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1. 发明申请

WO2004048424A1 BUTENE-1 COPOLYMERS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译： BUTENE-1共聚物及其制备方法
公开(公告)号：WO2004048424A1
公开(公告)日：2004-06-10
申请号：PCT/EP2003/012233
申请日：2003-11-03
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni , BIGIAVI, Daniele , PELLICONI, Anteo , GARAGNANI, Enea , BAITA, Pietro
发明人： MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni , BIGIAVI, Daniele , PELLICONI, Anteo , GARAGNANI, Enea , BAITA, Pietro
IPC分类号： C08F210/08
CPC分类号： C08L23/04 , C08F10/00 , C08F210/08 , C08L23/14 , C08L23/22 , C08L2666/06 , C08F4/651 , C08F4/6543 , C08F4/6465 , C08F210/06 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/11 , C08F2500/20 , C08F210/16 , C08F2/001
摘要： The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios rl·r2≤2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
摘要翻译：本发明涉及含有至多40摩尔％乙烯和/或丙烯的丁烯-1共聚物，其特征在于以下性质：d）反应性比率r r.r2 <= 2的产物; e）全同立构五元组（mmmm）形式的丁烯-1单元含量> 98％; 和f）不存在4,1个丁烯单元的插入。

2. 发明申请

WO2005014715A1 POLYOLEFIN COMPOSITION HAVING A HIGH BALANCE OF STIFFNESS AND IMPACT STRENGTH 审中-公开
标题翻译：具有高平衡强度和冲击强度的聚烯烃组合物
公开(公告)号：WO2005014715A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/008720
申请日：2004-08-03
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , GARAGNANI, Enea , PELLICONI, Anteo
发明人： GARAGNANI, Enea , PELLICONI, Anteo
IPC分类号： C08L23/10
CPC分类号： C08L23/10 , B60R19/03 , C08L23/16 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2308/00 , C08L2314/02 , C08L2666/06 , C08L2666/02
摘要： A polyolefin composition comprising (percentage by weight): (A) from 60 to 85% of a broad molecular weight distribution propylene polymer (component A) having a polydispersity index from 5 to 15 and melt flow rate of from 20 to 78 g/10 min (according to ASTM-D 1238, condition L); and (B) from 15 to 40% of a partially xylene-soluble olefin polymer rubber (component B) containing at least 65% by weight of ethylene. Said composition finds application in automotive field.
摘要翻译：包含（重量百分数）的聚烯烃组合物：（A）60至85％的分子量分布丙烯聚合物（组分A），其多分散指数为5至15，熔体流动速率为20至78g / 10 min（根据ASTM-D 1238，条件L）; 和（B）含有至少65重量％乙烯的部分二甲苯可溶性烯烃聚合物橡胶（组分B）的15至40％。所述组合物在汽车领域中得到应用。

3. 发明申请

WO2004087805A1 POLYOLEFIN MASTERBATCH AND COMPOSITION SUITABLE FOR INJECTION MOLDING 审中-公开
标题翻译：聚氨酯主要成分和适用于注射成型的组合物
公开(公告)号：WO2004087805A1
公开(公告)日：2004-10-14
申请号：PCT/EP2004/003304
申请日：2004-03-29
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , PELLICONI, Anteo , GARAGNANI, Enea , ENNIS, Gerald, J.
发明人： PELLICONI, Anteo , GARAGNANI, Enea , ENNIS, Gerald, J.
IPC分类号： C08L23/10
CPC分类号： C08L23/10 , C08F110/06 , C08F210/06 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2205/03 , C08L2207/02 , C08L2308/00 , C08L2310/00 , C08L2314/02 , C08L2666/02 , C08F2500/12 , C08F2500/19 , C08F2500/17 , C08F210/16
摘要： A masterbatch composition comprising (percent by weight): A) 50%-90% of a crystalline polypropylene component comprising: A I ) from 25% to 75% of a fraction having a melt flow rate MFR I of from 0.1 to 10 g/10 min.; and A II ) from 75% to 25% of a fraction having a melt flow rate value MFR II equal to or lower than 100 g/10 min.; wherein the ratio MFR I /MFR II is from 5 to 60; and B) 10%-50% of a copolymer component of ethylene and at least one C 3 -C 10 α-olefin, containing from 15% to 50% of ethylene; said masterbatch composition having a value of the intrinsic viscosity [η] of the fraction soluble in xylene at room temperature equal to or higher than 3.5 dl/g, is added to polyolefin materials to obtain final compositions suitable for injection molding.
摘要翻译：包含（重量％）的母料组合物：A）50％-90％的结晶聚丙烯组分，其包含：A）25％至75％的熔体流动速率MFR为0.1至10g / 10min的级分。和A II），其熔体流动速率值MFR 等于或低于100g / 10分钟的馏分的75％至25％。其中MFR / MFR II的比率为5至60; 和B）含有15％至50％乙烯的乙烯和至少一种C 3 -C 10α-烯烃的共聚物组分的10％-50％所述母料组合物具有在室温下等于或高于3.5dl / g的可溶于二甲苯的级分的特性粘度η的值加入到聚烯烃材料中以获得适于注塑的最终组合物。

4. 发明申请

WO2003076511A1 “POLYOLEFIN MASTERBATCH FOR PREPARING IMPACT-RESISTANT POLYOLEFIN ARTICLES” 审中-公开
标题翻译： “POLYOLEFIN MASTERBATCH FOR PRBRARING IMPACT-RESIDANT POLYOLEFIN ARTICLES”
公开(公告)号：WO2003076511A1
公开(公告)日：2003-09-18
申请号：PCT/EP2003/002518
申请日：2003-03-06
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , PELLICONI, Anteo , GARAGNANI, Enea , YOKOYAMA, Yutaka , WASHIYAMA, Junichiro , TAKENOUCHI, Hiroshi , NAKAJIMA, Takeshi
发明人： PELLICONI, Anteo , GARAGNANI, Enea , YOKOYAMA, Yutaka , WASHIYAMA, Junichiro , TAKENOUCHI, Hiroshi , NAKAJIMA, Takeshi
IPC分类号： C08L23/16
CPC分类号： C08F10/00 , C08F110/06 , C08F210/16 , C08L23/0815 , C08L23/12 , C08L23/16 , C08L2314/02 , C08F2/001 , C08L2666/04 , C08F2500/12 , C08F2500/18 , C08F2500/17 , C08F210/06 , C08F210/08
摘要： A masterbatch composition comprising (1) 10-50 wt% of a crystalline propylene homopolymer and (2) 50-90 wt% of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt%, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 dL/g, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.
摘要翻译：一种母料组合物，其包含110-50重量％的结晶丙烯均聚物和2 50-90重量％的由乙烯和一种或多种C 4 -C 10α-烯烃的共聚物组成的共混物，其包含10-40个C 4 -C 10 α-烯烃，和b是丙烯和乙烯的无定形共聚物。共聚物b的乙烯含量为20-70重量％，二甲苯可溶部分的特性粘度值为2.2〜3.5dL / g，该值等于二甲苯 - 可溶部分的特性粘度值的0.8〜1.2倍，共聚物a的可溶性部分。共聚物a / b的重量比为3/1〜1/3。包含所述母料组合物的聚烯烃组合物适于制造汽车部件。

5. 发明申请

WO2003031514A1 CRYSTALLINE PROPYLENE COPOLYMER COMPOSITIONS HAVING IMPROVED SEALABILITY AND OPTICAL PROPERTIES AND REDUCED SOLUBILITY 审中-公开
标题翻译：具有改进的密封性和光学性能和降低溶解性的结晶丙烯共聚物组合物
公开(公告)号：WO2003031514A1
公开(公告)日：2003-04-17
申请号：PCT/EP2002/011129
申请日：2002-10-04
申请人： BASELL POLIOLEFINE ITALIA, S.P.A. , PELLICONI, Anteo , GARAGNANI, Enea , SGARZI, Paola
发明人： PELLICONI, Anteo , GARAGNANI, Enea , SGARZI, Paola
IPC分类号： C08L23/14
CPC分类号： C08L23/142 , C08L2205/02 , C08L2205/025 , C08L2666/04
摘要： Propylene polymer compositions comprising (by weight): A) from 15% to 60% with C 4 -C 8 alpha-olefin(s), containing more than 10%, but less than 14%, of said C 4 -C 8 alpha-olefins (s); B) from 40% to 85% of a copolymer of propylene with C 4 -C 8 alpha-olefin(s), preferably butene, containing from 14% to 30% of said C 4 -C 8 alpha-olefin(s), and optionally from 0,5% to 3% of ethylene; provided that the total content of C 4 -C 8 alpha-olefin(s) in the propylene polymer composition be higher than 10%.
摘要翻译：丙烯聚合物组合物包含（重量）：A）15％至60％的C 4 -C 8α-烯烃，其含有超过10％但小于14％的所述C 4 -C 8α-烯烃（s ）; B）40％至85％的丙烯与C 4 -C 8α-烯烃（优选丁烯）的共聚物，其含有14％至30％的所述C 4 -C 8α-烯烃，并且任选地为0 ，5％至3％的乙烯; 丙烯聚合物组合物中的C 4 -C 8α-烯烃的总含量高于10％。

6. 发明申请

WO2003011962A1 SOFT POLYOLEFIN COMPOSITIONS 审中-公开
标题翻译：软的聚烯烃组合物
公开(公告)号：WO2003011962A1
公开(公告)日：2003-02-13
申请号：PCT/EP2002/003880
申请日：2002-04-08
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , PELLICONI, Anteo , GARAGNANI, Enea , VILLANUEVA, Alvaro
发明人： PELLICONI, Anteo , GARAGNANI, Enea , VILLANUEVA, Alvaro
IPC分类号： C08L23/10
CPC分类号： C08F210/06 , C08F297/08 , C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2207/02 , C08L2308/00 , C08L2314/02 , C08F2/001 , C08L2666/04 , C08F210/16 , C08F2500/17 , C08F2500/12
摘要： A polyolefin composition comprising: (A) from 8 to 25% by weight of a crystalline homopolymer or copolymer of propylene: (B) from 75 to 92% by weight of an elastomeric fraction comprising: (1) a first elastomeric copolymer of propylene with from 15 to 32% by weight at least one alpha-olefin of formula H 2 C=CHR, where R is H or a C 2-6 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, said first elastomeric copolymer containing alpha-olefin, and having solubility in xylene at room temperature greater than 50% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 3.0 to 5.0 dl/g; and (2) a second elastomeric copolymer of propylene with at least one alpha-olefin of formula H 2 C=CHR, where R is H or a C 2-6 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, said second elastomeric copolymer containing more than 32% up to 45% by weight alpha-olefin, and having solubility in xylene at room temperature greater than 80% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 4.0 to 6.5 dl/g; the (1)/(2) weight ratio ranging from 1:5 to 5:1.
摘要翻译：一种聚烯烃组合物，其包含：（A）8至25重量％的结晶均聚物或丙烯共聚物：（B）75至92重量％的弹性体部分，其包含：（1）丙烯与 15至32重量％的至少一种式H2C = CHR的α-烯烃，其中R为H或任选含有0.5至5重量％二烯的C 2-6直链或支链烷基，所述第一弹性体共聚物含有并且在室温下在二甲苯中的溶解度大于50重量％，二甲苯可溶部分的特性粘度为3.0-5.0dl / g; 和（2）丙烯与至少一种式H2C = CHR的α-烯烃的第二弹性体共聚物，其中R是H或任选含有0.5至5重量％二烯的C 2-6直链或支链烷基，所述第二弹性体共聚物含有超过32％至45％（重量）的α-烯烃，并且在室温下在二甲苯中的溶解度大于80％（重量），二甲苯可溶级分的特性粘度为4.0至6.5dl / g; （1）/（2）重量比为1:5至5:1。

7. 发明申请

WO2005121240A1 POLYOLEFIN COMPOSITION HAVING A HIGH BALANCE OF STIFFNESS, IMPACT STRENGTH AND ELONGATION AT BREAK AND LOW THERMAL SHRINKAGE 审中-公开
标题翻译：具有高平衡性，耐冲击强度和断裂强度低热收缩的聚烯烃组合物
公开(公告)号：WO2005121240A1
公开(公告)日：2005-12-22
申请号：PCT/EP2005/005881
申请日：2005-05-30
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , PELLICONI, Anteo , GARAGNANI, Enea
发明人： PELLICONI, Anteo , GARAGNANI, Enea
IPC分类号： C08L23/10
CPC分类号： C08F297/083 , C08F210/16 , C08L23/0807 , C08L23/0815 , C08L23/0853 , C08L23/0869 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/16 , C08L91/00 , C08L2205/02 , C08L2205/03 , C08L2308/00 , C08L2314/02 , C08L23/00 , C08L2666/06 , C08L2666/02 , C08F210/08 , C08F2500/12 , C08F2500/21 , C08F2500/11
摘要： Polymer composition showing an improved balance of flexural modulus, IZOD impact strength and elongation at break comprising (percent by weight): A) a polymer blend comprising: A1) 50-70% of a crystalline propylene homopolymer or copolymer; and A2) 30-50% of one or more copolymer(s) of ethylene with one or more C 4 -C 10 α-olefin(s) containing from 15 to 35% of said C 4 -C 10 α-olefin(s); said polymer blend (A) having values of MFR equal to or higher than 10g/10 min., a total content C 4 -C 10 α-olefin(s) equal to or higher than 8% and an intrinsic viscosity value of the fraction soluble in xylene at room temperature of from 1.3 to 2 dl/g, the amounts of (A1) and (A2) being referred to the total weight of the polymer blend; and optionally B) 1-15% of an elastomeric polymer different from A2), having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points; and/or C) 0.5-20% of a mineral filler; the amounts of optional components (B) and (C) being referred to the total weight of the composition.
摘要翻译：显示改善的弯曲模量，IZOD冲击强度和断裂伸长率平衡的聚合物组合物，其包含（重量％）：A）包含：A1）50-70％的结晶丙烯均聚物或共聚物的聚合物共混物; 和A2）30-50％的一种或多种乙烯共聚物与一种或多种含有15至35％所述C 4 -C 10α-烯烃的C 4 -C 10α-烯烃; 所述聚合物共混物（A）的MFR值等于或高于10g / 10分钟，总含量等于或高于8％的C 4 -C 10α-烯烃和可溶于二甲苯在室温下为1.3至2dl / g，（A1）和（A2）的量指的是聚合物共混物的总重量; 和任选的B）1-15％不同于A2）的弹性体聚合物，其硬度（肖氏A，ASTM D-2240）值等于或低于90分; 和/或C）0.5-20％的矿物填料; 任选组分（B）和（C）的量被称为组合物的总重量。

8. 发明申请

WO2005103140A1 POLYOLEFIN MASTERBATCH AND COMPOSITION SUITABLE FOR INJECTION MOLDING 审中-公开
标题翻译：聚氨酯主要成分和适用于注射成型的组合物
公开(公告)号：WO2005103140A1
公开(公告)日：2005-11-03
申请号：PCT/EP2005/003027
申请日：2005-03-22
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , PELLICONI, Anteo , GARAGNANI, Enea , PELLEGATTI, Giampaolo , ANGELINI, Antonella
发明人： PELLICONI, Anteo , GARAGNANI, Enea , PELLEGATTI, Giampaolo , ANGELINI, Antonella
IPC分类号： C08L23/14
CPC分类号： C08J3/226 , C08F110/06 , C08F210/06 , C08J2323/04 , C08J2423/00 , C08L23/04 , C08L23/10 , C08L23/12 , C08L23/142 , C08L23/16 , C08L91/00 , C08L2205/02 , C08L2205/035 , C08L2308/00 , C08L2310/00 , C08L2314/02 , C08L23/00 , C08L2666/02 , C08L2666/06 , C08F2500/12 , C08F2500/17 , C08F210/16
摘要： A masterbatch composition comprising (percent by weight): A) 15%-50% of a polypropylene component having a melt flow rate of from 1 to 250 g/10 min.; and B) 50%-85% of an olefin polymer partially soluble in xylene at room temperature, containing from 60% to 85% by weight of ethylene; said masterbatch composition having (i) a value of the intrinsic viscosity [rl] of the fraction soluble in xylene at room temperature ([rl] SO l) equal to or lower than 2.9 dl/g, and (ii) a value of the ratio MFR / [TI],,,, equal to or lower than 4, is added to polyolefin materials to obtain final compositions suitable for injection molding.
摘要翻译：包含（重量％）的母料组合物：A）15％-50％的熔体流动速率为1至250g / 10min的聚丙烯组分; 和B）在室温下部分溶于二甲苯的50％-85％的烯烃聚合物，含有60％至85％（重量）的乙烯; 所述母料组合物具有（i）等于或低于2.9dl / g的可溶于二甲苯的级分的特性粘度[r1]的值等于或低于2.9dl / g，和（ii）所述比例的值等于或低于4的MFR / [TI] ,,被加入到聚烯烃材料中以获得适于注射成型的最终组合物。

9. 发明申请

WO2004050713A3 1-BUTEN COPOLYMERS AND PROCESS FOR PREPARING THEM 审中-公开
公开(公告)号：WO2004050713A3
公开(公告)日：2004-06-17
申请号：PCT/EP2003/012944
申请日：2003-11-14
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , PELLICONI, Anteo , GARAGNANI, Enea
发明人： RESCONI, Luigi , PELLICONI, Anteo , GARAGNANI, Enea
IPC分类号： C08F210/08
摘要： A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH 2 =CHZ, wherein Z is a C 3 C 20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R 1 and R 3 are hydrocarbon groups; R 2 and R 4 are hydrogen atoms or hydrocarbon groups; T 1 and T 2 , equal to or different from each other are a moiety of formula (lI), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R 5 , R 6 , R 7 , R 8 and R 9 , equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.

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