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    • 1. 发明申请
    • METHOD FOR PROVIDING AN ORDERED LAYER OF SELF-ASSEMBLABLE POLYMER FOR USE IN LITHOGRAPHY
    • 用于提供自组装聚合物的订购层的方法用于LITHOGRAPHY
    • WO2011128120A1
    • 2011-10-20
    • PCT/EP2011/050668
    • 2011-01-19
    • ASML NETHERLANDS B.V.PEETERS, EmielWUISTER, SanderKOOLE, Roelof
    • PEETERS, EmielWUISTER, SanderKOOLE, Roelof
    • G03F7/00
    • G03F7/0002B82Y10/00B82Y40/00
    • A method for providing an ordered polymer layer at a surface of a substrate includes depositing a self-assemblable polymer layer directly onto a primer layer on a substrate to provide an interface between the self-assemblable polymer layer and the primer layer, and treating the self-assemblable polymer layer to provide self-assembly into an ordered polymer layer, such as a block copolymer, having first and second domain types at the interface. The primer layer is adapted to improve its chemical affinity to each domain type at the interface, in response to the presence of the respective domain type in the self-assembled polymer at the interface during the self-assembly of the self-assemblable polymer layer into the ordered polymer layer. This may lead to reduction in defect levels and/or improved persistence length for the ordered polymer layer. The method may be useful for forming resist layers for use in device lithography.
    • 在衬底的表面提供有序聚合物层的方法包括将可自组装的聚合物层直接沉积在基底上的底漆层上,以提供可自组装的聚合物层和底漆层之间的界面,以及处理自身 可以将聚合物层自组装成有序聚合物层,例如在界面处具有第一和第二域类型的嵌段共聚物。 响应于在自组装聚合物层的自组装期间在界面处的自组装聚合物中存在相应的畴型,引物层适于改善其在界面处对每种畴型的化学亲和力 有序聚合物层。 这可能导致有序聚合物层的缺陷水平和/或改善的持续长度的降低。 该方法可用于形成用于器件光刻的抗蚀剂层。
    • 3. 发明申请
    • SELF-ASSEMBLABLE POLYMER AND METHOD FOR USE IN LITHOGRAPHY
    • 自组装聚合物和方法用于光刻
    • WO2011151109A1
    • 2011-12-08
    • PCT/EP2011/056308
    • 2011-04-20
    • ASML Netherlands B.V.PEETERS, EmielWUISTER, SanderKOOLE, Roelof
    • PEETERS, EmielWUISTER, SanderKOOLE, Roelof
    • C08F293/00G03F7/00B81C1/00B82Y10/00B82Y30/00
    • C08F293/00B05D5/00B82Y10/00B82Y30/00B82Y40/00C08F297/04G03F7/0002G03F7/004G03F7/165G03F7/26
    • A self-assemblable polymer is disclosed, having first and second molecular configurations with the first molecular configuration has a higher Flory Huggins parameter for the self-assemblable polymer than the second molecular configuration, and the self-assemblable polymer is configurable from the first molecular configuration to the second molecular configuration, from the second molecular configuration to the first molecular configuration, or both, by the application of a stimulus. The polymer is of use in a method for providing an ordered, periodically patterned layer of the polymer on a substrate, by ordering and annealing the polymer in its second molecular configuration and setting the polymer when it is in the first molecular configuration. The second molecular configuration provides better ordering kinetics and permits annealing of defects near its order/disorder transition temperature, while the first molecular configuration, with a higher order/disorder transition temperature, provides low line edge/width roughness for the pattern formed on setting.
    • 公开了具有第一和第二分子构型的自组装聚合物,其具有第一分子构型,其具有比第二分子构型更高的可自组装聚合物的Flory Huggins参数,并且可自组装聚合物可从第一分子构型 到第二分子构型,从第二分子构型到第一分子构型,或两者都通过施加刺激。 聚合物可用于通过在其第二分子构型中排列和退火聚合物并在聚合物处于第一分子构型时设置聚合物,从而在基底上提供聚合物的有序周期性图案化层的方法。 第二种分子结构提供更好的排序动力学,并允许在其顺序/无序转变温度附近的缺陷退火,而具有较高阶/无序转变温度的第一分子构型为设置上形成的图案提供了低的线边缘/宽度粗糙度。