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1. 发明申请

WO1994025517A1 CURED UNSATURATED POLYESTERS GLYCOLYSIS FOR RECYCLE REACTANT 审中-公开
标题翻译：固化不饱和聚酯树脂回收再利用
公开(公告)号：WO1994025517A1
公开(公告)日：1994-11-10
申请号：PCT/US1994004864
申请日：1994-05-03
申请人： ASHLAND OIL, INC. , TUFTS, Timothy, A. , TSAI, Chung-Chieh , HUPP, Stephen, S.
发明人： ASHLAND OIL, INC.
IPC分类号： C08J11/24
CPC分类号： C08J11/24 , C08J11/06 , C08J2367/06 , Y02P20/582 , Y02W30/701 , Y02W30/706
摘要： The present invention is directed to a method for treating cross-linked (cured) filled or unfilled unsaturated polyester for deriving an alcohol recycle reactant useful in the synthesis of alcohol-formed derivative products. The first step of the method is the attrition of the cured unsaturated polyester to form particulates thereof. In the next step of the process, at least a fraction of any filler or fiberglass in the cured unsaturated polyester is separated to form a cured unsaturated polyester regrind. The next step is the subjecting of the cured unsaturated polyester regrind to agitated, uncatalyzed or catalyzed glycolysis in the presence of excess glycol and, optionally, a transesterification catalyst under agitation at elevated transesterification temperature. The final step of the process is the recovery of the recycle alcohol reactant for use in the synthesis of alcohol-formed derivative products. The glycolysis reaction is conducted under agitation in order to keep the cured unsaturated polyester regrind solids suspended during the glycolysis reaction. In this regard, establishment of shear conditions should aid in the glycolysis step of the process.
摘要翻译：本发明涉及一种用于处理交联（固化的）填充或未填充的不饱和聚酯以得到可用于合成醇形成的衍生产物的醇再循环反应物的方法。该方法的第一步是固化的不饱和聚酯的磨损以形成其颗粒。在该方法的下一步骤中，将固化的不饱和聚酯中的任何填料或玻璃纤维的至少一部分分离以形成固化的不饱和聚酯再研磨物。下一步是在过量的二醇和任选的酯交换催化剂的搅拌下，在升高的酯交换温度下使经固化的不饱和聚酯再研磨物进行搅拌，未催化或催化的糖酵解。该方法的最后一步是回收用于合成醇形成衍生产物的循环醇反应物。在搅拌下进行糖酵解反应，以便在糖酵解反应期间保持固化的不饱和聚酯再研磨固体。在这方面，剪切条件的建立应有助于该过程的糖酵解步骤。

2. 发明申请

WO1995013318A1 ENHANCERS FOR THERMOPLASTIC LOW PROFILE ADDITIVES 审中-公开
标题翻译：热塑性低配置添加剂的增强剂
公开(公告)号：WO1995013318A1
公开(公告)日：1995-05-18
申请号：PCT/US1994013011
申请日：1994-11-14
申请人： ASHLAND OIL, INC. , FISHER, Dennis, H. , TUFTS, Timothy, A. , MOSS, C., Timothy
发明人： ASHLAND OIL, INC.
IPC分类号： C08K05/11
CPC分类号： C08L67/06 , C08L2666/02
摘要： This invention is the polycapped oligomer adduct of a long chain fatty acid with a multi hydroxy functional or multi epoxy functional compound. This polycapped oligomer is useful in resin compositions to enhance the performance of thermoplastic low profile additives which improve the surface quality of molded composites such as automotive body panels.
摘要翻译：本发明是长链脂肪酸与多羟基官能或多环氧官能化合物的多孔低聚物加合物。这种聚合低聚物可用于树脂组合物中，以增强热塑性低分子添加剂的性能，其改善了模塑复合材料如汽车车身板的表面质量。

3. 发明申请

WO1995019231A1 HEAT REACTIVATABLE ADHESIVE 审中-公开
标题翻译：热反应胶
公开(公告)号：WO1995019231A1
公开(公告)日：1995-07-20
申请号：PCT/US1995000418
申请日：1995-01-11
申请人： ASHLAND OIL, INC. , MAGRUM, Glenn, R. , STOVER, Jack, A.
发明人： ASHLAND OIL, INC.
IPC分类号： B05D05/10
CPC分类号： C09J125/14 , B32B37/12 , C08L23/08 , C08L25/08 , C08L25/14 , C08L91/06 , C08L2666/02 , C08L2666/04 , C09J5/06 , C09J11/06 , C09J123/08 , C09J133/062 , C09J2423/00 , C09J2425/00
摘要： This invention is a method of using a heat activatable adhesive for laminating vinyl sheet to wood. The solvent-free adhesive combines a reactive styrene-acrylic latex emulsion and an ethylene-vinylacetate copolymer. After application to the vinyl substrate the adhesive is heat activated at temperatures as low as 160 DEG F (71 DEG C) and the laminate resists 200 DEG F (93 DEG C).
摘要翻译：本发明是使用可热活化的粘合剂将乙烯基板层压到木材上的方法。无溶剂粘合剂将反应性苯乙烯 - 丙烯酸胶乳乳液和乙烯 - 乙酸乙烯酯共聚物组合。在施加到乙烯基材料之后，粘合剂在低于160°F（71℃）的温度下热活化，并且层压板抵抗200°F（93℃）。

4. 发明申请

WO1995016010A1 IMPROVED MOLTEN METAL DECOMPOSITION APPARATUS AND PROCESS 审中-公开
标题翻译：改进的金属分解装置和工艺
公开(公告)号：WO1995016010A1
公开(公告)日：1995-06-15
申请号：PCT/US1994013421
申请日：1994-11-16
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , MALONE, Donald, P. , MILLER, Charles, B. , WISEMAN, Jonathan, A.
IPC分类号： C10J03/57
CPC分类号： C10J3/57 , B01J2219/182 , C10J2200/09 , C10J2200/152 , C10J2300/0959 , C10J2300/1659 , C10K3/04 , Y02P20/144
摘要： In an improved molten metal hydrogen generation bath, baffles form a draft tube or chimney-effect near the center of the bath. Flow through the chimney is aided by maintaining a temperature differential favoring convection and, optionally, a differential pressure between the portions of the bath on either side of the baffle-chimney arrangement. Feed is added to the feed zone and oxygen is added to the oxidation zone, emitting H2 from the feed zone and CO from the oxidation zone. Baffles may be made simply of brick work or high temperature metal and can fit into existing refractory-lined molten metal vessels. Products can be mixed as syngas feed for Fischer-Tropsch synthesis. Additionally, the Boudouard endothermic reaction (CO2 + C } 2CO) can be used to control temperatures by injecting CO in place of oxygen.
摘要翻译：在改进的熔融金属氢气生成池中，挡板在浴的中心附近形成引流管或烟囱效应。通过保持有利于对流的温差和任选地在挡板 - 烟囱装置的任一侧上的浴的部分之间的压差来帮助流过烟囱。将进料加入进料区，并将氧气加入到氧化区中，从进料区中排出H 2，从氧化区发射CO。挡板可以简单地由砖工或高温金属制成，并且可以装配到现有的耐火材料衬里的熔融金属容器中。产物可以作为合成气进料混合进行费 - 托合成。另外，Boudouard吸热反应（CO2 + C）2CO）可用于通过注入CO代替氧来控制温度。

5. 发明申请

WO1995008579A1 POLYURETHANE REACTION SYSTEM HAVING A BLOCKED CATALYST COMBINATION 审中-公开
标题翻译：具有阻塞催化剂组合的聚氨酯反应体系
公开(公告)号：WO1995008579A1
公开(公告)日：1995-03-30
申请号：PCT/US1994010512
申请日：1994-09-19
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , SCHOENER, Thomas, E. , HOUSENICK, Jeffrey, B.
IPC分类号： C08F08/30
CPC分类号： C09J175/04 , C08G18/089 , C08G18/163
摘要： Disclosed is a polyol/polyisocyanate adhesive system having an isocyanate component and a catalyzed component which form a heat-cured composition when admixed and heated above a threshold temperature. The catalyzed component has a hydroxyl-functional component catalyzed with a catalyst combination of a heat-activatable amine or amine-like catalyst which is activated at temperatures above the threshold temperature, and an activatable complexed metal catalyst comprising the reaction product of tin or bismuth catalysts, or a mixture thereof, and a molar excess of a mercapto compound complexing agent. The catalyst combination is effective to maintain the processibility of the system at ambient temperatures while promoting the rapid cure of the system when heated above the threshold temperature.
摘要翻译：公开了具有异氰酸酯组分和催化组分的多元醇/多异氰酸酯粘合剂体系，其在高于阈值温度时混合并加热时形成热固化组合物。催化的组分具有羟基官能组分，其催化剂组合是在高于阈值温度的温度下活化的可热激活的胺或类似胺的催化剂，以及可活化的复合金属催化剂，其包含锡或铋催化剂的反应产物，或其混合物，以及摩尔过量的巯基化合物络合剂。催化剂组合对于保持体系在环境温度下的加工性是有效的，同时在加热超过阈值温度时促进系统的快速固化。

6. 发明申请

WO1995003903A2 POLYURETHANE-FORMING BINDER SYSTEMS CONTAINING 2,2'-DIPYRIDYL, 1,10-PHENANTHROLINE, AND THEIR SUBSTITUTED ALKYL DERIVATIVES 审中-公开
标题翻译：包含2,2'-二吡啶，1,10-苯并呋喃及其取代的烷基衍生物的聚氨酯形成粘合剂体系
公开(公告)号：WO1995003903A2
公开(公告)日：1995-02-09
申请号：PCT/US1994007725
申请日：1994-07-12
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , BARNETT, Kenneth, W. , CARPENTER, William, G. , DUNNAVANT, William, R. , FECHTER, Robert, B.
IPC分类号： B22C00/00
CPC分类号： B22C1/2273
摘要： This invention relates to polyurethane-forming foundry binder systems which contain a nitrogen-containing aromatic compound selected from the group consisting of 2,2'-dipyridyl, 1,10-phenanthroline, and their substituted alkyl derivates. The foundry binder systems are particularly useful for making foundry mixes used in the cold-box fabrication process for making foundry shapes. However, the binders systems can also be used to hold foundry shapes, such as molds and cores, together in an assembly.
摘要翻译：本发明涉及含有选自2,2'-联吡啶，1,10-菲咯啉及其取代的烷基衍生物的含氮芳族化合物的聚氨酯形成铸造粘合剂体系。铸造粘合剂系统特别适用于制造用于制造铸造形状的冷箱制造工艺中的铸造混合物。然而，粘合剂系统也可以用于将铸造形状（例如模具和芯）在一起组装在一起。

7. 发明申请

WO1994023863A1 ASSEMBLY OF FOUNDRY SHAPES 审中-公开
标题翻译：基金会形成大会
公开(公告)号：WO1994023863A1
公开(公告)日：1994-10-27
申请号：PCT/US1994003936
申请日：1994-04-11
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , TORDOFF, William, L. , FU, Jiang
IPC分类号： B22C07/02
CPC分类号： B22C9/103 , B22C7/026 , B22C9/20
摘要： This invention relates to an assembly of foundry shapes and a process for making such assemblies of foundry shapes by contacting the foundry shapes with a substrate having a pressure sensitive adhesive on both sides of the substrate. The temperature of such molten metal for non ferrous metals is typically from 600 DEG C to 1000 DEG C while the temperature of ferrous metals is from 1200 DEG C to 1600 DEG C. One of the advantages of this process is that excess adhesive is not squeezed from between the foundry shapes when they are brought into contact with each other. Excess adhesive results in casting defects such as porosity and burn-on.
摘要翻译：本发明涉及铸造形状的组装以及通过使铸造形状与在基板的两侧具有压敏粘合剂的基底接触来制造铸造形状的组件的方法。黑色金属的这种熔融金属的温度通常为600℃至1000℃，而黑色金属的温度为1200℃至1600℃。该方法的优点之一是不会挤压多余的粘合剂当它们彼此接触时，从铸造件之间形成。过多的粘合剂导致诸如孔隙率和老化的铸造缺陷。

8. 发明申请

WO1994017392A1 PROCESS FOR PREDICTING PROPERTIES OF MULTI-COMPONENT FLUID BLENDS 审中-公开
标题翻译：多组分液体混合物预测性能的方法
公开(公告)号：WO1994017392A1
公开(公告)日：1994-08-04
申请号：PCT/US1993001091
申请日：1993-01-21
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , MAGGARD, Steven, M.
IPC分类号： G01N21/35
CPC分类号： G01N21/359 , F02B3/06 , G01N21/3504 , G01N21/3577 , G01N33/2829 , Y10T436/12
摘要： The octane of components used in the blending of gasoline is used to predict the octane of the finished gasoline blend by measuring absorbances, preferably in the near-infrared range, and metering the fraction of each blending component as independent variables and performing a multiple regression on the data modeling the dependent variable of the various octanes. Percent aromatics in diesel fuel and other finished chemical or physical properties of the finished blend can be controlled by feed-forward and/or feed-back techniques.
摘要翻译：用于混合汽油的组分的辛烷用于通过测量吸光度，优选在近红外范围内测量成品汽油混合物的辛烷值，并将每个共混组分的分数计量为自变量并进行多重回归数据建模各种辛烷值的因变量。柴油燃料中的芳族化合物百分数和完成的混合物的其他完成的化学或物理性质可以通过前馈和/或反馈技术来控制。

9. 发明申请

WO1993018074A1 POLYUREAURETHANE PRIMERLESS STRUCTURAL ADHESIVE 审中-公开
标题翻译：聚氨酯无结构粘结剂
公开(公告)号：WO1993018074A1
公开(公告)日：1993-09-16
申请号：PCT/US1993002205
申请日：1993-03-11
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , CHUNG, Daniel, A.
IPC分类号： C08G18/10
CPC分类号： C08J5/124 , C08G18/10 , C08G18/76 , C08G18/797 , C08J2367/06 , C09J175/12 , Y10S528/905 , Y10T428/31565 , C08G18/3225
摘要： This invention is a polyureaurethane structural adhesive for bonding untreated fiberglass reinforced polyester parts used in the manufacture of cars, trucks and boats.
摘要翻译：本发明是一种聚脲氨酯结构粘合剂，用于粘合用于制造汽车，卡车和船只的未经处理的玻璃纤维增强聚酯部件。

10. 发明申请

WO1993008241A1 SUPERPARAMAGNETIC FORMATION ON FCC CATALYST PROVIDES MEANS OF SEPARATION OF OLD EQUILIBRIUM FLUID CRACKING CATALYST 审中-公开
标题翻译： FCC催化剂上的超临界形成提供了老式平衡液体破碎催化剂分离方法
公开(公告)号：WO1993008241A1
公开(公告)日：1993-04-29
申请号：PCT/US1992006494
申请日：1992-07-29
申请人： ASHLAND OIL, INC.
发明人： ASHLAND OIL, INC. , HETTINGER, William, P.
IPC分类号： C10G11/18
CPC分类号： C10G11/182 , C10G11/18
摘要： Improved catalytic process for carrying out heavy hydrocarbon conversion in the presence of metals on the catalyst and in the feedstock, by catalytic cracking such heavy carbometallic oils to lighter molecular weight fractions. The discovery of a ferro/superparamagnetic component of older catalyst, which when present, can be employed to achieve enhanced magnetic separation of aged catalyst. This invention utilizes this property to enhance separation of more magnetically active, older, less catalytically active and selective, higher metals-containing catalyst particulates from less magnetically active, lower metal containing particulates. The more catalytically active and selective catalysts fractions, are then recycled back to the process.
摘要翻译：改进的催化方法，用于在金属存在下在催化剂和原料中进行重质烃转化，通过催化裂化将重质金属油转化成较轻的分子量级分。发现老催化剂的铁/超顺磁组分（其存在时）可用于实现老化催化剂的增强的磁分离。本发明利用该性质来增强从较低磁性活性的较低含金属颗粒物中分离出更多的具有较高活性，较老的，较少催化活性和选择性较高的含金属的催化剂颗粒。然后催化活性和选择性较高的催化剂组分再循环回该方法。

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