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    • 1. 发明申请
    • COMPOSITIONS CONTAINING ROSIN ESTER AND ETHYLENE POLYMERS
    • 含有ROSIN ESTER和EthylLENE聚合物的组合物
    • WO2016154456A1
    • 2016-09-29
    • PCT/US2016/024056
    • 2016-03-24
    • ARIZONA CHEMICAL COMPANY, LLC
    • LANGE, Jos, H.M.SCHAAPMAN, Mark, C.HINC, Justyna, J.
    • C09J123/08C09J193/04C08L23/08C08L93/04C09F1/04
    • C08L93/04C08K5/005C08L23/0853C08L23/0869C08L91/06C09F1/04C09J123/0853C09J123/0869C09J193/04
    • Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer, or low molecular weight copolymer having a relatively high melt index, derived from ethylene and vinyl acetate and/or a copolymer, or low molecular weight copolymer having a relatively high melt index, derived from ethylene and «-buty! acrylate) and a rosin ester, The rosin ester can have a low hydroxy! number (e.g., a hydroxy! number six or five or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-two or in between eight and twenty), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52 °C or in between 48 °C and 60 °C) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.
    • 公开了包含衍生自至少一种具有一个或多个酯基的极性单体的乙烯聚合物,其与乙烯聚合的聚合物(例如,具有相对高的熔体指数的共聚物或低分子量共聚物,衍生自乙烯和乙烯基 乙酸酯和/或共聚物,或具有相对较高熔体指数的低分子量共聚物,衍生自乙烯和丙烯酸正丁酯)和松香酯。松香酯可以具有低羟基! 数字(例如,羟基数6或5以下),低酸值(例如,酸值为10以下),相对低的PAN数(例如,PAN数小于22或之间 8和20),相对较高的第三力矩或第三功率平均分子量(Mz)(例如,2500和12000g / mol之间的Mz值),低硫含量(例如低于600ppm的硫含量 在抗氧化剂添加之前)或其组合。 组合物可以表现出高的耐热应力(例如,高于52℃的热应力通过温度值或在48℃至60℃之间)和/或在热老化时和/或改善的粘度稳定性和/或颜色稳定性和/ 或改进的兼容性。
    • 2. 发明申请
    • OLIGOESTERS AND COMPOSITIONS THEREOF
    • OLIGOESTERS及其组合物
    • WO2017117576A1
    • 2017-07-06
    • PCT/US2016/069594
    • 2016-12-30
    • ARIZONA CHEMICAL COMPANY, LLC
    • SCHAAPMAN, Mark, C.LANGE, Jos, H.M.EDUARD, PieterZEEMAN, Ronnie
    • C09F1/04C08G63/00C08G63/48C08L93/04C09F1/00
    • C09F1/04C08K5/053C08K5/09C08L9/06C08L93/04C09J193/04
    • An oligoester composition which is a reaction product of a reactant mixture comprising one or more rosins; at least 15% by weight of one or more monocarboxylic acids; and one or more polyhydric alcohols. A method for preparing an oligoester composition comprising (a) esterifying a mixture comprising one or more rosins, one or more monocarboxylic acids, and optionally one or more polycarboxylic acids with one or more polyhydric alcohols to form the oligoester composition. An oligoester composition which is an esterification reaction product of one or more rosins, one or more monocarboxylic acids, one or more polyhydric alcohols, and optionally one or more polycarboxylic acids, wherein the composition has a weight average molecular weight of from 500 g/mol to 8,000 g/mol and a Tg of between -80°C and 100°C.
    • 低聚酯组合物,其为包含一种或多种松香的反应混合物的反应产物; 至少15重量%的一种或多种一元羧酸; 和一种或多种多元醇。 一种低聚酯组合物的制备方法,包括(a)将包含一种或多种松香,一种或多种单羧酸和任选的一种或多种多羧酸的混合物与一种或多种多元醇酯化以形成低聚酯组合物。 一种低聚酯组合物,其为一种或多种松香,一种或多种一元羧酸,一种或多种多元醇和任选的一种或多种多元羧酸的酯化反应产物,其中该组合物的重均分子量为500g / mol 至8,000g / mol,Tg在-80℃至100℃之间