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1. 发明申请

WO2007005400A3 ALUMINOXANATE SALT COMPOSITIONS HAVING IMPROVED STABILITY IN AROMATIC AND ALIPHATIC SOLVENTS 审中-公开
标题翻译：在芳香族和脂肪族溶剂中具有改善的稳定性的氧化铝盐组合物
公开(公告)号：WO2007005400A3
公开(公告)日：2007-03-08
申请号：PCT/US2006024905
申请日：2006-06-27
申请人： ALBEMARLE CORP , SANGOKOYA SAMUEL A , DIEFENBACH STEVEN P , DALY CHRISTOPHER , SIMERAL LARRY S
发明人： SANGOKOYA SAMUEL A , DIEFENBACH STEVEN P , DALY CHRISTOPHER , SIMERAL LARRY S
IPC分类号： C07F5/06 , C07F7/08
CPC分类号： C07F5/066 , C07F5/068 , C07F7/0843
摘要： The present invention provides soluble aluminoxanate salt compositions, methods for preparing soluble aluminoxanate salt compositions, catalyst compositions comprising soluble aluminoxanate salt compositions, and methods for polymerizing olefins using catalyst compositions comprising soluble aluminoxanate salt compositions. Aluminoxanate salt compositions of the present invention are soluble in aromatic and aliphatic solvents and have improved solution stability and superior activator efficiency as compared to conventional aluminoxanes or modified aluminoxanes.
摘要翻译：本发明提供可溶性铝氧酸盐组合物，制备可溶性铝氧酸盐组合物的方法，包含可溶性铝氧烷酸盐组合物的催化剂组合物，以及使用包含可溶性铝氧烷酸盐组合物的催化剂组合物聚合烯烃的方法。与常规铝氧烷或改性铝氧烷相比，本发明铝氧烷酸盐组合物可溶于芳族和脂族溶剂，并具有改善的溶液稳定性和优异的活化剂效率。

2. 发明申请

WO2007005676A3 ACTIVATOR COMPOSITIONS AND THEIR USE IN CATALYSTS AND OLEFIN POLYMERIZATION 审中-公开
标题翻译：活化剂组成及其在催化剂和烯烃聚合中的应用
公开(公告)号：WO2007005676A3
公开(公告)日：2007-05-24
申请号：PCT/US2006025709
申请日：2006-06-30
申请人： ALBEMARLE CORP , LUO LUBIN , LEE JOHN Y , DIEFENBACH STEVEN P , SANGOKOYA SAMUEL A , BAUCH CHRISTOPHER G
发明人： LUO LUBIN , LEE JOHN Y , DIEFENBACH STEVEN P , SANGOKOYA SAMUEL A , BAUCH CHRISTOPHER G
IPC分类号： C08F10/00 , C07F5/06 , C08F4/659 , C08F4/6592
CPC分类号： C08F10/00 , C07B2200/11 , C07F5/062 , C08F4/65927 , C08F110/06 , C08F4/65912 , C08F4/65916
摘要： This invention relates to compounds and catalyst compositions useful for olefin polymerization. In one aspect, this invention encompasses metal oxide-supported, Brønsted acidic, bulky aluminate activators and their utility for forming catalyst compositions comprising cationic d- block or f-block compounds ionically bonded with the supported aluminate activators. The catalysts of this invention are useful in olefin polymerization processes such as slurry or gas phase polymerization of ethylene or propylene which utilize supported catalysts.
摘要翻译：本发明涉及用于烯烃聚合的化合物和催化剂组合物。在一个方面，本发明包括金属氧化物负载的布朗斯台德酸性体积铝酸盐活化剂及其用于形成包含与负载型铝酸盐活化剂离子键合的阳离子d-嵌段或f-嵌段化合物的催化剂组合物的用途。本发明的催化剂可用于烯烃聚合方法，如使用负载型催化剂的乙烯或丙烯的淤浆或气相聚合。

3. 发明申请

WO2007131010A3 ALUMINOXANE COMPOSITIONS, THEIR PREPARATION, AND THEIR USE IN CATALYSIS 审中-公开
标题翻译：铝氧化物组合物，其制备及其在催化中的应用
公开(公告)号：WO2007131010A3
公开(公告)日：2008-02-28
申请号：PCT/US2007067983
申请日：2007-05-02
申请人： ALBEMARLE CORP , LUO LUBIN , SANGOKOYA SAMUEL A , STRICKLER JAMIE R , DIEFENBACH STEVEN P
发明人： LUO LUBIN , SANGOKOYA SAMUEL A , STRICKLER JAMIE R , DIEFENBACH STEVEN P
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/02 , C08F4/65912
摘要： Aluminoxane compositions derived from aluminoxane source, halogen source, and Lewis base are provided. Such compositions are useful for activating catalysts for olefin polymerization.
摘要翻译：提供衍生自铝氧烷源，卤素源和路易斯碱的氧化铝组合物。这样的组合物可用于活化烯烃聚合催化剂。

4. 发明申请

WO2008036594A3 CATALYST ACTIVATORS, PROCESSES FOR MAKING SAME, AND USE THEREOF IN CATALYSTS AND POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：催化剂活化剂，其制备方法及其在催化剂和烯烃聚合中的用途
公开(公告)号：WO2008036594A3
公开(公告)日：2008-07-24
申请号：PCT/US2007078629
申请日：2007-09-17
申请人： ALBEMARLE CORP , LUO LUBIN , DIEFENBACH STEVEN P
发明人： LUO LUBIN , DIEFENBACH STEVEN P
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F210/06 , C08F4/65916 , C08F4/65912 , C08F210/16
摘要： Compositions useful for activating catalysts for olefin polymerization are provided. The compositions are derived from at least carrier having at least two hydrogen bonded hydroxyl groups, organoaluminum compound, Lewis base, and Bronsted acid, wherein the Lewis base and the Bronsted acid form at least one ionic Bronsted acid.
摘要翻译：提供可用于活化烯烃聚合催化剂的组合物。该组合物至少由具有至少两个氢键合羟基的载体，有机铝化合物，路易斯碱和布朗斯台德酸衍生而来，其中路易斯碱和布朗斯台德酸形成至少一种离子布朗斯特酸。

5. 发明申请

WO2008036591A2 CATALYST ACTIVATORS, PROCESSES FOR MAKING SAME, AND USE THEREOF IN CATALYSTS AND POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：催化剂活化剂，其制备方法及其在催化剂中的应用和烯烃的聚合
公开(公告)号：WO2008036591A2
公开(公告)日：2008-03-27
申请号：PCT/US2007078623
申请日：2007-09-17
申请人： ALBEMARLE CORP , LUO LUBIN , WANG ZHIKE , DIEFENBACH STEVEN P
发明人： LUO LUBIN , WANG ZHIKE , DIEFENBACH STEVEN P
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F4/65927 , C08F4/65916 , C08F4/65912
摘要： A composition useful for activating catalysts for olefin polymerization is provided. The composition is derived from at least; carrier containing water; organoaluminum compound; N.N-dimethylaniline and pentaflurophenol in amounts such that there are at least two equivalents of pentafluorophenol per equivalent of the N,N-dimethylaniline.
摘要翻译：提供了可用于活化烯烃聚合催化剂的组合物。该组合物至少衍生自; 含水载体有机铝化合物; N，N-二甲基苯胺和五氟苯酚的用量使得每当量的N，N-二甲基苯胺存在至少两当量的五氟苯酚。

6. 发明申请

WO2008076632A2 CATALYST ACTIVATORS, PROCESSES FOR MAKING SAME, AND USE THEREOF IN CATALYSTS AND POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：催化剂活化剂，其制备方法及其在催化剂和烯烃聚合中的用途
公开(公告)号：WO2008076632A2
公开(公告)日：2008-06-26
申请号：PCT/US2007086397
申请日：2007-12-04
申请人： ALBEMARLE CORP , LUO LUBIN , WU XIAO , DIEFENBACH STEVEN P
发明人： LUO LUBIN , WU XIAO , DIEFENBACH STEVEN P
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F4/65925 , C08F210/16 , C08F4/65912 , C08F4/65916 , C08F210/14
摘要： Compositions useful for activating catalysts for olefin polymerization are-provided. The compositions are derived from at least: a) compound derived from at least (i) carrier having at least one pair of hydrogen bonded hydroxyl groups, (ii) organoaluminum compound, and (iii) Lewis base, such that each of a majority of aluminum atoms in the organoaluminum compound forms chemical bonds with at least two oxygen atoms from the at least one pair of hydrogen bonded hydroxyl groups; and b) Bronsted acid, wherein the molar ratio of the Bronsted acid to the organoaluminum compound is less than or equal to about 2:1.
摘要翻译：提供可用于活化烯烃聚合催化剂的组合物。所述组合物至少衍生自：a）衍生自至少（i）具有至少一对氢键合羟基的载体，（ii）有机铝化合物和（iii）路易斯碱的化合物，使得大部分有机铝化合物中的铝原子与至少一对氢键合的羟基中的至少两个氧原子形成化学键; 和b）布朗斯台德酸，其中布朗斯台德酸与有机铝化合物的摩尔比小于或等于约2:1。

7. 发明申请

WO2007005921A3 BRONSTED ACIDIC ALUMINOXANE COMPOSITIONS AND THEIR USE IN OLEFIN POLYMERIZATION CATALYST COMPOSITIONS 审中-公开
标题翻译：青铜酸性氧化铝组合物及其在烯烃聚合催化剂组合物中的用途
公开(公告)号：WO2007005921A3
公开(公告)日：2007-05-24
申请号：PCT/US2006026113
申请日：2006-07-01
申请人： ALBEMARLE CORP , LUO LUBIN , DIEFENBACH STEVEN P , MATHUR RAJEEV S , WINKLER UWE F , WU XIAO
发明人： LUO LUBIN , DIEFENBACH STEVEN P , MATHUR RAJEEV S , WINKLER UWE F , WU XIAO
IPC分类号： C08F10/00 , C07F5/06 , C08F4/659 , C08F4/6592
CPC分类号： C07F5/066 , C08F4/65916 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/14 , C08F4/65912
摘要： This invention provides activator compositions comprising Brønsted acidic aluminoxanes that are stabilized with inert functional groups, Lewis bases, or both. Methods to make and use such activator compositions to form metallocene-based olefin polymerization catalysts are also provided.
摘要翻译：本发明提供了包含用惰性官能团，路易斯碱或两者稳定的布朗斯特酸性铝氧烷的活化剂组合物。还提供了制备和使用这种活化剂组合物以形成基于金属茂的烯烃聚合催化剂的方法。

8. 发明申请

WO2008011267A3 CATALYST ACTIVATORS, PROCESSES FOR MAKING SAME, AND USE THEREOF IN CATALYSTS AND POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：催化剂活化剂，其制备方法及其在催化剂中的应用和烯烃的聚合
公开(公告)号：WO2008011267A3
公开(公告)日：2008-04-24
申请号：PCT/US2007072645
申请日：2007-07-02
申请人： ALBEMARLE CORP , LUO LUBIN , WANG ZHIKE , DIEFENBACH STEVEN P
发明人： LUO LUBIN , WANG ZHIKE , DIEFENBACH STEVEN P
IPC分类号： C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/6592 , C08F110/02 , C08F210/16 , Y10S526/943 , C08F4/65912
摘要： A composition useful for activating catalysts for olefin polymerization is provided. The composition is derived from at least: carrier; organoaluminoxy compound; N,N- dimethylaniline and pentaflurophenol in amounts such that them are at least two equivalents of pentafluorophenol per equivalent of the N, N-dimefhylaniline.
摘要翻译：提供了可用于活化烯烃聚合催化剂的组合物。该组合物至少衍生自：载体; 有机铝氧化合物 N，N-二甲基苯胺和五氟苯酚，其用量为每当量N，N-二甲苯胺苯胺至少两当量五氟苯酚。

9. 发明申请

WO2007076398A3 CATALYST ACTIVATORS, PROCESSES FOR MAKING SAME, AND USE THEREOF IN CATALYSTS AND POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：催化剂活化剂，其制备方法及其在催化剂中的应用和烯烃的聚合
公开(公告)号：WO2007076398A3
公开(公告)日：2007-11-15
申请号：PCT/US2006062406
申请日：2006-12-20
申请人： ALBEMARLE CORP , LUO LUBIN , DIEFENBACH STEVEN P , WANG ZHIKE
发明人： LUO LUBIN , DIEFENBACH STEVEN P , WANG ZHIKE
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F4/65916 , C08F4/65922 , C08F4/65912
摘要： A composition useful for activating catalysts for olefin polymerization is provided. The composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron withdrawing group and at least one active proton; and Lewis base. Alternatively, the composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron withdrawing group and at least one active proton; and ionic compound having at least one active proton. Alternatively, the composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron donating group and at least one active proton; and, optionally, Lewis base. Alternatively, the composition is derived from at least: carrier; organoaluminoxy compound; component having at least one electron withdrawing group and at least one active proton; and component having at least one electron donating group and at least one active proton - and optionally, the composition comprises Lewis base.
摘要翻译：提供了可用于活化烯烃聚合催化剂的组合物。该组合物至少衍生自：载体; 有机铝氧化合物组分具有至少一个吸电子基团和至少一个活性质子; 和路易斯基地。或者，组合物至少从载体衍生; 有机铝氧化合物组分具有至少一个吸电子基团和至少一个活性质子; 和具有至少一个活性质子的离子化合物。或者，组合物至少从载体衍生; 有机铝氧化合物具有至少一个给电子基团和至少一个活性质子的组分; 和任选的路易斯碱。或者，组合物至少从载体衍生; 有机铝氧化合物组分具有至少一个吸电子基团和至少一个活性质子; 和具有至少一个给电子基团和至少一个活性质子的组分 - 并且任选地，该组合物包含路易斯碱。

10. 发明申请

WO0198381A3 POLYMERIZATION PROCESS USING SELF-SUPPORTED CATALYSTS 审中-公开
标题翻译：使用自支撑催化剂的聚合工艺
公开(公告)号：WO0198381A3
公开(公告)日：2003-01-16
申请号：PCT/US0119251
申请日：2001-06-13
申请人： ALBEMARLE CORP
发明人： KNEALE BRIAN , BOONE JAMES E , DIEFENBACH STEVEN P , LOECHELT CECIL P , PRINDLE JOHN C JR
IPC分类号： C08F4/642 , C08F4/649 , C08F4/6592 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/02 , C08F4/65912 , C08F4/6492 , C08F2500/18 , C08F2500/24
摘要： A polymer is formed continuously from at least one polymerizable aliphatic 1-olefin in a continuous polymerization process. Concurrently a catalytically-active, prepolymerized, self-supported olefin polymerization catalyst composition is being formed at the same plant facility or in a facility in proximity to the facility in which the continuous polymerization process is being performed. Catalyst from the prepolymerization facility is continuously or substantially continuously fed to the continuous polymerization process. The prepolymerization is conducted using: i) a polymerizable vinylolefin and ii) at least one metallocene of a transition, lanthanide, or actinide metal, and at least one aluminoxane, and/or at least one reaction product of at least one metallocene and at least one aluminoxane. The metallocene or at least one of the metallocenes has in the molecule prior to prepolymerization at least one polymerizable olefinic substituent.
摘要翻译：在连续聚合方法中，由至少一种可聚合脂族1-烯烃连续形成聚合物。同时，催化活性的，预聚合的，自负载的烯烃聚合催化剂组合物正在相同的设备设施或在其中进行连续聚合过程的设施附近的设施中形成。来自预聚合设备的催化剂连续地或基本连续地进料到连续聚合过程中。使用以下方法进行预聚合：i）可聚合的烯烃和ii）至少一种过渡金属茂，镧系元素或锕系金属，和至少一种铝氧烷，和/或至少一种至少一种茂金属和至少一种金属茂的反应产物一个铝氧烷茂金属或至少一种金属茂在预聚合之前在分子中具有至少一个可聚合的烯属取代基。

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