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    • 1. 发明申请
    • AQUEOUS DISPERSIONS OF WATER-SOLUBLE AND/OR WATER-SWELLABLE ANIONIC POLYMERS, METHOD FOR THEIR PRODUCTION AND USE THEREOF
    • 水溶性的和/或水溶胀性阴离子聚合物的水分散液,生产和使用方法
    • WO2006018113A3
    • 2006-08-03
    • PCT/EP2005008276
    • 2005-07-30
    • BASF AGBRAIG VOLKERGAUWEILER WERNERMUKHERJEE PULAKESHWEIDL CHRISTIAN HUBERT
    • BRAIG VOLKERGAUWEILER WERNERMUKHERJEE PULAKESHWEIDL CHRISTIAN HUBERT
    • C08F2/16C08F2/18C08F2/20C08F2/44C08F20/04C08F22/04
    • C08F283/06C08F2/20C08L51/08C08L53/00C08L53/005C09D7/43C09D11/03C14C11/003C08L2666/02
    • The invention relates to aqueous dispersions of water-soluble and/or water-swellable anionic polymers, which can be obtained by the radical polymerisation of ethylenically unsaturated anionic monomers in an aqueous medium in the presence of at least one stabiliser. According to the invention, the polymerisation is carried out in the presence of at least one water-soluble polymer, acting as a stabiliser, from the following groups: (a) polymers of vinyl acetate and/or vinyl propionate grafted onto (i) polyethylene glycols or (ii) polyethylene glycols or polypropylene glycols, whose end groups are terminated on one or both sides with alkyl, carboxyl or amino groups, polyalkylene glycols, or polyalkylene glycols, whose end groups are terminated on one or both sides with alkyl, carboxyl or amino groups and (b) water-soluble copolymers consisting of (b1) non-ionic monoethylenically unsaturated monomers, (b2) cationic monoethylenically unsaturated monomers and optionally (b3) anionic monoethylenically unsaturated monomers, the fraction of the polymerised cationic monomers being greater than that of the anionic monomers. The invention also relates to a method for producing the aqueous dispersions by the radical polymerisation of the anionic monomers in an aqueous medium in the presence of the aforementioned water-soluble polymers (a) and (b), in addition to the use of the aqueous dispersions as thickening agents for aqueous systems.
    • 水溶性和/或水溶胀性的阴离子聚合物是由烯属不饱和阴离子单体的自由基聚合获得,在至少一种稳定剂的存在下在水性介质中,水分散体,其中在所述基团(a)中的接枝聚合物中的至少一种水溶性聚合物的存在下聚合 接通(I)的聚乙二醇或乙酸乙烯酯和/或丙酸乙烯酯或两侧用烷基,羧基或氨基封端的聚乙二醇或聚丙二醇,聚亚烷基二醇,一个或(ii)两者封端的烷基,羧基或氨基,聚亚烷基二醇和( b)(b1)的非离子单烯属不饱和单体,(b2)中的阳离子单烯属不饱和单体以及合适的话(b3)的阴离子的单烯属不饱和单体,其中所述的聚合物的比例的水溶性共聚物 比阴离子单体作为稳定剂进行更大化的阳离子性单体,在上述水溶性聚合物的存在下制备在含水介质中由所述阴离子单体的自由基聚合的水性分散体的方法(a)和(b)中以及使用该水性分散体作为 增稠剂用于水性体系。