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1. 发明申请

WO2009058572A1 ORGANOPHOSPHONATE OLIGOMERS 审中-公开
标题翻译：有机磷酸酯低聚物
公开(公告)号：WO2009058572A1
公开(公告)日：2009-05-07
申请号：PCT/US2008/080101
申请日：2008-10-16
申请人： ALBEMARLE CORPORATION , TSAO, Techen , MACK, Arthur, G. , LAYMAN, William, J. , APLIN, Jeffrey, Todd
发明人： TSAO, Techen , MACK, Arthur, G. , LAYMAN, William, J. , APLIN, Jeffrey, Todd
IPC分类号： C07F9/09 , C08J9/00 , C08K5/521
CPC分类号： C07F9/091 , C07F9/093 , C07F9/4006 , C08J9/0038 , C08J2375/04 , C08K5/521 , C08L75/00
摘要： This invention provides chlorohydrocarbyloxy phosphonate oligomers, organophosphonate oligomers, and processes for the preparation of such oligomers. The chlorohydrocarbyloxy phosphonate oligomers can be represented by the formula (IV) where R 1 is a linear or branched hydrocarbylene group or oxygen-containing hydrocarbylene group, which hydrocarbylene group has about two to about twenty carbon atoms, or a hydrocarbylene group having at least one cycloaliphatic or aromatic ring; R 2 is an alkyl group or an aromatic group; and n is a number from about 2 to about 20.
摘要翻译：本发明提供了氯代氧代膦酸酯低聚物，有机膦酸酯低聚物和制备这种低聚物的方法。氯代氧代膦酸酯低聚物可以由式（IV）表示，其中R 1是亚烃基具有约2至约20个碳原子的直链或支链亚烃基或含氧亚烃基，或具有至少一个脂环族基团的亚烃基或芳环; R2是烷基或芳基; n为约2至约20的数。

2. 发明申请

WO2008073871A1 ORGANOPHOSPHONATE OLIGOMERS AND MIXTURES THEREOF USEFUL AS FLAME RETARDANTS 审中-公开
标题翻译：有机磷酸酯低聚物及其混合物有用于阻燃剂
公开(公告)号：WO2008073871A1
公开(公告)日：2008-06-19
申请号：PCT/US2007/086932
申请日：2007-12-10
申请人： ALBEMARLE CORPORATION , SAUER, Anne, M. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, Todd
发明人： SAUER, Anne, M. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, Todd
IPC分类号： C07F9/38 , C07F9/40 , C08K5/5317 , C08K5/5333 , C08G18/38
CPC分类号： C08G79/04 , C07F9/4075 , C08G18/4829 , C08G2101/0008 , C08K5/5333 , C08L75/04 , C08L2666/22
摘要： Organophosphonate oligomers, and mixtures thereof, useful as flame retardants.
摘要翻译：有机膦酸酯低聚物及其混合物，可用作阻燃剂。

3. 发明申请

WO2008154268A1 PROCESS FOR MAKING DIHYDROCARBYL HYDROCARBONPHOSPHONATES 审中-公开
标题翻译：制备二氢碳氢化合物的方法
公开(公告)号：WO2008154268A1
公开(公告)日：2008-12-18
申请号：PCT/US2008/065858
申请日：2008-06-05
申请人： ALBEMARLE CORPORATION , SAUER, Anne, M. , TSAO, Techen , MACK, Arthur, G. , LAYMAN, William, J.
发明人： SAUER, Anne, M. , TSAO, Techen , MACK, Arthur, G. , LAYMAN, William, J.
IPC分类号： C07F9/40
CPC分类号： C07F9/4006
摘要： This invention provides a process for the preparation of a dihydrocarbyl hydrocarbonphosphonate. The process comprises forming a reaction mixture from components comprising (i) at least one dihydrocarbyl phosphite, (ii) at least one alkali metal hydrocarbyloxide, and (iii) at least one alcohol, so that a dihydrocarbyl hydrocarbonphosphonate is formed.
摘要翻译：本发明提供了制备二烃基膦酸膦的方法。该方法包括从包含（i）至少一种亚磷酸二烃基酯，（ii）至少一种碱金属烃氧基化物和（iii）至少一种醇）的组分形成反应混合物，从而形成二烃基烃膦酸酯。

4. 发明申请

WO2008118699A1 USE OF LOW TRIPHENYLPHOSPHATE, HIGH PHOSPHOROUS CONTENT ISOPROPYL PHENYL PHOSPHATES AS FLAME RETARDANTS IN POLYURETHANE OR POLYISOCYANURATE FOAMS 审中-公开
标题翻译：低磷酸三钙的使用，高磷酸内酯异丙基苯酚磷酸酯作为聚氨酯或聚异氰酸酯FOAMS中的阻燃剂
公开(公告)号：WO2008118699A1
公开(公告)日：2008-10-02
申请号：PCT/US2008/057402
申请日：2008-03-19
申请人： ALBEMARLE CORPORATION , LAYMAN, William, J. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, T. , CHEW, Hoover
发明人： LAYMAN, William, J. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, T. , CHEW, Hoover
IPC分类号： C08K5/523 , C07F9/12 , C08L75/04
CPC分类号： C08K5/521 , C08G2101/0008 , C08G2101/0025 , C08J9/0038 , C08J2375/04 , C08K5/523 , C08K2201/014 , C08L75/00
摘要： The present invention relates to the use of low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation as flame retardants in polyurethane or polyisocyanurate foams or polyurethane or polyisocyanurate foam formulations.
摘要翻译：本发明涉及在聚氨酯或聚异氰脲酸酯泡沫或聚氨酯或聚异氰脲酸酯泡沫体制剂中使用低邻苯基磷酸盐，高磷含量的高邻位烷基化芳基磷酸酯作为阻燃剂。

5. 发明申请

WO2007127691A3 LOW TRIPHENYLPHOSPHATE, HIGH PHOSPHOROUS CONTENT ISOPROPYL PHENYL PHOSPHATES WITH HIGH ORTHO ALKYLATION 审中-公开
公开(公告)号：WO2007127691A3
公开(公告)日：2007-11-08
申请号：PCT/US2007/067188
申请日：2007-04-23
申请人： ALBERMARLE CORPORATION , LAYMAN, William, Joseph Jr. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, Todd , CHEW, Hoover , LUTHER, Douglas, W.
发明人： LAYMAN, William, Joseph Jr. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, Todd , CHEW, Hoover , LUTHER, Douglas, W.
IPC分类号： C07F9/12 , C08K5/523 , C09K21/12 , C08L27/00 , C08L75/04
摘要： The present invention relates to low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation that are suitable for use as flame retardant compositions, processes for their preparation, and their use as flame retardants.

6. 发明申请

WO2009035836A1 A METHOD FOR MAKING N-2,3-DIBROMOPROPYL-4-5-DIBROMOHEXAHYDROPHTHALIMIDE 审中-公开
标题翻译：制备N-2,3-DIBROMOPROLY-4-5-DIBROMOHEXAHYDROPHTHALIMIDE的方法
公开(公告)号：WO2009035836A1
公开(公告)日：2009-03-19
申请号：PCT/US2008/073793
申请日：2008-08-21
申请人： ALBEMARLE CORPORATION , MAXWELL, Kimberly, Ann , KARSEBOOM, Steven, G. , APLIN, Jeffrey, Todd , LIN, Ronny, W. , MACK, Arthur, G. , MORICE, Jorge , HUSSAIN, Saadat , ANDERSON, Steven, Alan , JAMESON, Christopher, Chad , COLONIUS, Neal, James
发明人： MAXWELL, Kimberly, Ann , KARSEBOOM, Steven, G. , APLIN, Jeffrey, Todd , LIN, Ronny, W. , MACK, Arthur, G. , MORICE, Jorge , HUSSAIN, Saadat , ANDERSON, Steven, Alan , JAMESON, Christopher, Chad , COLONIUS, Neal, James
IPC分类号： C07D209/48
CPC分类号： C07D209/48
摘要： The present invention relates to process technology suitable for producing, on a commercial scale, N-2,3-dibromopropyl-4,5-dibromohexahydrophthalimide.
摘要翻译：本发明涉及适用于工业规模生产N-2,3-二溴丙基-4,5-二溴六氢邻苯二甲酰亚胺的工艺技术。

7. 发明申请

WO2005023927A1 FLAME RETARDANTS WITH HIGH HALOGEN CONTENT AND LOW VISCOSITY 审中-公开
标题翻译：具有高含量和低粘度的阻燃剂
公开(公告)号：WO2005023927A1
公开(公告)日：2005-03-17
申请号：PCT/US2004/026826
申请日：2004-08-19
申请人： ALBEMARLE CORPORATION , FESKE, Elbert, F. , CLARK, Nelson, E. , MACK, Arthur, G. , APLIN, Jeffrey, Todd
发明人： FESKE, Elbert, F. , CLARK, Nelson, E. , MACK, Arthur, G. , APLIN, Jeffrey, Todd
IPC分类号： C08K5/12
CPC分类号： C08K5/1539 , C08G2101/00 , C08K5/0066 , C08K5/053 , C08K5/11 , C08K5/1515
摘要： A flame retardant formulation which is the combination of at least (1) at least one bromine-containing polyol flame retardant formed from the reaction of (a) tetrabromophthalic anhydride, (b) an aliphatic polyol, and (c) an epoxide, and (2) at least one aliphatic diester of an alkane dicarboxylic acid, with the proviso that the formulation has a viscosity at 25°C of about 20,000 cps or less, and a bromine content of at least about 40 wt%. A flame retardant compound formed from A) tetrabromophthalic anhydride; B) diethylene glycol; C) at least one alpha-omega alkane diol, or at least one alpha-omega alkane diol and at least one aliphatic monool; and D) at least one alkylene oxide; with the proviso that the compound has a viscosity at 25°C of about 60,000 cps or less, and a bromine content of at least about 43 wt%. Polymer compositions formed from (a) a polyurethane or a polyisocyanurate and (b) a formulation of the invention. One process to make a formulation involves heating a mixture of (a), (b), and at least one liquid aliphatic diester of a alkane dicarboxylic acid to form an intermediate composition; and then the intermediate is contacted one or more times with (c) thereby producing the formulation. Optionally, excess (c) is removed.
摘要翻译：阻燃剂组合物，其是由（a）四溴邻苯二甲酸酐，（b）脂族多元醇和（c）环氧化物的反应形成的至少（1）至少一种含溴多元醇阻燃剂和（c） 2）烷烃二羧酸的至少一种脂族二酯，条件是制剂在25℃下的粘度为约20,000cps或更低，溴含量为至少约40重量％。由A）四溴邻苯二甲酸酐形成的阻燃化合物; B）二甘醇; C）至少一种α-ω链烷二醇，或至少一种α-ω链烷二醇和至少一种脂族一元醇; 和D）至少一种环氧烷; 条件是该化合物在25℃下的粘度为约60,000cps或更低，溴含量为至少约43重量％。由（a）聚氨酯或聚异氰尿酸酯和（b）本发明的制剂形成的聚合物组合物。制备制剂的一个方法包括加热（a），（b）和至少一种烷烃二羧酸的液体脂族二酯的混合物以形成中间体组合物; 然后将中间体与（c）一次或多次接触，从而制备制剂。任选地，除去过量（c）。

8. 发明申请

WO2008134733A1 OLIGOMERIC PHOSPHONATE COMPOSITIONS, THEIR PREPARATION AND USES 审中-公开
标题翻译：低分子磷酸盐组合物，其制备和用途
公开(公告)号：WO2008134733A1
公开(公告)日：2008-11-06
申请号：PCT/US2008/062037
申请日：2008-04-30
申请人： ALBEMARLE CORPORATION , MACK, Arthur, G. , TSAO, Techen , SAUER, Anne, M.
发明人： MACK, Arthur, G. , TSAO, Techen , SAUER, Anne, M.
IPC分类号： C07F9/40
CPC分类号： C07F9/4075 , C07F9/4081
摘要： This invention provides oligomeric hydrogen phosphonates represented by the formula (I) where R is an alkyl group having one to about six carbon atoms; R' is a linear or branched hydrocarbylene group or an oxygen-containing hydrocarbylene group having two to about twenty carbon atoms or a hydrocarbylene group having at least one cycloaliphatic or aromatic ring, where at least one of R' is a linear or branched hydrocarbylene group or an oxygen-containing hydrocarbylene group and at least one of R' is a hydrocarbylene group having at least one cycloaliphatic or aromatic ring; and n is a number from 2 to about 20. Also provided are processes for making these oligomeric hydrogen phosphonates, oligomeric organophosphonate compositions, and processes for making these oligomeric organophosphonate compositions.
摘要翻译：本发明提供由式（I）表示的低聚氢膦酸盐，其中R是具有1至约6个碳原子的烷基; R'是具有2至约20个碳原子的直链或支链亚烃基或含氧亚烃基或具有至少一个脂环族或芳族环的亚烃基，其中至少一个R'是直链或支链亚烃基或含氧亚烃基，并且R'中的至少一个是具有至少一个脂环族或芳族环的亚烃基; 并且n是2至约20的数。还提供了制备这些低聚氢膦酸盐，低聚有机膦酸盐组合物的方法以及制备这些低聚有机膦酸盐组合物的方法。

9. 发明申请

WO2010048121A1 MIXED GLYCOL POLYPHOSPHONATE COMPOUNDS 审中-公开
标题翻译：混合的甘油聚磷酸酯化合物
公开(公告)号：WO2010048121A1
公开(公告)日：2010-04-29
申请号：PCT/US2009/061241
申请日：2009-10-20
申请人： ALBEMARLE CORPORATION , MACK, Arthur, G. , TSAO, Techen
发明人： MACK, Arthur, G. , TSAO, Techen
IPC分类号： C07F9/40 , C08K5/00 , C08K5/5333
CPC分类号： C07F9/4084 , C08G79/04
摘要： New highly-effective non-halogen, low VOC, low fogging, and cost-effective oligomeric polyphosphonate flame retardants for flexible polyurethane foams as well as for other flame retardant applications are described. In addition, methods for the preparation and uses of such new highly effective flame retardants are described. Formula (I)
摘要翻译：描述了用于柔性聚氨酯泡沫以及其它阻燃应用的新型高效无卤素，低VOC，低雾度和低成本低聚聚膦酸酯阻燃剂。另外，还描述了制备和使用这种新的高效阻燃剂的方法。式（I）

10. 发明申请

WO2008118695A1 USE OF LOW TRIPHENYLPHOSPHATE, HIGH PHOSPHOROUS CONTENT ISOPROPYL PHENYL PHOSPHATES AS FLAME RETARDANTS IN RESINS 审中-公开
标题翻译：低三磷酸磷酸盐，高磷酸盐异丙基苯酚磷酸盐作为树脂中的阻燃剂使用
公开(公告)号：WO2008118695A1
公开(公告)日：2008-10-02
申请号：PCT/US2008/057395
申请日：2008-03-19
申请人： ALBEMARLE CORPORATION , LAYMAN, JR., William, J. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, T. , LUTHER, Douglas, W.
发明人： LAYMAN, JR., William, J. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, T. , LUTHER, Douglas, W.
IPC分类号： C08K5/523 , C08L27/06 , C07F9/12
CPC分类号： C08K5/523 , C07F9/12
摘要： The present invention relates to the use of low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation as flame retardant compositions.
摘要翻译：本发明涉及具有高邻苯基烷基化作用的低磷酸三苯酯，高含磷芳基磷酸酯作为阻燃剂组合物的用途。

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