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    • 3. 发明申请
    • POLYMERIC CORROSION INHIBITORS
    • 聚合物腐蚀抑制剂
    • WO2011000895A1
    • 2011-01-06
    • PCT/EP2010/059325
    • 2010-07-01
    • AKZO NOBEL CHEMICALS INTERNATIONAL B.V.HELLBERG, Per-ErikGOROCHOVCEVA, Natalija
    • HELLBERG, Per-ErikGOROCHOVCEVA, Natalija
    • C23F11/173C02F5/12C09K8/54C23F11/14
    • C23F11/173C02F5/12C02F2303/08C09K8/54C10G75/02C10G2300/4075C23F11/145
    • The present invention relates to the use of a product obtainable by the reaction of an alkoxylated fatty amine having the formula (I) wherein R is a hydrocarbyl group having 8-24 carbon atom; each B is, independently, an alkyl group having 1-4 carbon atoms, a benzyl group, or the group (AO) n H, wherein A is an alkylene group containing 2-4 carbon atoms, preferably 2 carbon atoms; each n is at least 1 and the sum of all n is 2-30; x is 2 or 3; and y is 0-3, preferably 0 or 1; or of a product obtainable by partial or total quaternisation of the alkoxylated fatty amine of formula (I); with a dicarboxylic acid derivative having the formula (IIa) or (IIb) wherein D is -OH, -Cl, or -OR3, wherein R3 is a C1-C4 alkyl group; R2 is an alkylene radical of formula -(CH 2 ) z -, wherein z is an integer from 0 to 10, preferably from 2 to 4, and most preferably 2, and wherein the alkylene radical may be substituted by 1 or 2 -OH groups; the group –CH=CH-, or the o-phenylene group; or by reacting a product (I) with a dicarboxylic acid derivative (IIa) or (IIb), followed by partial or total quaternisation of the reaction product obtained; or by reacting a product (I) with a dicarboxylic acid derivative (IIa) or (IIb), followed by partial or total quaternisation of the reaction product obtained, wherein the product consists to > 60% w/w of oligomers/polymers with at least two alkoxylated amine units and one or more diacid/acid anhydride unit and to > 50% w/w of oligomers/polymers with at least two alkoxylated amine units and two or more diacid/acid anhydride units; as a corrosion inhibitor for metal surfaces. The invention also relates to a method for protecting a metal surface from corrosion by contacting the metal surface with said corrosion inhibitor.
    • 本发明涉及通过具有式(I)的烷氧基​​化脂肪胺与其中R是具有8-24个碳原子的烃基反应的产物的用途; 每个B独立地为具有1-4个碳原子的烷基,苄基或(AO)nH基团,其中A是含有2-4个碳原子,优选2个碳原子的亚烷基; 每个n至少为1,所有n的和为2-30; x为2或3; y为0-3,优选为0或1; 或通过式(I)的烷氧基​​化脂肪胺的部分或全部季铵化获得的产物; 与具有式(IIa)或(IIb)的二羧酸衍生物,其中D是-OH,-Cl或-OR 3,其中R 3是C 1 -C 4烷基; R 2是式 - (CH 2)z - 的亚烷基,其中z是0至10,优选2至4,最优选2的整数,并且其中亚烷基可以被1或2个-OH基团取代 ; 基团-CH = CH-或邻 - 亚苯基; 或通过使产物(I)与二羧酸衍生物(IIa)或(IIb)反应,然后部分或全部季铵化所得的反应产物; 或通过使产物(I)与二羧酸衍生物(IIa)或(IIb)反应,然后将获得的反应产物进行部分或全部季铵化反应,其中产物为> 60%w / w的低聚物/聚合物,其中 至少两个烷氧基化胺单元和一个或多个二酸/酸酐单元,并且具有至少两个烷氧基化胺单元和两个或更多个二酸/酸酐单元的低聚物/聚合物> 50%w / w; 作为金属表面的腐蚀抑制剂。 本发明还涉及通过使金属表面与所述腐蚀抑制剂接触来保护金属表面免受腐蚀的方法。