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1. 发明申请

WO2019067398A1 COPOLYMERS OF HALOGENATED OLEFINS AND HALOGENATED CO-MONOMERS 审中-公开
公开(公告)号：WO2019067398A1
公开(公告)日：2019-04-04
申请号：PCT/US2018/052559
申请日：2018-09-25
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , LIN, Caiping , POLSZ, Craig Alan , WOOD, Kurt Arthur , KOO, Brian T. , CLARKSON, Lucy , BROTZMAN, Jeffery
IPC分类号： C08F210/16
摘要： Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.

2. 发明申请

WO2014047230A1 IMPROVED STABILITY OF POLYURETHANE POLYOL BLENDS CONTAINING HALOGENATED OLEFIN BLOWING AGENT 审中-公开
标题翻译：含有氢化烯烃发泡剂的聚氨酯多元醇混合物的改进稳定性
公开(公告)号：WO2014047230A1
公开(公告)日：2014-03-27
申请号：PCT/US2013/060510
申请日：2013-09-19
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , COSTA, Joseph S. , ABBAS, Laurent , ELSHEIKH, Maher Y. , SESHADRI, Sri R. , SMITH, Gary S.
IPC分类号： C09K3/00
CPC分类号： C08J9/144 , C08G18/14 , C08G18/1808 , C08G18/1816 , C08G18/1833 , C08G18/4018 , C08G18/4208 , C08G18/4829 , C08G18/6674 , C08G18/72 , C08G2101/0025 , C08J9/0023 , C08J9/0061 , C08J2203/162 , C08J2375/08 , C08J2383/12
摘要： A polyol pre-mix composition includes a blowing agent having a halogenated hydroolefin, a polyol, a catalyst composition, and an antioxidant. The antioxidant may be, for example, a benzene diol or a benzene triol or other polyhydroxy-substituted aromatic compound, which is optionally substituted with one or more substituents such as alkyl groups. A two-part system for producing a thermosetting foam blend includes (a) a polyisocyanate and, optionally, one or more isocyanate compatible raw materials; and (b) the polyol pre-mix composition. A method for producing a thermosetting foam blend includes combining: (a) a polyisocyanate; and (b) the polyol pre-mix composition.
摘要翻译：多元醇预混合物组合物包括具有卤化氢烯烃，多元醇，催化剂组合物和抗氧化剂的发泡剂。抗氧化剂可以是例如苯二醇或苯三醇或其它多羟基取代的芳族化合物，其任选被一个或多个取代基例如烷基取代。用于生产热固性泡沫共混物的两部分系统包括（a）多异氰酸酯和任选的一种或多种异氰酸酯相容的原料; 和（b）多元醇预混合组合物。一种制备热固性泡沫共混物的方法包括：（a）多异氰酸酯; 和（b）多元醇预混合组合物。

3. 发明申请

WO2013116416A1 IMPROVED SHELF LIFE OF POLYOL BLENDS CONTAINING HALOGENATED OLEFINS BY ENCAPSULATION OF ACTIVE COMPONENTS 审中-公开
标题翻译：通过加强活性成分改善含有氢化烯烃的多元醇混合物的寿命
公开(公告)号：WO2013116416A1
公开(公告)日：2013-08-08
申请号：PCT/US2013/023974
申请日：2013-01-31
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , COSTA, Joseph S. , ABBAS, Laurent , SESHADRI, Sri R.
IPC分类号： C08G18/00
CPC分类号： C08J9/146 , C08G18/18 , C08G18/4018 , C08G18/48 , C08G18/7664 , C08G2101/0025 , C08G2101/005 , C08J9/14 , C08J9/144 , C08J9/149 , C08J2203/06 , C08J2203/12 , C08J2203/142 , C08J2203/146 , C08J2203/162 , C08J2203/182 , C08J2375/04 , C08L75/04 , C08L2203/14
摘要： The shelf life of polyurethane polyol pre-blends containing halogenated olefins is extended by encapsulation of active components such as catalysts and/or surfactants. The active component is encapsulated in a crystallizable or thermoplastic polymer. The encapsulated particles have a size of 2,800 microns or less and the active components are not significantly leaked out, particularly in the presence of halogenated olefins.
摘要翻译：包含卤代烯烃的聚氨酯多元醇预混合物的保存期限通过包封活性组分如催化剂和/或表面活性剂来延长。活性组分被包封在可结晶或热塑性聚合物中。包封的颗粒具有2,800微米或更小的尺寸，并且活性组分没有显着泄漏，特别是在卤代烯烃的存在下。

4. 发明申请

WO2021226051A1 AZEOTROPE AND AZEOTROPE-LIKE COMPOSITIONS OF 1-CHLORO-1,2 DIFLUOROETHYLENE AND 2,3,3,3-TETRAFLUOROPROP-1-ENE 审中-公开
公开(公告)号：WO2021226051A1
公开(公告)日：2021-11-11
申请号：PCT/US2021/030611
申请日：2021-05-04
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , KIM, Sarah , KOO, Brian T. , CLARKSON, Lucy M.
IPC分类号： C09K5/00 , C09K5/02 , C09K5/04
摘要： Provided are azeotrope or azeotrope-like compositions comprised of 1-chloro-1,2 difluoroethylene (R-1122a) and 2,3,3,3-tetrafluoropropene (HFO-1234yf) and uses thereof.

5. 发明申请

WO2021226048A1 HEAT TRANSFER COMPOSITIONS OF HYDROFLUOROCARBONS 审中-公开
公开(公告)号：WO2021226048A1
公开(公告)日：2021-11-11
申请号：PCT/US2021/030608
申请日：2021-05-04
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , KIM, Sarah , KOO, Brian Thomas , CLARKSON, Lucy Mary
IPC分类号： C09K5/00 , C09K5/02 , C09K5/04
摘要： The present invention relates to heat transfer compositions comprising 1-chloro-1,2 difluoroethylene for use in refrigeration, air conditioning, heat pump systems, chillers, and other heat transfer applications. The inventive heat transfer compositions can possess reduced global warming potential while providing good capacity and performance while providing preferable flammability characteristics

6. 发明申请

WO2019067401A1 ADDITION AND CONDENSATION POLYMERS PREPARED FROM HALOGENATED REACTANTS 审中-公开
公开(公告)号：WO2019067401A1
公开(公告)日：2019-04-04
申请号：PCT/US2018/052563
申请日：2018-09-25
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , POLSZ, Craig Alan , CLARKSON, Lucy
IPC分类号： C08G18/50 , C08G18/38 , C08G18/72 , C08L75/08
摘要： Polymers containing halogen functionality are prepared by the addition or condensation polymerization of at least one halogenated reactant containing at least two active hydrogen-containing functional groups per molecule and at least one halogenated heteroalkyl or halogenated heteroalkenyl group per molecule and at least one co-reactant containing at least two functional groups reactive with the active hydrogen groups of the at least one halogenated reactant.

7. 发明申请

WO2019067394A1 HALOGENATED HETEROALKENYL- AND HETEROALKYL-FUNCTIONALIZED ORGANIC COMPOUNDS AND METHODS FOR PREPARING SUCH COMPOUNDS 审中-公开
公开(公告)号：WO2019067394A1
公开(公告)日：2019-04-04
申请号：PCT/US2018/052553
申请日：2018-09-25
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , SYVRET, Robert George , POLSZ, Craig Alan , LIU, Haiming , MILLER, Jay Fingeret , CLARKSON, Lucy
IPC分类号： C01B7/19 , C07C19/08
摘要： A method for synthesizing halogenated organic compounds, such as halogenated alkenyl group-containing and halogenated alkyl group-containing compounds having a heteroatom (e.g., O,N.S) coupled to a carbon atom of a halogenated alkenyl or halogenated alkyl group, involves reacting a halogenated olefin such as a chloro-substituted trifluoropropenyl compound with an active hydrogen-containing organic compound such as an alcohol (e.g., an aliphatic monoalcohol, aliphatic polyalcohol, or a phenolic compound), a primary amine, a secondary amine or a thiol.

8. 发明申请

WO2017048334A1 POLYOL PRE-MIXES HAVING IMPROVED SHELF LIFE 审中-公开
标题翻译：具有改进的保质期的聚氨酯预混物
公开(公告)号：WO2017048334A1
公开(公告)日：2017-03-23
申请号：PCT/US2016/034211
申请日：2016-05-26
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , COSTA, Joseph S. , SESHADRI, Sri R. , ABBAS, Laurent
IPC分类号： C08G18/08 , C08G18/34 , C08G18/42 , C08J9/14
CPC分类号： C08J9/144 , C08G18/00 , C08G2101/00 , C08J2201/022 , C08J2203/142 , C08J2205/052 , C08J2205/06 , C08J2205/10 , C08J2375/06 , C08J2375/08
摘要： A polyol pre-mix containing at least one halogenated hydroolefin blowing agent and having improved shelf life stability is provided, wherein each polyol combined with the halogenated hydroolefin blowing agent has an apparent pH of between 3 and 11.4. Controlling the apparent pH of the polyol(s) enables the polyol pre-mix to be stored for extended periods of time and then used in combination with organic polyisocyanate to produce foam formulations having gel times and tack free times not significantly different from those exhibited when freshly prepared polyol pre-mix is used.
摘要翻译：提供含有至少一种卤代氢烯烃发泡剂并具有改善的保质期稳定性的多元醇预混物，其中与卤代氢化烯烃发泡剂结合的每种多元醇的表观pH为3至11.4。控制多元醇的表观pH使得多元醇预混物能够长时间储存，然后与有机多异氰酸酯组合使用，以产生具有凝胶时间和无粘性时间的泡沫制剂，其与使用新鲜制备的多元醇预混物。

9. 发明申请

WO2013074324A1 PROCESS FOR THE MANUFACTURE OF HYDROFLUOROOLEFINS 审中-公开
标题翻译：氢氟虫腈的制备方法
公开(公告)号：WO2013074324A1
公开(公告)日：2013-05-23
申请号：PCT/US2012/063649
申请日：2012-11-06
申请人： ARKEMA INC. , ELSHEIKH, Maher Y. , BONNET, Philippe , CHEN, Benjamin Bin
发明人： ELSHEIKH, Maher Y. , BONNET, Philippe , CHEN, Benjamin Bin
IPC分类号： C07C17/00 , C07C17/20 , C07C21/20
CPC分类号： C07C17/206 , C07C17/358 , C07C21/18 , C07C21/04
摘要： A process for the synthesis of hydrocchlorofluoro olefins (HCFO) and/or hydrofluoroolefins (HFO). The process is based on the steps of fluorination of hydrochloropropenes or hydrochloropropanes to form hydrochlorofluoropropenes and/or hydrofluoropropenes, followed by gas phase, catalytic fluorination of the hydrochlorofluoropropenes to form hydrofluoropropenes. The process produces 1,1, 1,2- tetrafluoropropene (HFO-1234yf) from "feedstock" such as tetrachloropropenes, 1,1,2,3 tetrachloropropene (HCO-1230xa) and/or 1,1,1,2 tetrachloropropene (HCO-1230xf) or pentachloropropanes, HCC-240db, HCC-240aa and/or HCC-240ab which are precursors of the tetrachloropropenes. The process of the present invention comprises the steps of: a) liquid phase or gas phase fluorination of tetrachloropropene (which may be formed via gas phase fluorination of pentachloropropane), in the presence or absence of homogenous or heterogeneous catalyst; to form the intermediate product HCFO- 1233xf and thereafter b) gas phase, catalytic fluorination of the intermediate HCFO-1233xf to form the hydrofluoropropene product 1,1,1,2-tetrafluoropropene (HFO-1234yf).
摘要翻译：一种合成氢氟氯氟烯烃（HCFO）和/或氢氟烯烃（HFO）的方法。该方法基于氢氯丙烯或氢氯丙烷氟化以形成氢氯氟丙烯和/或氢氟丙烯的步骤，然后进行气相，氢氯氟丙烯的催化氟化以形成氢氟丙烯。该方法从“原料”产生1,1,1,2-四氟丙烯（HFO-1234yf），例如四氯丙烯，1,1,2,3四氯丙烯（HCO-1230xa）和/或1,1,1,2-四氯丙烯（ HCO-1230xf）或五氯丙烷，HCC-240db，HCC-240aa和/或HCC-240ab，它们是四氯丙烯的前体。本发明的方法包括以下步骤：a）在存在或不存在均相或多相催化剂的情况下，四氯丙烯（其可通过五氯丙烷的气相氟化形成）进行液相或气相氟化; 形成中间产物HCFO-1233xf，然后b）中间体HCFO-1233xf的气相，催化氟化以形成氢氟丙烯产物1,1,1,2-四氟丙烯（HFO-1234yf）。

10. 发明申请

WO2018022419A1 POLYOL PRE-MIXES HAVING IMPROVED SHELF LIFE 审中-公开
标题翻译：多元醇预混料具有改善的保质期
公开(公告)号：WO2018022419A1
公开(公告)日：2018-02-01
申请号：PCT/US2017/043069
申请日：2017-07-20
申请人： ARKEMA INC.
发明人： CHEN, Benjamin Bin , COSTA, Joseph S. , ABBAS, Laurent , SESHADRI, Sri R.
IPC分类号： C09K3/00 , C08L75/08
摘要： Incorporating a cycloaliphatic epoxide such as cyclohexene oxide into a polyol pre-mix containing an amine catalyst and a halogenated hydroolefin blowing agent such as HCFO-1233zd helps to improve the storage-stability of the pre-mix and to ensure that a thermoset foam prepared therefrom is of satisfactory quality.
摘要翻译：将脂环族环氧化物例如环己烯氧化物引入到含有胺催化剂和卤化氢烯烃发泡剂如HCFO-1233zd的多元醇预混合物中有助于改善预混合物的储存稳定性和以确保由其制备的热固性泡沫质量令人满意。

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