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    • 9. 发明申请
    • THERMOSET MATERIALS WITH IMPROVED IMPACT RESISTANCE
    • 具有改善抗冲击性的热敏材料
    • WO2006077153A3
    • 2006-11-02
    • PCT/EP2006000564
    • 2006-01-18
    • ARKEMA FRANCEGUERRET OLIVIERGERARD PIERREPASCAULT JEAN-PIERREBONNET ANTHONY
    • GUERRET OLIVIERGERARD PIERREPASCAULT JEAN-PIERREBONNET ANTHONY
    • C08L53/00C08L33/00C08L63/00C08L69/00C08L101/00
    • C08L53/00C08L101/00C08L2666/14C08L2666/02C08L2666/04
    • The present invention relates to a thermoset material with improved impact resistance comprising, by weight: 99 to 20% of a thermoset resin, 1 to 80% of an impact modifier comprising at least one copolymer chosen from copolymers comprising A-B-C and A-B blocks, in which: each block is connected to the other by means of a covalent bond or of an intermediate molecule connected to one of the blocks via a covalent bond and to the other block via another covalent bond, A is a copolymer of methyl methacrylate and of at least one water-soluble monomer, C is either (i) a PMMA (homopolymer or copolymer) this PMMA comprising optionally a water-soluble monomer or (ii) a polymer based on vinyl monomers or mixture of vinyl monomers, B is incompatible or partially compatible with the thermoset resin and incompatible with the A block and the optional C block and its glass transition temperature Tg is less than the operating temperature of the thermoset material. The invention also relates to the use of these impact modifiers in thermo- sets.
    • 本发明涉及具有改进的抗冲击性的热固性材料,其包含按重量计:99-20%的热固性树脂,1至80%的抗冲改性剂,其包含至少一种选自包含ABC和AB嵌段的共聚物的共聚物,其中 :每个嵌段通过共价键或通过共价键连接到其中一个嵌段的中间分子连接,另一个通过另一个共价键连接到另一个嵌段,A是甲基丙烯酸甲酯和至少 一种水溶性单体,C是(i)PMMA(均聚物或共聚物),该PMMA包含任选的水溶性单体或(ii)基于乙烯基单体或乙烯基单体混合物的聚合物,B是不相容或部分相容的 与热固性树脂并且与A块和任选的C嵌段不相容,并且其玻璃化转变温度Tg小于热固性材料的操作温度。 本发明还涉及这些抗冲改性剂在热敏电阻中的应用。