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1. 发明申请

WO2011160936A1 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2011160936A1
公开(公告)日：2011-12-29
申请号：PCT/EP2011/059267
申请日：2011-06-06
申请人： BASELL POLIOLEFINE ITALIA SRL , FUSHIMI, Masaki , GUIDOTTI, Simona , KRISTEN, Marc Oliver , MIGNOGNA, Alessandro , MORINI, Giampiero , PATER, Jochem T. M.
发明人： FUSHIMI, Masaki , GUIDOTTI, Simona , KRISTEN, Marc Oliver , MIGNOGNA, Alessandro , MORINI, Giampiero , PATER, Jochem T. M.
IPC分类号： C08F10/06
CPC分类号： C08F4/6494 , C08F10/06 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/651
摘要： A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from 1,3-diethers; (b) an alkylaluminum cocatalyst; and (c) an ester of formula ROOC-(CH 2 ) n -COOR in which n is an integer from 2 to 8, R groups, equal to or different from each other, are C1-C10 alkyl groups.
摘要翻译：一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自1,3-二醚的电子给体化合物的固体催化剂组分接触获得的产物; （b）烷基铝助催化剂; 和（c）式为ROOC-（CH 2）n -COOR的酯，其中n为2至8的整数，R基彼此相同或不同，为C 1 -C 10烷基。

2. 发明申请

WO2011107370A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2011107370A1
公开(公告)日：2011-09-09
申请号：PCT/EP2011/052563
申请日：2011-02-22
申请人： BASELL POLIOLEFINE ITALIA SRL , GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochem T. M. , MORINI, Giampiero
发明人： GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochem T. M. , MORINI, Giampiero
IPC分类号： C08F4/651 , C08F110/06 , C08F4/654 , C08F4/646
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/6465 , C08F4/651 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where R 1 and R II are the same or different and are hydrogen or linear or branched C 1 -C 18 hydrocarbon groups which can also form one or more cyclic structures; R III groups, equal or different from each other, are hydrogen or C 1 -C 18 hydrocarbon groups; R IV groups equal or different from each other, have the same meaning of R III except that they cannot be hydrogen; each of R I to R IV groups can contain heteroatoms selected from halogens, N, O, S and Si.
摘要翻译：用于烯烃CH 2 = CHR聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一种选自烷氧基苯，另一种选自那些其中R 1和R II相同或不同并且是氢或可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; 相同或不同的RIII基团是氢或C 1 -C 18烃基; RIV基团相同或不同，具有与RIII相同的含义，不同之处在于它们不能是氢; 每个RI至RIV基团可以含有选自卤素，N，O，S和Si的杂原子。

3. 发明申请

WO2012017038A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012017038A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/063447
申请日：2011-08-04
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Jochem T. M.
发明人： MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Jochem T. M.
IPC分类号： C08F10/06 , C08F4/651 , C08F4/646
CPC分类号： C08F10/06 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F4/6545
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor of Formula (I) in which R, R 1 and R 4 groups, equal to or different from each other, are C 1 -C 15 hydrocarbon groups and the R groups can be linked to form a cycle, R 2 -R 3 groups, equal to or different from each other, are selected from hydrogen and C 1 -C 15 hydrocarbon groups, the R 1 -R 4 groups can optionally contain an heteroatom selected from halogen, P, S, N,O and Si, n is an integer from 0 to 5 and said electron donor and Ti atoms being present in an amount such that their molar ratio is equal to, or lower than, 0.65.
摘要翻译：包含Mg，Ti和其中R，R 1和R 4基团彼此相同或不同的R，R 1和R 4基团的式（I）的电子给体的烯烃聚合用催化剂组分是C1-C15烃基，R基团可以连接为了形成一个循环，相同或不同的R2-R3基团选自氢和C1-C15烃基，R1-R4基团可任选地含有选自卤素，P，S，N，O的杂原子和Si，n为0至5的整数，并且所述电子给体和Ti原子的存在量使得它们的摩尔比等于或低于0.65。

4. 发明申请

WO2011107371A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2011107371A1
公开(公告)日：2011-09-09
申请号：PCT/EP2011/052566
申请日：2011-02-22
申请人： BASELL POLIOLEFINE ITALIA SRL , GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochemm, T., M. , MORINI, Giampiero
发明人： GUIDOTTI, Simona , PIEMONTESI, Fabrizio , PATER, Jochemm, T., M. , MORINI, Giampiero
IPC分类号： C08F4/651 , C08F110/06 , C08F4/654 , C08F4/646
CPC分类号： C08F110/06 , C08F4/6545 , C08F4/651 , C08F4/6465 , C08F2500/15
摘要： Catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected those of formula (I) wherein: R 2 , equal to or different from each other, are hydrogen atoms or C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements or alkoxy groups of formula -OR 1 , two or more of the R 2 groups can be connected together to form a cycle; R 1 , equal to or different from each other, are C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the periodic table of the elements, with the proviso that at least one of R 2 is -OR 1 and the other being selected from succinates of formula (II): wherein the radicals R 1 and R II , equal to or different from each other, are a C 1 -C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms; the radicals R III to R IV equal to or different from each other, are hydrogen or a C 1 - C 20 linear or branched alkyl, alkenyl, cycloalkyl, aryl, arylalkyl or alkylaryl group, optionally containing heteroatoms, and the radicals R III to R VI which are joined to the same carbon atom of the succinate chain can be linked together to form a cycle.
摘要翻译：用于烯烃CH 2 = CHR的聚合的催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和两个电子给体化合物，其中一个选自式（I）的那些，其中：R 2 彼此相同或不同的是氢原子或任选含有属于式-OR1的元素或烷氧基的周期表第13-17族的杂原子的C1-C20烃基，R2基中的两个或更多个可以连接在一起形成一个循环; R1彼此相同或不同的是C1-C20烃基，其任选地含有属于元素周期表第13-17族的杂原子，条件是R 2中的至少一个为-OR 1且另一个选自来自式（II）的琥珀酸盐：其中基团R 1和R II彼此相同或不同，为任选含有杂原子的C 1 -C 20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基; RIII至RIV彼此相同或不同的基团是氢或任选含有杂原子的C 1-20直链或支链烷基，烯基，环烷基，芳基，芳基烷基或烷基芳基，以及RIII至RVI基团连接至琥珀酸酯链的相同碳原子可以连接在一起形成循环。

5. 发明申请

WO2012139897A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012139897A1
公开(公告)日：2012-10-18
申请号：PCT/EP2012/055593
申请日：2012-03-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
发明人： GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
IPC分类号： C08F10/06 , C08F4/651
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.
摘要翻译：一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于： ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于，0.60。

6. 发明申请

WO2009150106A1 CATALYST FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：WO2009150106A1
公开(公告)日：2009-12-17
申请号：PCT/EP2009/056952
申请日：2009-06-05
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , FUSHIMI, Masaki , KRISTEN, Marc Oliver , SCHNEIDER, Martin , MORINI, Giampiero
发明人： FUSHIMI, Masaki , KRISTEN, Marc Oliver , SCHNEIDER, Martin , MORINI, Giampiero
IPC分类号： C08F4/646 , C08F10/00
CPC分类号： C08F10/02 , C08F10/00 , C08F4/6493
摘要： The present invention relates to catalysts systems for the polymerization of olefins CH 2 =CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising (A) a solid catalyst component comprising Ti, Mg, and halogen (B) an aluminum alkyl compound and (C) a brominated cyclic hydrocarbon. Said catalyst systems have improved polymerization activity.
摘要翻译：本发明涉及用于烯烃CH 2 = CHR聚合的催化剂体系，其中R是具有1-12个碳原子的烷基，环烷基或芳基，其包含（A）包含Ti，Mg和卤素（B ）烷基铝化合物和（C）溴化环状烃。所述催化剂体系具有改善的聚合活性。

7. 发明申请

WO2012052389A1 PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS 审中-公开
标题翻译：制备高纯丙烯聚合物的方法
公开(公告)号：WO2012052389A1
公开(公告)日：2012-04-26
申请号：PCT/EP2011/068084
申请日：2011-10-17
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , PATER, Joachim T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , MORINI, Giampiero , VITALE, Gianni
发明人： PATER, Joachim T., M. , GUIDOTTI, Simona , MIGNOGNA, Alessandro , MORINI, Giampiero , VITALE, Gianni
IPC分类号： C08F10/06 , C08J5/18 , C08F4/654 , C08F4/651
CPC分类号： C08F10/06 , C08F4/651 , C08F4/6543
摘要： A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by reacting:- an organo-aluminium compound, with - a solid catalyst component comprising Mg, Ti and electron donor compound selected from specific diolesters, said process being carried out employing an organo-aluminum/propylene ratio equal to or lower than 1.75 mmole/kg.
摘要翻译：一种用于制备高纯度丙烯聚合物的方法，该催化剂在催化剂存在下进行，所述催化剂包括通过使有机铝化合物与包含Mg，Ti和选自特定二极体的电子给体化合物的固体催化剂组分反应而获得的产物所述方法使用等于或低于1.75mmol / kg的有机铝/丙烯比进行。

8. 发明申请

WO2012175425A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012175425A1
公开(公告)日：2012-12-27
申请号：PCT/EP2012/061466
申请日：2012-06-15
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Joachim, T. M.
发明人： MIGNOGNA, Alessandro , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Joachim, T. M.
IPC分类号： C08F10/00 , C08F4/651
CPC分类号： C08F4/50 , C08F4/16 , C08F10/00 , C08F110/06 , C08F4/651 , C08F2500/12 , C08F4/6541
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R 1 to R 4 groups, equal to or different from each other, are hydrogen, C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and S i ,, R 6 group is selected from C 1 -C 15 hydrocarbon groups optionally containing an heteroatom selected from halogen, P, S, N and Si, and R 5 is selected from phenyl groups mono or poly substituted with halogens, said groups R 1 -R 4 being also optionally linked to form a saturated or unsaturated mono or poly cycle.
摘要翻译：包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分，其中相同或不同的R 1至R 4基团为氢，任选地含有选自卤素，P，S，N和Si，R 6基团的杂原子选自任选含有选自卤素，P，S，N和Si的杂原子的C 1 -C 15烃基，R 5选自苯基单或多被卤素取代，所述基团R 1 -R 4也任选地连接形成饱和或不饱和的单或多环。

9. 发明申请

WO2012052387A1 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2012052387A1
公开(公告)日：2012-04-26
申请号：PCT/EP2011/068080
申请日：2011-10-17
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MORINI, Giampiero , GUIDOTTI, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M.
发明人： MORINI, Giampiero , GUIDOTTI, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M.
IPC分类号： C08F10/06 , C08F4/651 , C08F4/654 , C08F4/649
CPC分类号： C08F4/16 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/6494 , C08F4/651 , C08F2/14 , C08F2500/03 , C08F2500/12
摘要： A catalyst system comprising the product obtained by contacting (a) a solid catalyst component containing Mg, Ti, halogen and at least an electron donor compound selected from diolesters of a specific formula (b) an alkylaluminum cocatalyst and (c) an ester of formula R'OOC-(CR" 2 ) m -COOR' in which m is an integer from 2 to 8, the R' groups, equal to or different from each other, are C1-C10 alkyl groups and the R" groups, independently, are hydrogen or C1 -C15 hydrocarbon groups.
摘要翻译：一种催化剂体系，其包括通过使（a）含有Mg，Ti，卤素和至少一种选自特定式（b）的二极体的电子给体化合物的（a）固体催化剂组分与烷基铝助催化剂和（c）式 R'OOC-（CR“2）m-COOR'，其中m为2至8的整数，R'基彼此相同或不同，为C1-C10烷基，R”基团独立地为是氢或C 1 -C 15烃基。

10. 发明申请

WO2012017040A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012017040A1
公开(公告)日：2012-02-09
申请号：PCT/EP2011/063450
申请日：2011-08-04
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MORINI, Giampiero , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MIGNOGNA, Alessandro , Pater, Jochem, T., M.
发明人： MORINI, Giampiero , BALBONI, Davide , CRISTOFORI, Antonio , GUIDOTTI, Simona , MIGNOGNA, Alessandro , Pater, Jochem, T., M.
IPC分类号： C08F10/06 , C08F4/651 , C08F4/646 , C08F4/654
CPC分类号： C08F4/6494 , C08F10/06 , C08F4/6465 , C08F4/651 , C08F4/6543
摘要： A catalyst component for the polymerization of olefins comprising Mg, Ti and at least two electron donor compounds, one of which (A) belonging to specific diolesters and the other electron donor compound (B) being selected from aromatic monoesters of the following formula (B) in which R groups equal to or different from each other, are selected from C 1 -C 15 hydrocarbon groups which can be also linked to form one or more cycles, m is an integer from 1 to 5 and R 5 is a C 1 -C 15 alkyl group, said electron donors A and B being in amounts such that the A/B molar ratio is lower than 20.
摘要翻译：一种用于烯烃聚合的催化剂组分，包括Mg，Ti和至少两种电子给体化合物，其中一种（A）属于特定二极体，另一种电子给体化合物（B）选自下式的芳族单酯（B ）其中R基彼此相同或不同，选自可以连接形成一个或多个周期的C 1 -C 15烃基，m是1至5的整数，R 5是C 1 -C 15烷基所述电子给体A和B的量使得A / B摩尔比低于20。

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