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1. 发明申请

WO2007093745A3 STRUCTURE MADE FROM A THERMOPLASTIC COMPOSITION OF A POLYOLEFIN FUNCTIONALISED BY POLYETHER GRAFTS AND USE THEREOF 审中-公开
标题翻译：由聚酯纤维功能化的聚烯烃的热塑性组合物的结构及其用途
公开(公告)号：WO2007093745A3
公开(公告)日：2008-03-20
申请号：PCT/FR2007050805
申请日：2007-02-15
申请人： ARKEMA FRANCE , FLAT JEAN-JACQUES , HERT MARIUS
发明人： FLAT JEAN-JACQUES , HERT MARIUS
IPC分类号： C08L51/00 , C08F8/00 , C08F255/00 , C08F255/02 , C08G81/02 , C08L51/06 , C09D151/00 , C09D151/06
CPC分类号： C08G81/025 , C08F255/02 , C08L51/006 , C08L51/06 , Y10T442/2139 , Y10T442/674 , Y10T442/678 , C08L2666/24
摘要： The invention relates to a structure comprising a substrate and at least one first layer applied to the substrate made from a thermoplastic composition with at least one functionalised thermoplastic obtained by copolymerisation or grafting of a polyolefin backbone with an unsaturated monomer with an anhydride, acid or epoxide function, the functionalised polyolefin being grafted by polyether groups with a terminal amine by means of reactive extrusion. Said structure is a breathable waterproof material with water vapour permeability of at least 300 g/m 2 24 h -1 measured by the standard ASTM E96, method BW (38°C/50 % relative humidity), for a film of 25 µm. The invention further relates to the use of such a composition as a breathable waterproof material with water vapour permeability of at least 300 g/m 2 24 h -1 measured by the standard ASTM E96, method BW (38°C/50 % relative humidity), for a film of 25 µm.
摘要翻译：本发明涉及一种结构，其包括基材和至少一个第一层，其施加到由热塑性组合物制成的基材上，所述第一层具有至少一种官能化的热塑性聚合物，所述官能化热塑性聚合物通过聚合物主链与不饱和单体与酸酐，酸或环氧化物共聚或接枝功能化的聚烯烃通过反应性挤出用末端胺接枝聚醚基团。所述结构是通过标准ASTM E96，方法BW（38℃）测量的透水性为至少300g / m 2·24h -1 -1的透气防水材料 / 50％相对湿度），对于25μm的膜。本发明还涉及这样一种组合物作为透气性防水材料的用途，所述防水材料的水蒸汽渗透性为标准值至少为300g / m 2·24h -1 -1 ASTM E96，方法BW（38℃/ 50％相对湿度），对于25μm的膜。

2. 发明申请

WO2010061128A4 POLYAMIDE AND POLYOLEFIN THERMOPLASTIC COMPOSITION 审中-公开
标题翻译：聚酰胺和聚烯烃热塑性组合物
公开(公告)号：WO2010061128A4
公开(公告)日：2010-07-29
申请号：PCT/FR2009052287
申请日：2009-11-24
申请人： ARKEMA FRANCE , FLAT JEAN-JACQUES , BLONDEL PHILIPPE
发明人： FLAT JEAN-JACQUES , BLONDEL PHILIPPE
IPC分类号： C08L77/02 , C08K5/5313 , C08L23/08 , C08L77/06
CPC分类号： C08L77/02 , C08K5/5313 , C08L23/0853 , C08L23/0869 , C08L23/12 , C08L23/147 , C08L77/00 , C08L77/06 , C08L2666/06
摘要： The present invention relates to a thermoplastic composition including: at least one polyamide matrix (A); at least one functionalized polyolefin (B1); and at least one functionalized polyolefin (B2); and having 18 to 50 wt %, relative to the total weight of the composition, of at least one metal salt that is optionally contained in a polymer that is selected from a phosphinic acid metal salt, a diphosphinic acid metal salt, and a mixture thereof. The invention also relates to the use thereof for manufacturing cast elements.
摘要翻译：本发明涉及一种热塑性组合物，其包含：至少一种聚酰胺基质（A）; 至少一种官能化聚烯烃（B1）; 和至少一种官能化聚烯烃（B2）; 并且相对于组合物的总重量具有18至50重量％的至少一种金属盐，所述金属盐任选地包含在选自次膦酸金属盐，二次膦酸金属盐及其混合物的聚合物中。本发明还涉及其用于制造铸件的用途。

3. 发明申请

WO2010069546A2 POLYAMIDE-GRAFTED POLYMERS, PHOTOVOLTAIC MODULES WITH A BACKSHEET FILM COMPRISING A POLYAMIDE-GRAFTED POLYMER AND MANUFACTURING PROCESS AND USE THEREOF 审中-公开
标题翻译：聚酰亚胺聚合物，具有包含聚酰胺聚合物的制备薄膜的光伏模块和制造方法及其用途
公开(公告)号：WO2010069546A2
公开(公告)日：2010-06-24
申请号：PCT/EP2009008972
申请日：2009-12-15
申请人： ARKEMA FRANCE , ETIMEX SOLAR GMBH , VOGT MARC , JOUSSET DOMINIQUE , BIZET STEPHANE , FLAT JEAN-JACQUES
发明人： VOGT MARC , JOUSSET DOMINIQUE , BIZET STEPHANE , FLAT JEAN-JACQUES
IPC分类号： C08G81/00 , C08F255/02 , C08F267/04 , C08F267/06 , C08G81/02 , C08G83/00 , C08L77/00 , C08L77/02 , C08L77/06 , H01L31/048
CPC分类号： C08G81/028 , C08L23/0869 , H01L31/049 , Y02E10/50 , C08L2666/20
摘要： One subject of the invention is the use of a film as a protective backsheet in a photovoltaic module, said film comprising at least one layer of a composition containing a polyamide-grafted polymer, this polyamide-grafted polymer comprising a polyolefin backbone containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, in which: ° the polyamide graft is attached to the polyolefin backbone by the residue of the unsaturated monomer (X) that comprises a functional group capable of reacting via a condensation reaction with a polyamide having at least one amine end group and/or at least one carboxylic acid end group; ° the residue of the unsaturated monomer (X) is attached to the backbone by grafting or copolymerization; said polyamide-grafted polymer comprising, relative to its total weight: ° from 40 to 95% by weight of the polyolefin backbone comprising the unsaturated monomer (X); and ° from 5 to 60% by weight of polyamide grafts, and the melting point or glass transition temperature of the polyamide grafts being greater than or equal to 85°C. The invention also relates to a process of manufacturing a photovoltaic module, to a photovoltaic module and also to the use of this module for producing electricity.
摘要翻译：本发明的一个主题是在光伏模块中使用膜作为保护性底片，所述膜包括至少一层含有聚酰胺接枝聚合物的组合物，该聚酰胺接枝聚合物包含聚烯烃主链，其含有至少一种不饱和单体（X）和至少一种聚酰胺接枝物，其中：聚酰胺接枝物通过不饱和单体（X）的残基连接到聚烯烃主链上，所述不饱和单体（X）包含能够通过缩合反应与具有至少一个胺端基和/或至少一个羧酸端基的聚酰胺; °不饱和单体（X）的残基通过接枝或共聚连接到骨架上; 所述聚酰胺接枝聚合物相对于其总重量包含：40至95重量％的包含不饱和单体（X）的聚烯烃主链; 和5至60重量％的聚酰胺接枝物，聚酰胺接枝物的熔点或玻璃化转变温度大于或等于85℃。本发明还涉及制造光伏组件，光伏组件以及该模块用于发电的方法。

4. 发明申请

WO2010069546A3 POLYAMIDE-GRAFTED POLYMERS, PHOTOVOLTAIC MODULES WITH A BACKSHEET FILM COMPRISING A POLYAMIDE-GRAFTED POLYMER AND MANUFACTURING PROCESS AND USE THEREOF 审中-公开
标题翻译：聚酰胺接枝聚合物，具有包含聚酰胺接枝聚合物的背表面膜的光伏组件和制造方法及其用途
公开(公告)号：WO2010069546A3
公开(公告)日：2011-08-25
申请号：PCT/EP2009008972
申请日：2009-12-15
申请人： ARKEMA FRANCE , SOLUTIA SOLAR GMBH , VOGT MARC , JOUSSET DOMINIQUE , BIZET STEPHANE , FLAT JEAN-JACQUES
发明人： VOGT MARC , JOUSSET DOMINIQUE , BIZET STEPHANE , FLAT JEAN-JACQUES
IPC分类号： C08G81/00 , C08F255/02 , C08F267/04 , C08F267/06 , C08G81/02 , C08G83/00 , C08L77/00 , C08L77/02 , C08L77/06 , H01L31/048
CPC分类号： C08G81/028 , C08L23/0869 , H01L31/049 , Y02E10/50 , C08L2666/20
摘要： One subject of the invention is the use of a film as a protective backsheet in a photovoltaic module, said film comprising at least one layer of a composition containing a polyamide-grafted polymer, this polyamide-grafted polymer comprising a polyolefin backbone containing a residue of at least one unsaturated monomer (X) and at least one polyamide graft, in which: ° the polyamide graft is attached to the polyolefin backbone by the residue of the unsaturated monomer (X) that comprises a functional group capable of reacting via a condensation reaction with a polyamide having at least one amine end group and/or at least one carboxylic acid end group; ° the residue of the unsaturated monomer (X) is attached to the backbone by grafting or copolymerization; said polyamide-grafted polymer comprising, relative to its total weight: ° from 40 to 95% by weight of the polyolefin backbone comprising the unsaturated monomer (X); and ° from 5 to 60% by weight of polyamide grafts, and the melting point or glass transition temperature of the polyamide grafts being greater than or equal to 85°C. The invention also relates to a process of manufacturing a photovoltaic module, to a photovoltaic module and also to the use of this module for producing electricity.
摘要翻译：本发明的一个主题是使用薄膜作为光伏组件中的保护底片，所述膜包含至少一层含有聚酰胺接枝聚合物的组合物，该聚酰胺接枝聚合物包含聚烯烃主链，所述聚烯烃主链含有至少一种不饱和单体（X）和至少一种聚酰胺接枝物，其中：·聚酰胺接枝物通过不饱和单体（X）的残基与聚烯烃骨架连接，所述不饱和单体（X）包含能够通过缩合反应与具有至少一个胺端基和/或至少一个羧酸端基的聚酰胺接触; °不饱和单体（X）的残基通过接枝或共聚连接到主链上; 所述聚酰胺接枝聚合物相对于其总重量包含：40-95重量％的包含不饱和单体（X）的聚烯烃主链; 和5至60重量％的聚酰胺接枝物，并且聚酰胺接枝物的熔点或玻璃化转变温度大于或等于85℃。本发明还涉及制造光伏模块的方法，光伏模块以及该模块用于发电的用途。

5. 发明申请

WO2008104677A3 FLEXIBLE THERMOPLASTIC COMPOSITION WITH IMPROVED RESISTANCE TO THE EFFECT OF OILS, AND USE OF SUCH A COMPOSITION 审中-公开
标题翻译：具有改进的抗油性影响的柔韧性热塑性组合物以及使用这种组合物
公开(公告)号：WO2008104677A3
公开(公告)日：2008-11-06
申请号：PCT/FR2008050180
申请日：2008-02-06
申请人： ARKEMA FRANCE , BIZET STEPHANE , FLAT JEAN-JACQUES
发明人： BIZET STEPHANE , FLAT JEAN-JACQUES
IPC分类号： C08G81/02 , C08L29/04 , C08L51/00 , C08L77/00 , C08L87/00
CPC分类号： C08L51/08 , C08F255/00 , C08F255/02 , C08G81/028 , C08L23/0861 , C08L51/06 , C08L2666/24 , C08L2666/20 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amino end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerisation from the double bond thereof; and the composition comprises between 40 and 90 wt. % of the polyolefin core comprising the unsaturated monomer (X), between 5 and 40 wt. % of polyamide grafts, and between 5 and 40 wt. % of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
摘要翻译：本发明涉及耐油老化效应的柔性热塑性组合物，所述组合物包含含有聚酰胺嵌段并由聚烯烃骨架和至少一种聚酰胺接枝物组成的接枝共聚物。根据本发明，移植物通过具有可与包含氨基末端或羧酸末端的聚酰胺反应的功能的不饱和单体（X）的残基连接至核心; 不饱和单体（X）的残基通过从其双键接枝或共聚而与骨架连接; 并且该组合物包含40-90wt。包含不饱和单体（X）的聚烯烃核心的5％至40wt。％的聚酰胺接枝物，以及5至40wt。％的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

6. 发明申请

WO2007141449A3 FLEXIBLE HIGH THERMOMECHANICAL STRESS-RESISTANT AND FIREPROOF HALOGEN-FREE THERMOPLASTIC COMPOSITIONS 审中-公开
标题翻译：柔性高温耐热耐火材料和无机无卤素热塑性组合物
公开(公告)号：WO2007141449A3
公开(公告)日：2008-01-31
申请号：PCT/FR2007051365
申请日：2007-06-01
申请人： ARKEMA FRANCE , FLAT JEAN-JACQUES , BLONDEL PHILIPPE , MESLET DAVID
发明人： FLAT JEAN-JACQUES , BLONDEL PHILIPPE , MESLET DAVID
IPC分类号： C08L77/00 , B60R16/08 , C08G81/02 , C08L87/00 , C09D5/18 , C09K21/00 , H01B3/44 , H01B7/295 , H01R13/527
CPC分类号： C09K21/12 , C08G81/028 , C08L23/02 , C09D5/18 , C09K21/04 , H01B7/295 , H01R13/527 , C08L2666/20
摘要： The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer, consisting of a trunk and on average at least one polyamide graft wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise in mixture: 50 to 70 wt. % of polyamide block copolymer; 25 to 35 wt. % of a fire-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates and polyphosphates; about 2 wt. % of zeolite or hydrotalcite molecular sieves. Said compositions are particularly useful for making electric cables, electric components, for molding electrotechnical housings, or for making coating layers or thermal protection sleeves for fluid transfer lines in the automotive industry.
摘要翻译：本发明涉及柔性高热机械应力耐受性和阻燃无卤热塑性组合物，其包含聚酰胺嵌段共聚物，其由树干和平均至少一个聚酰胺接枝物组成，其中移植物通过残留物与树干结合具有能够在胺末端与聚酰胺反应的功能的不饱和单体（X），不饱和单体残基（X）通过从其双键接枝或共聚而结合在树干上。本发明的特征在于，所述组合物包含混合物：50至70wt。％的聚酰胺嵌段共聚物; 25〜35重量％选自磷酸铵，次膦酸盐，焦磷酸盐和多磷酸盐的阻燃剂的百分比; 约2重量％％的沸石或水滑石分子筛。所述组合物特别可用于制造用于汽车工业中的流体输送管线的电缆，电气部件，用于模制电工外壳或用于制造涂层或热保护套管。

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