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    • 1. 发明申请
    • UNSEGREGATED OXIDE SUPERCONDUCTOR SILVER COMPOSITE
    • 非标准氧化物超导体银复合材料
    • WO1995000457A1
    • 1995-01-05
    • PCT/US1994007131
    • 1994-06-23
    • AMERICAN SUPERCONDUCTOR CORPORATION
    • AMERICAN SUPERCONDUCTOR CORPORATIONOTTO, AlexanderMASUR, Lawrence, J.PODTBURG, Eric, R.SANDHAGE, Kenneth, H.CRAVEN, Christopher, A.SCHREIBER, Jeffrey, D.
    • C04B35/00
    • H01L39/248C04B35/45C04B35/65
    • A method for forming unsegregated metal oxide-silver composites includes preparing a precursor alloy comprising silver and precursor elements of a desired metal oxide and oxidizing the alloy under conditions of high oxygen activity selected to permit diffusion of oxygen into silver while significantly restricting the diffusion of the precursor elements into silver, such that oxidation of the precursor elements to the metal oxide occurs before diffusion of the metallic elements into silver. Further processing of the metal oxide composite affords an oxide superconducting composite with a highly unsegregated microstructure. A novel precursor may be used in conjunction with the oxidation under conditions of high oxygen activity to further restrict segregation of metal oxide-silver composite. A precursor composite for preparation of an oxide superconductor includes a primary alloy phase of constituent elements of a desired oxide superconductor; and a secondary phase comprising copper, the secondary phase supported by the primary alloy phase. The composite may additionally include a matrix material for supporting the primary alloy phase and second phase disposed therein. The composite is oxidized to form an oxide superconductor composite.
    • 用于形成未分离的金属氧化物 - 银复合物的方法包括制备包含银的前体合金和期望的金属氧化物的前体元素,并在选择高氧活性的条件下氧化合金,以允许氧扩散到银中,同时显着地限制 前体元素变成银,使得在将金属元素扩散到银之前,前体元素氧化成金属氧化物。 金属氧化物复合物的进一步处理提供具有高度未偏析的微结构的氧化物超导复合材料。 在高氧活性的条件下,新的前体可与氧化结合使用,以进一步限制金属氧化物 - 银复合物的分离。 用于制备氧化物超导体的前体复合材料包括期望的氧化物超导体的构成元素的主合金相; 以及包含铜的第二相,第二相由主合金相负载。 复合材料还可以包括用于支撑初级合金相的基体材料和设置在其中的第二相。 复合材料被氧化形成氧化物超导体复合材料。