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1. 发明申请

WO2004054948A8 METHOD FOR THE PRODUCTION OF 1.6-HEXANEDIOL 审中-公开
标题翻译：用于生产1,6-己二醇
公开(公告)号：WO2004054948A8
公开(公告)日：2005-06-23
申请号：PCT/EP0313634
申请日：2003-12-03
申请人： BASF AG , FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
发明人： FISCHER ROLF-HARTMUTH , KRUG THOMAS , HAUNERT ANDREA , ROEPER MICHAEL , SIRCH TILMAN , STUEER WOLFRAM
IPC分类号： C07C29/17 , C07C29/149 , C07C31/20 , C07C67/347 , C07C69/593
CPC分类号： C07C29/177 , C07C31/20
摘要： The invention relates to a method for producing 1,6-hexanediol having a purity of > 99.5 wt. % by catalytic dimerisation of acrylic acid esters, catalytic hydrogenation of the thus obtained hexene diacidic diester in order to form 1.6-hexanediol. Said method consists in: a) dimerising C1- C8-acrylic acid esters in the presence of at least one rhodium compound in order to form mixtures predominantly of 2- and 3-hexene diacdic diesters, b) hydrating the obtained dimerisation discharge in the presence of chrome-free catalysts containing mainly copper as a hydrogenation component and c) purifying the thus obtained raw 1.6-hexanediol by fractionating distillation.
摘要翻译：本发明涉及一种用于制备具有> 99.5重量％的纯度的1,6-己二醇，由丙烯酸酯，以这种方式获得成1,6-己二醇的二酯己烯的催化氢化方法，其包括催化二聚化：一个）C1至C8丙烯酸酯在二聚的至少一种铑化合物的存在下，得到主要为2-和3-己烯二酯的混合物，b）中氢化在无铬的存在下将所得二聚化流出物，含有作为氢化主要是铜催化剂，和c）将如此得到的粗1 1,6-己二醇通过分馏进行纯化。

2. 发明申请

WO9812165A3 PROCESS FOR PRODUCING ALKOXYBUTENES 审中-公开
标题翻译：用于生产alkoxybutenes
公开(公告)号：WO9812165A3
公开(公告)日：1999-07-22
申请号：PCT/EP9704704
申请日：1997-08-29
申请人： BASF AG , KANAND JUERGEN , ROEPER MICHAEL
发明人： KANAND JUERGEN , ROEPER MICHAEL
IPC分类号： C07C41/00 , C07B61/00 , C07C41/06 , C07C43/15
CPC分类号： C07C41/06 , C07C43/15 , C07C43/04
摘要： In a process for producing alkoxybutenes, 1,3-butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of formula ROH (I) at an increased temperature and pressure in the presence of a Brönsted acid, yielding a mixture of addition products of formulas (II) and (III), in which the radical R is a C2-C20 alkyl, alkenyl, cycloalkyl or cycloalkenyl group substituted or not with 1 to 2 C1-C10 alkoxy or hydroxy groups, or is a C2-C10 aryl or C7-C11 aralkyl group or a methyl group. The disclosed improvement consists in that the reaction is carried out in the presence of water.
摘要翻译：一种用于制备alkoxybutenes方法，其中1,3-丁二烯或含丁二烯的烃混合物与式（I），ROH的醇，在升高的温度和升高的压力下，在布朗斯台德酸的存在下式的加成物的混合物（II）和（III）进行反应，其中基团R是未取代或至多被1至2 C1 C2至C20烷基，烯基，环烷基或环烯基，或C 10烷氧基或羟基基团 C2是C10芳基或C7至C11芳烷基或甲基，其中的改进在于，一个执行在水的存在下进行反应。

3. 发明申请

WO0136356A3 C13 ALCOHOL MIXTURE AND FUNCTIONALISED C13 ALCOHOL MIXTURE 审中-公开
标题翻译： C13醇混合物和功能化的C13醇混合物
公开(公告)号：WO0136356A3
公开(公告)日：2001-12-06
申请号：PCT/EP0011440
申请日：2000-11-17
申请人： BASF AG , ZELLER EDGAR , WALTER MARC , RICHTER WOLFGANG , DIEHL KLAUS , ROEPER MICHAEL , TROPSCH JUERGEN
发明人： ZELLER EDGAR , WALTER MARC , RICHTER WOLFGANG , DIEHL KLAUS , ROEPER MICHAEL , TROPSCH JUERGEN
IPC分类号： B01F17/38 , C07B61/00 , C07C2/08 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C43/11 , C07C45/50 , C07F9/09 , C07F9/11 , C11D7/26 , C07C2/10 , C07C11/02 , C07C47/02 , C11D1/34
CPC分类号： C11D7/262 , C07C29/141 , C07C29/16 , C07C41/03 , C07C43/11 , C07C45/50 , C07F9/091 , C07F9/11 , C11D7/261 , C07C31/125 , C07C47/02
摘要： The invention relates to a method for producing a C13 alcohol mixture, according to which a) a stream of C4 hydrocarbon containing butenes, which includes less than 5 % by weight of iso-butene in relation to the butene fraction, is brought into contact with a heterogeneous catalyst containing a nickel at a raised temperature, b) a C12 olefin fraction is isolated from the reaction mixture, c) the C12 olefin fraction is hydroformulated by being reacted with carbon dioxide and hydrogen in the presence of a cobalt catalyst and d) is hydrated. The alcohol mixture thus obtained is suitable for producing surfactants by alkoxylation, glycosidation, sulphation, phosphation, alkoxylation and subsequent sulphation or alkoxylation and subsequent phosphation.
摘要翻译：公开的是用于制造C13醇混合物，其中所述C 4烃流中的）含有少于5重量％的丁烯，基于丁烯馏分异丁烯，含有在高温下与一种镍的非均相催化剂的方法使接触，b）从所述反应混合物中，C 12烯烃馏分C）的C12烯烃馏分通过与一氧化碳和氢在氢化钴催化剂和d）的存在下，然后可购得的醇混合物反应加氢甲酰化中分离。醇混合物是适合于通过烷氧基化，糖苷化，硫酸化，磷酸化，烷氧基化和随后的硫酸化烷氧基化或和随后的磷酸酯化制备的表面活性剂。

4. 发明申请

WO02064249A3 COMPOUND SUITABLE FOR USE AS A CATALYST OR FOR PRODUCING A CATALYST SYSTEM DERIVED FROM A BIS-PHOSPHORINANE 审中-公开
标题翻译： AS催化剂或制备催化剂体系合适的连接是衍生自TO-phosphorinane
公开(公告)号：WO02064249A3
公开(公告)日：2003-03-20
申请号：PCT/EP0200822
申请日：2002-01-26
申请人： BASF AG , SLANY MICHAEL , SCHAEFER MARTIN , ROEPER MICHAEL
发明人： SLANY MICHAEL , SCHAEFER MARTIN , ROEPER MICHAEL
IPC分类号： B01J31/22 , B01J31/24 , C07B61/00 , C07C67/38 , C07C69/24 , C07C69/34 , C07C253/30 , C07C255/19 , C07F9/6568 , C07F9/50
CPC分类号： B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C67/38 , C07C253/30 , C07F9/65683 , C07C69/44 , C07C69/24 , C07C255/19
摘要： .he invention relates to a compound of formula I wherein X represents a low alkylen group, an arylene group or an alkarylene group, L1 has formula II wherein Y1 represents oxygen, sulphur or N-R17, R11, R12, R13, R14, R15, R16, R17 independently represent hydrogen, alkyl or aryl, L2 has formula III wherein Y2 represents oxygen, sulphur or N-R27, R21, R22, R23, R24, R25, R26, R27 independently represent hydrogen, alkyl or aryl wherein L1 and L2 can be identical or different. The inventive compound is suitable for use as a catalyst or for producing a catalyst system.
摘要翻译：作为催化剂或用于制备式（I）的催化剂体系适宜化合物的制备，其中X：低级亚烷基，亚芳基或亚烷芳基团L <1>，其中Y <1>为氧，硫或NR <17>，R <11>，R <12> ，R <13>，R <14>，R <15> - [R <16>，R物质<17>独立地是氢，烷基或芳→<2>ý<2>为氧，硫或NR <27>， [R <21>，R <22>，R <23>，R <24>，R <25>，R <26>，R物质<27>独立地是氢，烷基或芳基，其中L <1>和L < 2>可以相同或不同。

5. 发明申请

WO9812164A3 PROCESS FOR PRODUCING n-BUTYLALKYL ETHERS 审中-公开
标题翻译：工艺生产N- BUTYLALKYLETHERN
公开(公告)号：WO9812164A3
公开(公告)日：1999-04-01
申请号：PCT/EP9704703
申请日：1997-08-29
申请人： BASF AG , KANAND JUERGEN , ROEPER MICHAEL
发明人： KANAND JUERGEN , ROEPER MICHAEL
IPC分类号： B01J31/24 , C07B61/00 , C07C41/00 , C07C41/06 , C07C41/20 , C07C41/32 , C07C43/04
CPC分类号： C07C41/06 , C07C41/20 , C07C41/32 , C07C41/54 , C07C43/15 , C07C43/04 , C07C43/303
摘要： In a process for producing n-butylalkyl ethers, (a) 1,3-butadiene or a butadiene-containing hydrocarbon mixture is reacted with an alcohol of formula ROH (I), in which the radical R is a C2-C20 alkyl or alkenyl group substituted or not with 1 to 2 C1-C10 alkoxy or hydroxy groups, a C6-C10 aryl or C7-C11 aralkyl group or a methyl group, at an increased temperature and pressure in the presence of a Brönsted acid or in the presence of a complex of an element of groups Ib, VIIb or VIIIb of the periodic table of elements with a phosphorus- or nitrogen-containing ligand, yielding a mixture of addition products of formulas (II) and (III); (b) the isomers are separated; (c) addition product III is isomerised into addition product II; (d) addition product II is hydrogenated in the presence of a homogeneous or heterogeneous transition metal element catalyst in the liquid phase or in the presence of a heterogeneous, transition metal element-containing catalyst in the gas phase, yielding n-butylalkyl ether of formula (IV).
摘要翻译：通过一种用于制备过程正Butylalkylethern：1）1,3-丁二烯或烃混合物与下式的醇含丁二烯的：ROH，其中R是未取代的或被1至2的C1〜C10烷氧基或羟基取代的C2至C20烷基或链烯基，C6至C10芳基或C7-C11芳烷基团或甲基基团，在升高的温度和在布朗斯台德酸的或在存在升高的压力从Ib族，VIIB或用含磷或含氮配体的元素的周期表VIIIb的元素的复合物的存在下反应得到下式的加合物（II）和混合物（III）; b）分离的异构体; c）该加合物III异构化为加合物II和d）氢化所述加合物II在均相或非均相过渡金属元素催化剂的在液相中或在非均相，含过渡金属元素的催化剂的在气相存在下式的n Butylalkylether存在（IV），

6. 发明申请

WO0216290A3 METHOD FOR SYNTHESISING TERMINAL OLEFINS HAVING A LIMITED MOLAR MASS DISTRIBUTION 审中-公开
标题翻译： METHOD FOR TERMINAL烯烃与窄分子量分布的合成
公开(公告)号：WO0216290A3
公开(公告)日：2002-06-27
申请号：PCT/EP0109756
申请日：2001-08-23
申请人： BASF AG , RATH HANS PETER , MACH HELMUT , ROEPER MICHAEL , STEPHAN JUERGEN , KARL JOERN , BLACKBOROW RICHARD
发明人： RATH HANS PETER , MACH HELMUT , ROEPER MICHAEL , STEPHAN JUERGEN , KARL JOERN , BLACKBOROW RICHARD
IPC分类号： C07C6/04 , C07C11/02 , C08F2/34
CPC分类号： C07C6/04 , C07C11/02 , C07C2521/10 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/46 , C07C2523/755 , C07C2527/232
摘要： The invention relates to a method for producing linear alpha olefins by means of an isomerising metathetical reaction and ensuing ethenolysis. The method comprises the following steps: i) a C4-C10 olefin fraction is introduced into an isomerising metathesis reaction; ii) the mixture obtained is separated into a) a C2-C3-olefin fraction, b) a fraction containing olefins having the desired carbon count, c) a light fraction containing olefins having a carbon count of C4 or above, but below the carbon count of the desired fraction b) and, d) a heavy fraction containing olefins having a carbon count which is above the carbon count of the desired fraction b); iii) the light fraction c) and optionally the heavy fraction d) are redirected into the isomerising metathesis reaction i); iv) the fraction b) and optionally the fraction d) are introduced into an ethenolysis reaction; and v) the alpha olefin fraction produced in iv) is isolated. Linear C8-C12 alpha olefins can be especially produced using said method.
摘要翻译：本发明涉及一种用于通过异构随后乙烯醇分解的复分解反应制备线性α-烯烃的方法。该方法包括以下步骤：1）在异构化的复分解反应来引入C4-C10-Olefinenfraktion，ⅱ）分离）的C2-C3烯烃在获得的混合物，b）含有与所需的碳原子数的烯烃的级分，C ）包含含有C4的碳原子数为低于期望的级分b的碳原子数）和d）的重馏分，具有所希望的级分b的Kohlensotffzahl以上的碳原子数的烯烃的烯烃的轻馏分）含有iii）所述的轻馏分回收 C），并在异构化复分解反应我任选重馏分d））的部分b的，静脉内）插入）中并在乙烯醇分解任选的成分d），v）分离在IV产生的α-烯烃馏分）。特别地，可以是由该方法的线性C 8 -C 12α烯烃表示。

7. 发明申请

WO2005061447A3 METHOD FOR PRODUCING ALKYLARYL COMPOUNDS 审中-公开
标题翻译：用于生产烷CONNECTIONS
公开(公告)号：WO2005061447A3
公开(公告)日：2007-01-04
申请号：PCT/EP2004014444
申请日：2004-12-17
申请人： BASF AG , BOTTKE NILS , TROPSCH JUERGEN , NARBESHUBER THOMAS , STEPHAN JUERGEN , ROEPER MICHAEL , HEIDEMANN THOMAS , STEINBRENNER ULRICH , BENFER REGINA
发明人： BOTTKE NILS , TROPSCH JUERGEN , NARBESHUBER THOMAS , STEPHAN JUERGEN , ROEPER MICHAEL , HEIDEMANN THOMAS , STEINBRENNER ULRICH , BENFER REGINA
IPC分类号： C07C2/66 , C07C303/06 , C07C309/31 , C11D1/22 , C11D11/04
CPC分类号： C07C6/04 , C07C2/08 , C07C2/66 , C07C5/2506 , C07C303/06 , C11D1/22 , C11D11/04 , C07C309/31 , C07C11/02 , C07C11/10 , C07C15/107
摘要： The production of alkylaryl compounds comprises the following stages: a) reaction of a C4/C5 olefin mixture on a metathesis catalyst to produce a C 4-8 olefin mixture containing 2-pentene and the optional isolation of the C 4-8 olefin mixture; b) isolation of between 5 and 100 % of the 2-pentene obtained in step a) and subsequent reaction on an isomerisation catalyst to form a mixture of 2-pentene and 1-pentene, which is returned to stage a); c) dimerisation of the C 4-8 olefin mixture obtained in stage b) after the isolation process, to form a mixture containing C 8-16 olefins, isolation of the C 8-16 olefins and optional isolation of a partial stream of the latter; d) reaction of the C 8-16 olefin mixtures obtained in stage c) or the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst, to form alkyl aromatic compounds, whereby prior to the reaction an additional 0 to 60 wt. % linear olefins, in relation to the C 8-16 olefin mixtures obtained in stage c), can be added; e) optional sulphonation of the alkyl aromatic compounds obtained in stage d) and neutralisation to form alkylaryl sulphonates, whereby prior to the sulphonation an additional 0 to 60 wt. % linear alkyl benzols, in relation to the alkyl aromatic compounds obtained in stage d), can be added, provided that there were no admixtures in stage d); f) optional mixing of the alkylaryl sulphonates obtained in stage e) with between 0 and 60 wt. %, linear alkylaryl sulphonates, in relation to the alkylaryl sulphonates obtained in stage e), provided that there were no admixtures in stages d) and e).
摘要翻译：烷基芳基化合物通过C4 / C5烯烃混合物的超过一个C含有2-戊烯_{4-8 烯烃混合物的制备复分解催化剂的C _{的）反应，和可选地移除该制剂 4-8 烯烃混合物，b）中的5％至100％的分离在步骤a）所得2-戊烯和异构化催化剂的2-戊烯与1-戊烯的混合物随后的反应，在阶段a）再循环，C）C的分离之后，在步骤b中得到的二聚）_{4-8 在二聚催化剂存在下烯烃混合物，得到含烯烃-C _{8-16 混合物，的C _{8-16 烯烃，和任选除去一个部分流体，D）在步骤C中获得的化合物反应）C _{8-16 烯烃混合物或所述部分与芳族料流的分离在烷基化催化剂的存在下烃以形成烷基芳香族Ve的 rbindungen，其中烯烃，e）可以反应，0〜60重量％之前添加到直链烯烃，基于在步骤c得到的）C在磺化_{8-16，任选地获得步骤d）的烷基芳族化合物中和以得到烷基芳基磺酸盐，其中之前的磺化，0至60重量％，基于在步骤d）中获得的烷基，可被加入到直链烷基苯的芳族化合物中，如果在步骤d没有掺合）下进行中，f）如果到60重量％）的0）在步骤e中得到的烷基芳基磺酸盐的适当的混合，基于在步骤e烷芳基磺酸盐所获得的），线性烷基芳基磺酸盐，如果在步骤没有外加剂d）和e被执行。}}}}}}}

8. 发明申请

WO0200669A3 PHOSPHACYCLOHEXANES AND THE USE THEREOF IN THE HYDROFORMYLATION OF OLEFINS 审中-公开
标题翻译： Phosphacyclohexanes及其用途烯烃氢甲酰化反应
公开(公告)号：WO0200669A3
公开(公告)日：2002-06-20
申请号：PCT/EP0107219
申请日：2001-06-25
申请人： BASF AG , MACKEWITZ THOMAS , AHLERS WOLFGANG , ZELLER EDGAR , ROEPER MICHAEL , PACIELLO ROCCO , KNOLL KONRAD , PAPP RAINER , VOSS HARTWIG
发明人： MACKEWITZ THOMAS , AHLERS WOLFGANG , ZELLER EDGAR , ROEPER MICHAEL , PACIELLO ROCCO , KNOLL KONRAD , PAPP RAINER , VOSS HARTWIG
IPC分类号： B01J31/24 , B01J31/28 , C07C45/50 , C07F9/6568 , C07F15/00 , C07F15/04 , C07F15/06
CPC分类号： B01J31/2466 , B01J31/20 , B01J31/2423 , B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , C07F9/65683 , C07F15/0026 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07F15/065 , C07C47/21 , C07C47/02
摘要： The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C1-100-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl; R to R can independently represent hydrogen, C1-20-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl; W, W' can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to groups VIII to X of the periodic table.
摘要翻译： Phosphacyclohexanes通式（I）和（II），除其他外，以下含义：R是氢，烷基C1-100，C7-20芳烷基，C7-20烷芳基，C 6-12 - 芳基，R <1>至R <10>独立地是氢，C 1-20烷基，C 7-20 - 芳烷基，C7-20烷芳基，C 6-12 - 芳基; W，W“各自独立地为单键或具有1至20个碳原子，其可以是环状或芳族基团的一部分，并且可以被杂原子间隔的桥梁，被用作在第八的过渡金属的过渡金属配合物的配体的元素的周期表的第10组，

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