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    • 2. 发明申请
    • PROCESS FOR CONVERTING DROSS RESIDUES TO USEFUL PRODUCTS
    • 将废弃物转化为有用的产品的方法
    • WO1991009978A1
    • 1991-07-11
    • PCT/CA1990000454
    • 1990-12-24
    • ALCAN INTERNATIONAL LIMITED
    • ALCAN INTERNATIONAL LIMITEDCHAUVETTE, GaetanKIMMERLE, Frank, M.ROUSSEL, Roger
    • C22B21/00
    • C22B21/0023C01C1/04C01F7/0693C22B7/04C22B21/0007C22B21/0069Y02P10/234
    • A process for converting dross residues having an aluminum nitride content of at least 5 wt % and a metallic aluminum content of no more than 10 wt % ( particularly plasma dross residues) to useful products. The process comprises treating the dross residues with a solution having a pH of 7 or more, the reaction at alkaline pH values being AlN + 4H2O -> Al(OH)3 + NH4 + OH followed by: Al(OH)3 + OH -> Al2O + 2H2O and NH4 + OH -> NH3 + H2O. The initial treatment of the dross residues may be under mild conditions to generate ammonia from the nitride. The ammonia can be collected as a useful product or converted to other useful products such as ammonium salts. Under harsher conditions, e.g. elevated temperature and pressure with caustic alkalis, a substantial portion of the dross residue dissolves to form an alkali metal aluminate solution which is itself a useful product (e.g. it can be used in the Bayer process) or can be converted into other useful products such as aluminum trihydrate. A portion of the dross residue normally remains undissolved and this can also be a useful product, e.g. a refractory precursor, or may be disposed of by dumping since it is non-polluting.
    • 将具有至少5重量%的氮化铝含量和不超过10重量%的金属铝含量(特别是等离子体杂质残渣)的渣渣转化成有用的产品的方法。 该方法包括用pH为7或更高的溶液处理渣渣,碱性pH值为AlN + 4H 2 O→Al(OH)3 + NH 4 + OH→的反应,随后为:Al OH)3 + OH→Al 2 O + + 2H 2 O和NH 4 + + OH→NH 3 + H 2 O。 渣渣残留物的初始处理可能处于温和条件下,从氮化物产生氨。 可以将氨作为有用的产物收集或转化成其它有用的产物如铵盐。 在更苛刻的条件下,例如 升高的温度和压力与苛性碱,大部分的浮渣残留物溶解形成碱金属铝酸盐溶液本身是有用的产品(例如它可以用于拜耳法)或可以转化成其他有用的产品,如 三水合铝。 一部分浮渣残渣通常保持不溶,这也可以是有用的产物,例如, 耐火材料前体,或者可以通过倾倒处理,因为它是无污染的。