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1. 发明申请

WO1993010098A1 PROCESS FOR PREPARING 3(5)-METHYLPYRAZOLES 审中-公开
标题翻译：制备3（5） - 甲基吡唑的方法
公开(公告)号：WO1993010098A1
公开(公告)日：1993-05-27
申请号：PCT/EP1992002514
申请日：1992-11-03
申请人： BASF AKTIENGESELLSCHAFT , KAESTNER, Ralf , RITTINGER, Stefan , PAESSLER, Peter , RIEBER, Norbert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D231/12
CPC分类号： C07D231/12
摘要： A process is disclosed for preparing methylpyrazoles from diacetylene and hydrazines. Diacetylene is separated by absorption from cracked gas, then reacted with hydrazines.

2. 发明申请

WO1996020146A1 USE OF PYRAZOLE DERIVATIVES WITH HYDROPHOBIC GROUPS AS NITRIFICATION INHIBITORS 审中-公开
标题翻译：包含疏水性基团如硝化抑制剂的吡唑衍生物的WERWENDUNG
公开(公告)号：WO1996020146A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995004953
申请日：1995-12-14
申请人： BASF AKTIENGESELLSCHAFT , RITTINGER, Stefan , RIEBER, Norbert , GOLD, Randall, Evan , DRESSEL, Jürgen
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C05G03/08
CPC分类号： C08J3/243 , C05G3/08 , C07D231/12 , C07D231/16 , C07D233/56 , C07D249/08 , C08J2321/00 , Y02P60/218
摘要： Disclosed is the use as nitrification inhibitors of pyrazole derivatives of formula (I), or salts thereof, in which the groups R -R have the following meanings: R , R and R represent C1-C20 alkyl, C3-C8 cycloalkyl, C5-C20 aryl or alkyl aryl (these four groups can be singly or doubly substituted by a halogen and/or hydroxyl), and halogen, nitro or hydrogen; and R represents either (a) C6-C20 alkyl, one or two hydrogen atoms being optionally substituted by a halogen; or (b) C1-C20 alkyl. In the latter case, 1-4 hydrogen atoms can be substituted by a group of formula (II), in which R , R , and R represent C1-C20 alkyl, C3-C8 cycloalkyl, C5-C20 aryl or alkyl aryl (these four groups can be singly or doubly substituted by a halogen and/or hydroxyl), as well as halogen, nitro or hydrogen; and 1 or two hydrogen atoms are optionally substituted by a halogen.
摘要翻译：式（I）或它们的盐的吡唑衍生物的用途，其中基团R <1>至R <4>具有以下含义：R t <1>，R <2>和R <3>：C1至C20 烷基，C3至C8环烷基，C5-C20芳基或烷基芳基，其中这4个基团单 - 或由卤素二取代的，羟基可被取代，以及卤素，硝基或氢，并且R <4>是或者a）C6和/或至C20烷基，任选被1或2个氢原子被卤素取代，或b）C1-C20烷基，其中1至4个氢原子被下式基团（II），其中R <5> - [R <6的取代 >和R <7> C1-C20烷基，C3至C8环烷基，C5-C20芳基或烷基芳基，其中这些基团4至单取代或被卤素和/或羟基，以及卤素，硝基取代的或氢和任选地1至2个氢原子被卤素取代，如硝化抑制剂。

3. 发明申请

WO1998005607A2 NEW NITRIFICATION INHIBITORS AND THE USE OF POLYACIDS TO TREAT MINERAL FERTILIZERS CONTAINING A NITRIFICATION INHIBITOR 审中-公开
标题翻译： NEW硝化抑制剂，和多元酸的矿物肥料的治疗中的用途制备硝化抑制剂CONTAIN
公开(公告)号：WO1998005607A2
公开(公告)日：1998-02-12
申请号：PCT/EP1997004278
申请日：1997-08-06
申请人： BASF AKTIENGESELLSCHAFT , BARTH, Thomas , RIEBER, Norbert , GOLD, Randall, Evan , DRESSEL, Jürgen , ERHARDT, Klaus , HORCHLER VON LOCQUENGH, Klaus , LEIBOLD, Edgar , RITTINGER, Stefan
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C05G03/08
CPC分类号： C07D231/12 , C05F3/00 , C05G3/08 , C07D231/16 , C07D233/56 , C07D249/08 , Y02A40/205 , Y02P20/145 , Y02P60/218 , Y10S71/902
摘要： The use of anorganic or organic polyacids to treat mineral fertilizers, in particular the use of polyacids as a mixture with at least one nitrification inhibitor to treat mineral fertilizers. The invention also concerns the use of selected pyrazole derivatives as inhibitors in mineral fertilizers ans as stabilizers for liquid manure or liquid fertilizer formulations, and the treated mineral fertilizers themselves, as well as new pyrazole derivatives that can be used as nitrification inhibitors in mineral fertilizers and as stabilizers in liquid manure or liquid fertilizer formulations.
摘要翻译：用于治疗无机肥料，特别是使用多元酸的作为与至少一种硝化抑制剂为无机肥料的处理混合物的无机或有机多元酸的使用; 使用选择的吡唑衍生物作为在无机肥料硝化抑制剂，并且作为液体肥料或液体肥料配方，以及相应的处理过的无机肥料本身的稳定剂; 其可被用作无机肥料硝化抑制剂，并且作为液体肥料或液体肥料制剂的稳定剂新的吡唑衍生物。

4. 发明申请

WO1996024566A1 USE OF NOT EASILY VOLATILISED PYRAZOL DERIVATIVES WITH HYDROPHILIC GROUPS AS NITRIFICATION INHIBITORS 审中-公开
标题翻译： HEAVY VOLATILE吡唑与亲水性基团USE作为硝化抑制剂
公开(公告)号：WO1996024566A1
公开(公告)日：1996-08-15
申请号：PCT/EP1996000319
申请日：1996-01-26
申请人： BASF AKTIENGESELLSCHAFT , RITTINGER, Stefan , RIEBER, Norbert , GOLD, Randall, Evan , DRESSEL, Jürgen
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C05G03/08
CPC分类号： C07D231/12 , C05G3/08 , C07D231/16 , Y02P60/218
摘要： Pyrazol derivatives having general formula (I) are disclosed, as well as their use as nitrification inhibitors. In said formula (I): residues R , R , R and R may be substituted once or twice by halogen and/or hydroxyl; the residues R , R and R stand for halogen, nitro, hydrogen, C1-C20-alkyl, C3-C8-cycloalkyl, C5-C20-aryl or alkyl aryl; and R may stand for (a) a residue R of the formula (II), in which R and R stand for hydrogen, C1-C20-alkyl optionally substituted once or twice by halogen and/or hydroxyl, a carboxyl group, a carboxymethyl group or a functional derivative of both latter groups, and R stands for a carboxyl residue or a carboxy-(C1-C3-alkyl) residue or for a functional derivative of said groups, or R may stand for (b) a residue R having the formula (III), in which R and R stand for hydrogen, C1-C20-alkyl, C2-C8-cycloalkyl, C5-C20-aryl or alkyl aryl, these residues being optionally substituted once or twice by halogen, and R stands for hydrogen or a poly-(C2-C4-alkylene oxide) residue whose terminal hydroxyl group may be etherified with an aliphatic C1-C10 alcohol or esterified with a C1-C10 carboxylic acid.
摘要翻译：通式（I）的硝化抑制剂，的吡唑衍生物的用途其中基团R <1>，R <2>，R <3>和R <4>具有以下含义：R t <1>，R <2>和 [R <3>是卤素，硝基，氢，C1〜C20烷基，C3至C8环烷基，C5-C20芳基或烷基芳基，其中这些基团4至单取代或被卤素和/或羟基取代， [R <4>是或者a）基团R <4A>具有式（II）其中R <5>和R <6>是氢，C 1 - 至C 20 - 烷基，其是单取代或被卤素和/或羟基取代的可以被取代，羧基，羧甲基或两个最后提到的基团的功能性衍生物，和R 7是羧基基团或羧基 - （C1-C3烷基）基团赋r是这些基团的功能性衍生物，或b）的基团 [R <4B>式（III）其中R <8>和R <9>是氢C1-C20烷基，C3至C8环烷基，C5-C20芳基或烷基芳基，其中这些基团两次可以被卤素取代，且R <10>为氢或聚（C 2至C 4亚烷基氧）基团，醚化的，其末端羟基用脂族C1〜C10的醇或酯化为C1至C10羧酸是可以。

5. 发明申请

WO1997047614A1 PROCESS FOR PRODUCING EPOXIDES FROM OLEFINES AND HYDROGEN PEROXIDE 审中-公开
标题翻译：用于生产烯烃和氢气环氧化物
公开(公告)号：WO1997047614A1
公开(公告)日：1997-12-18
申请号：PCT/EP1997002816
申请日：1997-05-30
申请人： BASF AKTIENGESELLSCHAFT , GROSCH, Georg Heinrich , MÜLLER, Ulrich , SCHULZ, Michael , RIEBER, Norbert , WÜRZ, Harald
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D301/12
CPC分类号： C07D303/04 , B01J29/04 , B01J29/89 , C07D301/12
摘要： A process for producing epoxides from olefines and hydrogen peroxide or hydroperoxides using an oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure and in the absence of an anthrahydroquinone/anthroquinone redox system, in which the oxidation catalyst is formed by solidifying shaping processes.
摘要翻译：一种用于从使用基于具有沸石结构的钛或钒硅沸石和在不存在蒽氢醌/蒽醌的氧化还原体系的氧化催化剂的烯烃和过氧化氢的环氧化物的制备方法，其特征在于所述氧化催化剂已经通过合并成形工艺形成。

6. 发明申请

WO1997031711A1 GRID CATALYST BASED ON TITANIUM ZEOLITE OR VANADIUM ZEOLITE AND ON INERT RETICULATED FABRICS FOR USE IN THE CATALYSIS OF OXIDATION REACTIONS 审中-公开
标题翻译：电源催化剂基于钛或钒沸石和惰性强大动力，加速组织的氧化反应
公开(公告)号：WO1997031711A1
公开(公告)日：1997-09-04
申请号：PCT/EP1997000804
申请日：1997-02-20
申请人： BASF AKTIENGESELLSCHAFT , MÜLLER, Ulrich , BRÖCKER, Franz, Josef , GROSCH, Georg, Heinrich , PÜTTER, Hermann , SCHULZ, Michael , RIEBER, Norbert , HARDER, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： B01J35/04
CPC分类号： B01J29/04 , B01J29/89 , B01J35/04 , B01J37/0246 , C01B15/029 , C01B21/1436 , C01B21/1454 , C07D301/12
摘要： The invention concerns a grid catalyst based on titanium zeolite or vanadium zeolite and on inert reticulated fabrics suitable for use in the catalysis of oxidation reactions such as the epoxidation of olefins, the production of hydrogen peroxide or the synthesis of hydroxylamine.
摘要翻译：本发明涉及一种基于钛或钒沸石和惰性纱布织物，其适合用于加速氧化反应，例如烯烃的环氧化中，过氧化氢产生或羟胺合成纱布催化剂。

7. 发明申请

WO1996002323A1 OXIDATION CATALYST, PROCESS FOR ITS PREPARATION AND OXIDATION PROCESS USING SAID OXIDATION CATALYST 审中-公开
标题翻译：氧化催化剂的方法用于生产和氧化过程中使用氧化催化剂
公开(公告)号：WO1996002323A1
公开(公告)日：1996-02-01
申请号：PCT/EP1995002651
申请日：1995-07-07
申请人： BASF AKTIENGESELLSCHAFT , MÜLLER, Ulrich , LINGELBACH, Peter , BASSLER, Peter , HARDER, Wolfgang , ELLER, Karsten , KOHL, Veronika , DEMBOWSKI, Jürgen , RIEBER, Norbert , FISCHER, Martin
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： B01J29/04
CPC分类号： B01J29/89 , B01J23/40 , C01B15/029 , C07D301/04 , C07D301/12
摘要： The invention concerns a titanium or vanadium silicalite-based oxidation catalyst having a zeolite structure and containing between 0.01 and 20 wt % of one or a plurality of platinum metals from the group comprising ruthenium, rhodium, palladium, osmium, iridium and platinum. The invention is characterized in that the platinum metals are each present in at least two different bond energy states and preferably do not contain any metal-to-metal bonds.
摘要翻译：基于钛或钒硅沸石具有沸石结构且含有从0.01至20重量选自钌，铑，钯，锇，铱和铂中选择的一种或多种铂族金属％，其特征在于，在氧化催化剂，该铂族金属在每至少两个不同的键的能量状态存在，并优选没有金属 - 金属键。

8. 发明申请

WO1997047613A1 PROCESS FOR PRODUCING EPOXIDES FROM OLEFINES AND HYDROGEN PEROXIDE OR HYDROPEROXIDES USING A ZEOLITHIC OXIDATION CATALYST 审中-公开
标题翻译：用于从烯烃和过氧化氢或氢过氧化物PRODUCING环氧化物使用沸石氧化催化剂
公开(公告)号：WO1997047613A1
公开(公告)日：1997-12-18
申请号：PCT/EP1997002815
申请日：1997-05-30
申请人： BASF AKTIENGESELLSCHAFT , MÜLLER, Ulrich , GROSCH, Georg, Heinrich , HAUER, Bernhard , SCHULZ, Michael , RIEBER, Norbert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D301/12
CPC分类号： C07D301/19 , B01J29/04 , B01J29/89 , C07D301/12
摘要： A process for producing epoxides from olefines and hydrogen peroxide or hydroperoxides in the liquid phase using an oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure, in which the concentration of the hydrogen peroxide or hydroperoxides in the reaction mixture is in the range from 0.05 to less than 1 wt.% during the reaction.
摘要翻译：一种用于从使用一种氧化催化剂基于钛硅酸盐或具有沸石结构钒硅酸盐在液相中的烯烃和过氧化氢或氢过氧化物的环氧化物的制备方法，其特征在于，在反应混合物中的过氧化氢或氢过氧化物的在范围内的反应中的浓度 0.05至小于1重量％左右。

9. 发明申请

WO1997047386A1 OXIDATION CATALYST AND PROCESS FOR THE PRODUCTION OF EPOXIDES FROM OLEFINES, HYDROGEN AND OXYGEN USING SAID OXIDATION CATALYST 审中-公开
标题翻译：氧化催化剂和方法用于从烯烃，氢，氧环氧化物使用氧化催化剂
公开(公告)号：WO1997047386A1
公开(公告)日：1997-12-18
申请号：PCT/EP1997002821
申请日：1997-05-30
申请人： BASF AKTIENGESELLSCHAFT , GROSCH, Georg, Heinrich , MÜLLER, Ulrich , SCHULZ, Michael , RIEBER, Norbert , WÜRZ, Harald
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： B01J29/04
CPC分类号： B01J29/04 , B01J29/89 , C07D301/04
摘要： An oxidation catalyst based on titanium or vanadium silicalites with a zeolithic structure and containing 0.01 to 30 wt.% of one or more noble metals from the group ruthenium, rhodium, palladium, osmium, iridium, platinum, rhenium, gold and silver, in which the oxidation catalyst is formed by solidifying shaping processes. Said oxidation catalyst is used in the production of epoxides, especially propylene oxide, from olefines, hydrogen and oxygen.
摘要翻译：基于钛或具有沸石结构且含有从0.01至30重量选自钌，铑，钯，锇，铱，铂，铼，金的一种或多种贵金属的％的钒硅沸石和氧化催化剂银，其特征在于，所述氧化催化剂已经通过合并成形工艺形成。用于生产环氧化物，特别是环氧丙烷，由烯烃，氢气和氧气的这种氧化催化剂。

10. 发明申请

WO1996026198A1 PROCESS FOR PRODUCING EPOXIDES USING AROMATIC PEROXYCARBOXYLIC ACIDS 审中-公开
标题翻译：用于生产环氧芳香过氧
公开(公告)号：WO1996026198A1
公开(公告)日：1996-08-29
申请号：PCT/EP1996000578
申请日：1996-02-10
申请人： BASF AKTIENGESELLSCHAFT , TELES, Joaquim, Henrique , SCHNURR, Werner , FISCHER, Rolf , RIEBER, Norbert , SCHULZ, Michael
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D301/14
CPC分类号： C07C45/41 , C07C407/00 , C07D301/14 , C07D303/04 , C07C409/30
摘要： The invention concerns the production of epoxides from olefins using aromatic peroxycarboxylic acids. Following epoxidisation (step A), the aromatic carboxylic acids thereby produced are separated from the epoxides and catalytically hydrated (step B) to form the corresponding aromatic aldehydes which are then oxidised (step C) with oxygen or with an oxygen-containing gas mixture to form again the aromatic peroxycarboxylic acids which can be used again to produce the epoxides.
摘要翻译：通过环氧化后（步骤A）中分离从所述环氧化物得到的芳族羧酸由芳族过氧羧酸手段从烯烃环氧化物的制备，在催化步骤B被氢化成相应的芳族醛和在步骤C中，这些醛类与氧气或含氧气体混合物回氧化成芳族过氧羧酸，其被再次用于制备环氧化物的。

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