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    • 1. 发明申请
    • USE OF HYPERBRANCHED POLYCARBONATES AS A DISPERSING AGENT FOR PIGMENTS
    • 超支化聚碳酸酯作为分散剂使用的颜料
    • WO2007135032A3
    • 2008-01-17
    • PCT/EP2007054721
    • 2007-05-15
    • BASF AGBRUCHMANN BERNDGARCIA ESPINO ANDRES CARLOSKLUEGLEIN MATTHIASBEST WOLFGANGJESSE JOACHIMSENS BENNO
    • BRUCHMANN BERNDGARCIA ESPINO ANDRES CARLOSKLUEGLEIN MATTHIASBEST WOLFGANGJESSE JOACHIMSENS BENNO
    • C09B67/20C08G64/00C08L69/00C09D169/00
    • C09B67/0063C08G64/0216C09B67/0066C09B67/009
    • Disclosed is the use of highly functional, highly branched or hyperbranched polycarbonates as a dispersing agent for pigments. Said polycarbonates can be obtained by a) producing one or several different condensation products (K) by a1) reacting at least one organic carbonate (A) of general formula RO[(CO)O] n R with at least one aliphatic, aliphatic/aromatic, or aromatic alcohol (B) comprising at least 3 OH groups while eliminating alcohols ROH, R independently representing a linear or branched aliphatic, aromatic/aliphatic, or aromatic hydrocarbon radical containing 1 to 20 C atoms, and radicals R being optionally interconnected so as to form a ring containing the grouping -O[(CO)O] n -, and n representing an integer ranging from 1 to 5, or a2) reacting phosgene, diphosgene, or triphosgene with the aliphatic, aliphatic/aromatic, or aromatic alcohol (B) while releasing hydrogen chloride, the quantitative ratio between alcohols (B) and the carbonates (A) or the phosgenes in the reaction mixture being selected such that the condensation products (K) on average are provided with one carbonate group or carbamyl chloride group and more than one OH group or one OH group and more than one carbonate group or carbamyl chloride group, and b) intermolecularly reacting the condensation products (K) obtained in step a).
    • 的高功能的使用,高度支化或超支化聚碳酸酯,由获得)制备一种或多种不同的缩合产物(K)由任一a1)中的通式的至少一种有机碳酸酯(A)RO [(CO)O] Ñ反应< / SUB>与至少一种脂族,脂族/芳族或芳族醇(B)R具有至少3个OH基团,消去醇的ROH,其中R各自独立地为直链或支链脂族,芳族/ 脂族或芳族烃基,其具有1至20个碳原子是与基团R也可以形成一个分组-O [(CO)O] 名词 - 含环可连接在一起,n是一个整数 从1至5,或a2)反应的光气,双光气或三光气与脂族,脂族/芳族或芳族醇(B)与氯仿溶剂的释放 其中选择的醇(B)与碳酸酯(A)或在反应混合物中光气的比例,例如,R是氢,即缩合产物(K)平均含有一个碳酸酯或氨基甲酰氯基团和多于一个OH基团或一个OH 基团和一个以上的碳酸酯或氨基甲酰氯基团有,和b)形成的,在步骤a的缩合产物)(K),作为分散剂用于颜料的分子间反应。
    • 6. 发明申请
    • PIGMENT COMPOSITIONS
    • 颜料组合物
    • WO2010060698A3
    • 2011-03-24
    • PCT/EP2009063849
    • 2009-10-22
    • BASF SEWAGENBLAST GERHARDREICHELT HELMUTREINHARDT ROBERTBEST WOLFGANGSCHAMBONY SIMONMICHAILOVSKI ALEXEJ
    • WAGENBLAST GERHARDREICHELT HELMUTREINHARDT ROBERTBEST WOLFGANGSCHAMBONY SIMONMICHAILOVSKI ALEXEJ
    • C08K5/00C07D249/20
    • C08K5/0041C07D249/20C08K3/24C08K5/3475C09B69/06
    • The invention relates to pigment compositions containing UV absorbers and inorganic polyacids. The UV absorbers can be cationic UV absorbers, for example, salicylic acid derivatives, cinnamic acid derivatives, benzotriazole derivatives, benzophenone derivatives, naphthalimide derivatives, phenyltriazines, benzylidene camphor derivatives. The cationic UV absorbers often contain quaternized nitrogen atoms, imidazolium groups, pyridinium groups, or sulfonium groups. The invention further relates to a method for producing pigment compositions, comprising providing a solution of one or more cationic absorbers, providing a solution of one or more inorganic polyacids or salts of polyacids, mixing the solutions, and precipitating the pigment composition. The invention further relates to uses of pigment compositions as light stabilizers. The invention further relates to cationic UV absorbers of the formula (I), wherein X- is a halide, CH3SO3-, CH3OSO3-, C2H5OSO3-, p-CH3-C6H4OSO3-, CN-, SCN-, R11 is H, halogen, C1-C20 alkyl, perfluoro-C1-C20 alkyl, R12 is C1-C20 alkyl, R13 is C1-C20 alkyl, R14 is C1-C20 alkyl, and R15 is C1-C20 alkyl, C2-C6-alkylene-N+(CH3)3X-, or R13 and R14 can jointly form a C4-C7 alkylene group that can optionally be interrupted by a heteroatom, and wherein the C1-C20 alkyl groups of the substituents R11, R12, R13, R14, and/or R15 can optionally be interrupted by one or more O atoms.
    • 颜料组合物,其包括UV吸收剂和无机多元酸。 该UV吸收剂可以是阳离子UV吸收剂,例如,水杨酸,肉桂酸,苯并三唑,二苯甲酮,Naphthylimidderivate,苯基三嗪,亚苄基樟脑。 阳离子UV吸收剂通常包含季铵化的氮原子,咪唑鎓,吡啶鎓或锍基团。 一种用于制备包括提供一种或多种阳离子UV吸收剂的溶液中的颜料组合物,提供一种或多种无机酸和多元酸的盐的溶液中,混合溶液,并沉淀出颜料组合物的过程。 颜料组合物的使用光稳定剂。 式(I),其中X是阳离子UV吸收剂卤化物,CH 3 SO 3,CH3OSO3-,C2H5OSO3-,对CH3-C6H4OSO3-,CN-,SCN-,R 11为H,卤素,C1-C20烷基,perflouro- C1-C20烷基,R12 C1-C20烷基,R13 C1-C20烷基,R14 C1-C20烷基,R15 C1-C20烷基,C2-C6亚烷基 - N +(CH 3)3 X是或R 13和 R14可以形成C 4 -C 7亚烷基一起,其可以任选地被杂原子打断,其中所述C 1 -C 20是取代基R11,R12,R13,R14的烷基基团和/或R 15任选地被一个或多个O原子中断, 可以。