匀溶解的铑催化剂从液体反应混合物的分离”从反应介质裸“Rhodiumdatalysators通过络合或吸附一个合格的手段铑未涂覆或涂覆有粘合剂，可磁化的结合，无机颜料和通过从与包含在铑反应介质装载该液体反应介质此颜料的沉积通过将A A OUTER磁场。

2. 发明申请

WO1996016012A2 ALDEHYDE PREPARATION PROCESS 审中-公开
标题翻译：用于生产醛
公开(公告)号：WO1996016012A2
公开(公告)日：1996-05-30
申请号：PCT/EP1995004506
申请日：1995-11-16
申请人： BASF AKTIENGESELLSCHAFT , KORMANN, Claudius , KNEUPER, Heinz-Josef
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C45/50
CPC分类号： B01J31/1658 , B01J27/25 , B01J31/20 , B01J31/2234 , B01J31/4046 , B01J37/342 , B01J38/00 , B01J2231/321 , B01J2531/822 , C07C27/08 , C07C45/50 , C11D3/2072 , Y02P20/584 , C07C47/02
摘要： A process is disclosed for preparing aldehydes and/or alcohols by hydroformylating olefins with more than 3 carbon atoms with a "naked" rhodium catalyst homogeneously dissolved in the reaction medium at an increased pressure and temperature, then by removing the rhodium catalyst from the liquid reaction mixture. A magnetisable inorganic pigment coated with a polymer binder is used to remove the "naked" rhodium catalyst homogeneously dissolved in the hydroformylation medium. After said pigment absorbs the rhodium contained in the hydroformylation medium, it is eliminated from the liquid hydroformylation medium by exposure to an outer magnetic field.
摘要翻译：一种制备醛和/或醇的由具有3个以上碳原子的烯烃的加氢甲酰化通过均匀溶解在反应介质中的“裸”铑在升高的压力催化剂的装置和在升高的温度和从液体反应混合物中的铑催化剂中分离，其中一个分离过程均匀溶解，“裸露的”铑从加氢甲酰化介质的催化剂使用了涂覆有聚合物粘合剂，可磁化，无机颜料，并通过从该液体加氢甲酰化介质施加外部磁场铑所包含的在加氢甲酰化介质的装入之后该颜料分离。

3. 发明申请

WO1997028113A1 PROCESS FOR PRODUCING ALDEHYDES BY HYDROFORMYLATION OF OLEFINS 审中-公开
标题翻译：用于生产烯烃的醛通过氢甲酰化
公开(公告)号：WO1997028113A1
公开(公告)日：1997-08-07
申请号：PCT/EP1997000372
申请日：1997-01-28
申请人： BASF AKTIENGESELLSCHAFT , PACIELLO, Rocco , KNEUPER, Heinz-Josef , GEISSLER, Bernhard , RÖPER, Michael
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C45/50
CPC分类号： C07C45/80 , B01J31/1658 , B01J31/1815 , B01J31/4046 , B01J2231/321 , B01J2531/822 , C07C29/16 , C07C45/50 , Y02P20/584 , C07C47/02 , C07C31/125
摘要： A process is proposed for producing aldehydes and alcohols by hydroformylation of olefins with more than three carbon atoms. The process involves a hydroformylation stage, in which the olefin is hydroformylated at a pressure of 50-1000 bar and a temperature of 50-180 DEG C with the aid of a rhodium catalyst dissolved in an homogeneous reaction medium, and a catalyst recovery stage, in which the rhodium catalyst is extracted. The process involves the following steps: (a) hydroformylation carried out in the presence of a rhodium complex containing a ligand in the form of a phosphorous-free multidentate organic nitrogen compound capable of forming complexes with group VIII metals, said nitrogen compound containing in addition at least one tertiary nitrogen rest which can be protonated with a weak acid; (b) extraction of the product from the hydroformylation stage, where appropriate after separation or partial separation of the aldehydes and alcohols, using an aqueous solution of a distillable acid; (c) heat treatment of the aqueous acid extract in the presence of an organic solvent or solvent mixture which is inert under the hydroformylation conditions, the aqueous acid being distilled off, in order to de-protonate the complex and convert it to the organic phase; and (d) recycling of the organic phase containing the catalyst complex into the hydroformylation stage.
摘要翻译：一种用于通过具有多于3个碳原子，在包含加氢甲酰化阶段，在其中所述烯烃从50至1000巴，50〜180℃的温度下的烯烃的加氢甲酰化制备醛或醛和醇的过程中，通过溶解在均相反应介质中的铑催化剂的方法进行加氢甲酰化，使能和催化剂回收步骤由铑催化剂，它包括进行（a）在铑配合物的无磷的，多齿的配位体的存在下加氢甲酰化，以形成与元素周期表中的第VIII族金属络合物，其特征在于有机氮化合物，其附加的至少一种的提取，包含由弱酸质子化的叔氮部分，（b）该加氢甲酰化阶段的排出，如果需要除去或部分除去醛和醇，之后用destinination的水溶液进行萃取 llierbaren酸受试者中，（C）在有机溶剂或溶剂混合物，其是在加氢甲酰化条件下呈惰性的存在含水酸提取物，与由酸的水溶液通过该复合物去质子化，并转移到organishce相热处理的蒸馏去除，受试者和（d ）回收有机含有催化剂配合物加氢甲酰化阶段。

4. 发明申请

WO1997023586A1 FUEL OR LUBRICANT COMPOSITIONS CONTAINING SECONDARY POLYISOBUTENE AMINES 审中-公开
标题翻译： SECONDARY Polyisobuteneamines含燃料或润滑剂组合物
公开(公告)号：WO1997023586A1
公开(公告)日：1997-07-03
申请号：PCT/EP1996005635
申请日：1996-12-16
申请人： BASF AKTIENGESELLSCHAFT , RÖPER, Michael , GEISSLER, Bernhard , LANGGUTH, Ernst , KNEUPER, Heinz-Josef
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C10M133/54
CPC分类号： C10M133/54 , C08F8/32 , C10L1/2222 , C10L1/2383 , C10L10/00 , C10L10/06 , C10M133/06 , C10M2215/04 , C10M2215/26 , C08F110/10
摘要： Disclosed are fuel or lubricant compositions containing polyisobutene amines and containing specifically at least one secondary polyisobutene amine of formula (I) in which R represents a polyisobutene group with 6-45 isobutylene units at least 20 % of which can be replaced with n-butylene units. The quantity of secondary polyisobutene amine must be greater than the quantity of any primary or tertiary polyisobutene amine which may be present.
摘要翻译：含燃料或含有式（I）其中R是基团具有6至45异丁烯单元的聚异丁烯中的至少一个次级polyisobutenamine润滑剂组合物Polyisobuteneamines，可以通过正 - 丁烯单元被替换以异丁烯单元的20％，条件是次级聚异丁烯胺的量是大于相应的一级或三级polyisobuteneamine的量任选地还含有。

5. 发明申请

WO1995025080A1 PROCESS FOR PRODUCING ALCOHOLS AND/OR ALDEHYDES 审中-公开
标题翻译：用于生产醇类和/或醛
公开(公告)号：WO1995025080A1
公开(公告)日：1995-09-21
申请号：PCT/EP1995000825
申请日：1995-03-06
申请人： BASF AKTIENGESELLSCHAFT , KNEUPER, Heinz-Josef , ARON, Maik , KORGITZSCH, Frank-Michael , NILLES, Michael , HARDER, Wolfgang , RÖPER, Michael , PACIELLO, Rocco
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C45/50
CPC分类号： B01J31/20 , B01J23/464 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/183 , B01J31/4046 , B01J2231/321 , B01J2531/822 , C07C29/141 , C07C29/16 , C07C45/50 , C07C45/80 , C07C51/235 , C07C209/00 , Y02P20/584 , C07C31/125 , C07C47/02
摘要： A process for producing aldehydes by the hydroformylation of olefins with more than 3 carbon atoms, comprising the hydroformylation stage by means of a rhodium catalyst uniformly dissolved in the reaction medium, the separation of the rhodium catalyst from the product from the hydroformylation reaction and its return to the hydroformylation stage, in which the rhodium catalyst is extracted into the aqueous phase by means of an aqueous solution of a nitrogen-containing complexing agent from the group of sulphonated pyridines, sulphonated quinolines, possibly substituted sulphonated or sulphonated component-containing 2,2' bipyridines, 1,10 phenanthrolines, 1,1' biquinolines, 2,2', 6', 2'' terpyridines and porphines, and/or from the group of carboxylated pyridines, carboxylated quinolines, possibly substituted, carboxylated or carboxylated substance-containing 2,2' bipyridines, 1,10 phenanthrolines, 2,2' biquinolines, 2,2', 6', 2'' terpyridines and porphines, and the alcohol and/or aldehyde is isolated and from the extracted hydroformylation product, the aqueous rodhium-containing extract is taken to a pre-carbonylation stage and subjected to a pre-carbonylation in said stage in the presence of a substantially water-soluble organic fluid and in the presence of carbon monoxide, synthesis gas or a carbon monoxide-containing gas mixture at a pressure of 50 to 100 bars and a temperature of 50 to 180 DEG C, the product from the pre-carbonylation stage is separated into an organic part containing the majority of the rhodium and an aqueous phase containing the complexing agents and the organic phase for the hydroformylation of the olefin is taken to the hydroformylation stage at 50 to 100 bars and a temperature of 50 to 180 DEG C.
摘要翻译：一种用于通过具有多于3个碳原子，包括加氢甲酰化的阶段通过一均匀溶解在反应介质中的铑催化剂装置的烯烃的加氢甲酰化制备醛的方法中，铑催化剂的从加氢甲酰化反应中的分离和从羰基化的铑在分离回收加氢甲酰化，其特征在于，由含氮络合剂选自磺化吡啶的，磺化的喹啉，未取代的水溶液来磺化来自加氢甲酰化的铑催化剂或取代的或磺化的取代基的苯基2,2'-联吡啶，1 ，10-菲咯啉，2,2'- biquinolines，2,2”，6' ，2‘’ - 三联吡啶和卟吩，和/或选自羧化吡啶，羧化喹啉，未取代的或取代的，羧化或羧化substit- uenten支撑2,2'-联吡啶，1,10-菲咯啉，2,2'- biquinolines，2,2”，6' ，2‘’ - 三联吡啶和卟吩，萃取到水相并从所提取的加氢甲酰化，以醇和/或醛中分离，进给precarbonylation阶段的水性含铑提取物和它在precarbonylation阶段在50压杆在基本上不溶于水的有机液体的存在下，在一氧化碳，合成气体或含一氧化碳的气体混合物的存在下1000和一个温度从50至180℃的precarbonylation受试者，在含有铑的有机相的主要部分和一个配位剂含有水相和有机相，烯烃的加氢甲酰化在50至1000巴和温度分离从precarbonylation阶段放电 50〜180℃下加氢甲酰化饲料。

6. 发明申请

WO1997030016A1 METHOD OF PREPARING ALDEHYDES BY HYDROFORMYLATION WITH A RHODIUM CATALYST AND RECOVERY OF THE RHODIUM CATALYST BY EXTRACTION 审中-公开
标题翻译：用于生产醛通过氢甲酰化与提取铑催化剂和恢复铑
公开(公告)号：WO1997030016A1
公开(公告)日：1997-08-21
申请号：PCT/EP1997000635
申请日：1997-02-12
申请人： BASF AKTIENGESELLSCHAFT , GEISSLER, Bernhard , KNEUPER, Heinz-Josef , RÖPER, Michael , PACIELLO, Rocco , OPPENLÄNDER, Knut , GÜNTHER, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C45/50
CPC分类号： B01J31/20 , B01J31/1658 , B01J31/4046 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07F9/3817 , C08G73/0206 , Y02P20/584 , C07C47/02
摘要： Described is a method of preparing aldehydes, or aldehydes and alcohols, by the hydroformylation of olefins with more than three carbon atoms, the method including a hydroformylation stage in which the olefin is hydroformylated at a pressure of 50 to 1,000 bar and a temperature of 50 to 180 DEG C by means of a rhodium catalyst dissolved in a homogeneous reaction medium and a catalyst-recovery stage in which the rhodium catalyst is extracted using an aqueous solution of a complexing agent, the alcohol and/or alkdehyde is isolated from the extracted hydroformylation products, the aqueous rhodium-containing extract is carbonylated in the presence of carbon monoxide, synthesis gas or a gas mixture containing carbon monoxide at a pressure of 50 to 1,000 bar and a temperature of 50 to 180 DEG C, the carbonylation products separated into an organic phase containing most of the rhodium and an aqueous phase containing the complexing agent and the organic phase is fed back to the hydroformylation stage, the rhodium catalyst obtained from the products of the hydroformylation stage being extracted with an aqueous solution of a water-soluble polymer, without any sulphonic acid groups, capable of forming a complex with rhodium.
摘要翻译：一种用于通过具有多于3个碳原子，包括加氢甲酰化步骤的烯烃的加氢甲酰化制备醛或醛和醇的方法，其中一个接的溶解在均相反应介质中的铑催化剂装置，在50至1000巴的烯烃和50至180℃的温度下加氢甲酰化和催化剂回收步骤由铑催化剂的提取与络合剂的水溶液，从所提取的加氢甲酰化产物的醇和/或醛的分离，在50至1000的压力含有一氧化碳，合成气或一氧化碳气体混合物的存在下在水含铑提取物precarbonylation 巴和温度为50〜180℃时，precarbonylation的排出分离成铑的有机相的含主要部分和含有配位剂和再循环的水相有机相萃取到加氢甲酰化阶段，其中，所述铑催化剂是从加氢甲酰化的放电能力，具有sulfonsäuregruppenfreien的水溶液，对铑的水溶性聚合物的螯合。

7. 发明申请

WO1995000525A1 PHOSPHOROUS-CONTAINING CALIXARENES 审中-公开
标题翻译：含磷杯芳烃
公开(公告)号：WO1995000525A1
公开(公告)日：1995-01-05
申请号：PCT/EP1994001999
申请日：1994-06-20
申请人： BASF AKTIENGESELLSCHAFT , PACIELLO, Rocco , RÖPER, Michael , KNEUPER, Heinz-Josef , LANGGUTH, Ernst , LORZ, Peter, Michael
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07F09/6571
CPC分类号： B01J31/066 , B01J31/1683 , B01J31/185 , B01J31/1865 , B01J2531/821 , B01J2531/822 , C07C45/50 , C07F9/6571 , C07F9/65719 , C07F9/65746 , C07F15/008 , C07C47/02
摘要： Phosphorous-containing calixarenes having the general formula (I) are disclosed, as well as a process for preparing the same and a process for preparing aldehydes by hydroformylating C3-C20 olefins by means of rhodium/carbonyl ruthenium/carbonyl complexes, in which the phosphorous-containing calixarenes having the formula (I) are used as ligands.
摘要翻译：含磷的通式（I）和它们的制备方法和一种用于制备醛的由C3-C20烯烃的加氢甲酰化由铑或钌羰基配合物的装置的杯芳烃，其中式（I）的配体的含磷杯芳烃可以使用。

8. 发明申请

WO1996006891A1 HIGH PURITY FERROMAGNETIC IRON OXIDE PIGMENTS 审中-公开
标题翻译：高纯度铁磁氧化铁颜料
公开(公告)号：WO1996006891A1
公开(公告)日：1996-03-07
申请号：PCT/EP1995003230
申请日：1995-08-16
申请人： BASF AKTIENGESELLSCHAFT , KORMANN, Claudius , SCHWAB, Ekkehard , SCHLEGEL, Reinhold
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C09C01/24
CPC分类号： G01R33/5601 , A61K49/1818 , B82Y5/00 , B82Y30/00 , C01G49/06 , C01G49/08 , C01P2004/64 , C01P2006/42 , C01P2006/80 , C09D17/007 , G11B5/70652 , G11B5/70684 , G11B5/70689
摘要： gamma -Fe2O3 pigments and Fe3O4 pigments have particles of 2 to 200 nm diameter, more than 40 nTm /g saturation magnetisation, less than 10 nTm /g remanence, a Cr content below 40 mg/kg pigment, a Cu content below 40 mg/kg pigment and a C content below 100 mg/kg pigment. Also disclosed is an aqueous suspension of said pigments. These pigments are used in aqueous suspension in the medical field, in particular as contrasting agents in nuclear magnetic resonance tomography.
摘要翻译：伽马-Fe2O3颜料和具有2粒径为100nm时，饱和磁化强度高于40 NTM <3> /克，低于10 NTM <3> / g的剩磁的Fe3O4颜料，Cr含量低于40mg / kg的颜料中，Cu含量低于40mg / kg的颜料和低于100毫克/公斤颜料和水性悬浮液的C含量，所述的颜料。将颜料在水性悬浮液中使用在医疗领域中，特别是作为在磁共振成像中的造影剂。

9. 发明申请

WO1995013874A1 MAGNETICALLY SEPARABLE CATALYSTS 审中-公开
标题翻译：磁性分割的催化剂
公开(公告)号：WO1995013874A1
公开(公告)日：1995-05-26
申请号：PCT/EP1994003747
申请日：1994-11-11
申请人： BASF AKTIENGESELLSCHAFT , KORMANN, Claudius , WETTLING, Thomas , SCHWAB, Ekkehard , HENKELMANN, Jochem
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： B01J35/00
CPC分类号： C07D301/00 , B01J35/0033 , B01J37/0221 , C07B35/02
摘要： Disclosed are catalysts based on: a) a magnetizable core which, b) can as needed be coated with a binder, and c) carries on its surface catalytically active metals or metallic compounds.
摘要翻译：催化剂，的组成）可磁化芯，B），其任选地涂覆有粘合剂，以及c）在其表面承载的催化活性金属或金属化合物。

10. 发明申请

WO1997007058A1 HYDROLYTIC PREPARATION OF TITANIUM DIOXIDE PIGMENTS 审中-公开
标题翻译：二氧化钛颜料的水解产物
公开(公告)号：WO1997007058A1
公开(公告)日：1997-02-27
申请号：PCT/EP1996003504
申请日：1996-08-08
申请人： BASF AKTIENGESELLSCHAFT , JACHOW, Harald , SCHWAB, Ekkehard , KORMANN, Claudius , DAUSCH, Wilma , SPERLING, Karin , WESTENFELDER, Horst
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C01G23/053
CPC分类号： A61Q19/004 , A61K8/29 , A61K2800/413 , A61K2800/43 , A61Q19/00 , B82Y5/00 , B82Y30/00 , C01G23/053 , C01G23/0536 , C01P2002/84 , C01P2004/64 , C01P2006/12 , C01P2006/60 , C09C1/3661
摘要： The invention concerns titanium dioxide pigments obtained by complete hydrolysis of a hydrolizable titanium compound at between 0 and 100 DEG C with intensive stirring, a pH set between 3 and 8 and maintenance of this pH within a range of 0.3 units. The titanium dioxide pigments can be used to produce cosmetic preparations and medicaments.
摘要翻译：二氧化钛颜料，由在0至100℃，剧烈搅拌下可水解的钛化合物的完全水解而得到，并用pH为3的范围内的设定为8，并在一定范围的0.3个单位保持恒定该pH值。二氧化钛颜料可用于生产化妆品制剂和药物。

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