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1. 发明申请

WO2016040783A1 LOW EMISSIONS POLYURETHANE FOAM MADE WITH ISOCYANATE REACTIVE AMINE CRYSTALS 审中-公开
标题翻译：低发射聚氨酯泡沫与异氰酸酯反应性氨基水晶
公开(公告)号：WO2016040783A1
公开(公告)日：2016-03-17
申请号：PCT/US2015/049655
申请日：2015-09-11
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , PANITZCH, Torsten , KELLER, Renee Jo
IPC分类号： C08G18/66 , C08G18/76 , C08G18/18 , C08G18/32 , C08G18/40 , C08G18/48 , C07C209/60 , C07C211/14 , C08G101/00
CPC分类号： C08G18/1808 , C07C209/48 , C07C211/14 , C07C253/30 , C08G18/0871 , C08G18/14 , C08G18/1825 , C08G18/3275 , C08G18/409 , C08G18/4804 , C08G18/4812 , C08G18/4841 , C08G18/6688 , C08G18/7621 , C08G18/7657 , C08G18/7671 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J9/0061 , C08J2205/05 , C08J2205/06 , C08J2375/08 , C07C255/24
摘要： Tertiary amine catalysts having isocyanate reactive groups capable of forming thermally stable covalent bonds able to withstand temperatures from 120oC and higher and up to 250oC are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60); b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25oC to 90oC); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.
摘要翻译：公开了具有能够形成能够承受120℃以上且高达250℃的温度的热稳定共价键的具有异氰酸酯反应性基团的叔胺催化剂。这些催化剂可用于生产具有以下所需特性的聚氨酯泡沫：a）在宽范围的环境条件和异氰酸酯指数（例如低至65但高于60的指数）下的非常低的化学物质排放; b）即使在高于环境温度（温度范围25oC至90oC）的情况下，泡沫暴露于水或水溶液时，b）充分的水解稳定性可保持催化剂共价结合泡沫，而不会浸出叔胺催化剂。和c）聚氨酯聚合物和其它聚合物（例如聚碳酸酯）之间的稳定的接触界面，其中叔胺催化剂从聚氨酯聚合物到其它聚合物的最小迁移，即使在热和湿度的条件下也在接触点处没有显着的聚合物劣化。

2. 发明申请

WO2013002963A1 REDUCING EMISSIONS IN POLYURETHANE FOAM 审中-公开
标题翻译：降低聚氨酯泡沫中的排放
公开(公告)号：WO2013002963A1
公开(公告)日：2013-01-03
申请号：PCT/US2012/040652
申请日：2012-06-04
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , THURAU, Courtney Thompson , KELLER, Renee Jo , ARNOLD, Allen Robert, Jr.
发明人： BURDENIUC, Juan Jesus , THURAU, Courtney Thompson , KELLER, Renee Jo , ARNOLD, Allen Robert, Jr.
IPC分类号： B01J31/04 , B01J31/02 , C08G18/18
CPC分类号： B01J31/04 , B01J31/0237 , B01J31/0238 , B01J31/0244 , B01J31/0249 , B01J2231/14 , C08G18/1875 , C08G18/4072 , C08G18/4841 , C08G18/632 , C08G2101/0008 , C08G2101/0083 , C08G2290/00
摘要： This invention disclosure relates to a process to make flexible open cell polyurethane foam with optimum mechanical properties and lowest chemical emissions. Using the selection of tertiary amine catalysts together with a group of carboxylic acids according to this disclosure can produce foam products with optimum properties and lowest chemical emanations.
摘要翻译：本发明涉及制备具有最佳机械性能和最低化学物质排放的柔性开孔聚氨酯泡沫的方法。使用根据本公开的叔胺催化剂与一组羧酸的选择可以生产具有最佳性能和最低化学发射的泡沫产品。

3. 发明申请

WO2013143129A1 POLYURETHANE FOAM PRODUCTION PROCESS, PRE-MIX, FORMULATION, AND PRODUCT 审中-公开
标题翻译：聚氨酯泡沫生产工艺，预混料，配方和产品
公开(公告)号：WO2013143129A1
公开(公告)日：2013-10-03
申请号：PCT/CN2012/073339
申请日：2012-03-30
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , LENG, Boxun , PANITZSCH, Torsten , WENDEL, Stephan, Hermann , KELLER, Renee Jo
发明人： BURDENIUC, Juan Jesus , LENG, Boxun , PANITZSCH, Torsten , WENDEL, Stephan, Hermann , KELLER, Renee Jo
IPC分类号： C08G18/06 , C07C31/34 , C08G65/08 , C08G77/04
CPC分类号： C08J9/0019 , C08G18/163 , C08G18/1833 , C08G18/1875 , C08G18/246 , C08G18/2885 , C08G18/4009 , C08G18/4072 , C08G18/7621 , C08G2101/0008 , C08G2101/0016 , C08J9/142 , C08J2375/04
摘要： Disclosed are a process of producing a polyurethane foam product, a polyurethane foam product pre-mix, polyurethane foam product formulation, and a polyurethane foam product. The process of producing the polyurethane foam product includes contacting a halohydrin component with a polyurethane foam product pre-mix. The polyurethane foam product pre-mix includes the halohydrin component. The polyurethane foam product formulation includes a polyol component, an isocyanate component, and a halohydrin component. The polyurethane foam product is formed by the pre-mix having the halohydrin component.
摘要翻译：公开了生产聚氨酯泡沫产品，聚氨酯泡沫塑料产品预混物，聚氨酯泡沫塑料产品配方和聚氨酯泡沫产品的方法。生产聚氨酯泡沫产品的方法包括将卤代醇组分与聚氨酯泡沫产品预混物接触。聚氨酯泡沫产品预混物包括卤代醇组分。聚氨酯泡沫产品配方包括多元醇组分，异氰酸酯组分和卤代醇组分。通过具有卤代醇组分的预混物形成聚氨酯泡沫产品。

4. 发明申请

WO2012006548A1 ADDITIVES FOR IMPROVING POLYURETHANE FOAM PERFORMANCE 审中-公开
标题翻译：改善聚氨酯泡沫性能的添加剂
公开(公告)号：WO2012006548A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/043396
申请日：2011-07-08
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo , JEON, You-Moon
发明人： BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo , JEON, You-Moon
IPC分类号： C08G18/32 , C08G18/38 , C08G18/67 , C08J9/00 , C08K5/31
CPC分类号： C08J9/0042 , C08G18/1825 , C08G18/1875 , C08G18/325 , C08G18/3268 , C08G18/3838 , C08G18/4841 , C08G18/6688 , C08G18/678 , C08G2101/00 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2290/00 , C08J2375/08 , C08K5/31 , C08L75/04
摘要： Polyurethane foam compositions and processes to make flexible polyurethane foams are disclosed. Polyurethane foam is produced in the presence of additives comprising guanidine derivatives. Improvements in physical properties such as air flow, dimensional stability, tensile, tear, elongation and foam hardness is observed when these additives are present in polyurethane formulations. In addition, these additives can minimize polymer degradation under humid ageing conditions resulting in foam products with better mechanical properties.
摘要翻译：公开了聚氨酯泡沫组合物和制备柔性聚氨酯泡沫体的方法。在包含胍衍生物的添加剂的存在下生产聚氨酯泡沫。当这些添加剂存在于聚氨酯配方中时，观察到物理性能如气流，尺寸稳定性，拉伸，撕裂，伸长率和泡沫硬度的改善。此外，这些添加剂可以在潮湿老化条件下使聚合物降解最小化，从而产生具有更好机械性能的泡沫产品。

5. 发明申请

WO2012006539A1 PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM 审中-公开
标题翻译：生产柔性聚氨酯泡沫的方法
公开(公告)号：WO2012006539A1
公开(公告)日：2012-01-12
申请号：PCT/US2011/043385
申请日：2011-07-08
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , JEON, You-Moon , KELLER, Renee Jo
发明人： BURDENIUC, Juan Jesus , TOBIAS, James Douglas , JEON, You-Moon , KELLER, Renee Jo
IPC分类号： C08G18/16 , C08J9/00
CPC分类号： C08J9/0028 , C08G18/0838 , C08G18/16 , C08G18/185 , C08G18/4072 , C08G18/6552 , C08G2101/00 , C08G2101/0008 , C08J9/0033 , C08J9/0042 , C08J2205/05 , C08J2375/04 , C08J2375/08
摘要： A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N, N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH# 1100 as cell opening aides for 2-cyanoacetamide or other similar molecules containing active methylene or methine groups to make a polyurethane foam is also disclosed. The advantage of using cell opener aids results in a) no foam shrinkage; b) lower use levels of cell opener; c) foam performance reproducibility d) optimum physical properties. In addition, combining the acid blocked amine catalyst together with the cell opener and the cell opener aid results in a less corrosive mixture as well as provides a method that does not require mechanical crushing for cell opening.
摘要翻译：公开了用于制备柔性聚氨酯泡沫，特别是柔性模塑聚氨酯泡沫的组合物和方法。使用偶极非质子液体如DMSO，DMI，环丁砜，N-甲基 - 乙酰乙酰胺，N，N-二甲基乙酰乙酰胺以及羟基号为OH＃1100的二元醇作为2-氰基乙酰胺或含有活性亚甲基的其它类似分子的细胞开放助剂或次甲基以制备聚氨酯泡沫。使用细胞开放助剂的优点导致a）没有泡沫收缩; b）细胞开放剂的使用水平较低; c）泡沫性能重现性d）最佳物理性能。此外，将酸封闭的胺催化剂与开孔剂和开孔剂组合在一起导致较少的腐蚀性混合物，并且提供了不需要机械破碎以进行开孔的方法。

6. 发明申请

WO2016196643A1 REACTIVE AMINE CATALYSTS FOR POLYURETHANE APPLICATIONS 审中-公开
标题翻译：用于聚氨酯应用的反应性胺催化剂
公开(公告)号：WO2016196643A1
公开(公告)日：2016-12-08
申请号：PCT/US2016/035286
申请日：2016-06-01
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , PANITZSCH, Torsten , XI, Kai , KELLER, Renee Jo
IPC分类号： C08G18/76 , C08G18/18 , C08G18/65
CPC分类号： C08G18/1825 , C07C273/1809 , C08G18/1841 , C08G18/3203 , C08G18/657 , C08G18/7621 , C08G2101/0008 , C08G2101/0083 , C08J9/142 , C08J2205/06 , C08J2375/04
摘要： Tertiary amine catalysts having isocyanate reactive groups that are capable of forming thermally stable covalent bonds able to withstand temperatures up to 120C. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g. indexes as low as 65 but higher than 60) while meeting all physical property requirements; b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25C to 90C); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.
摘要翻译：具有异氰酸酯反应性基团的叔胺催化剂能够形成能够承受温度高达120℃的热稳定共价键。这些催化剂可用于生产具有以下所需特性的聚氨酯泡沫：a）在满足所有物理性能要求的同时，在广泛的环境条件和异氰酸酯指数（例如低至65但高于60的指数）下，化学物质排放量非常低。 b）即使在高于环境温度（温度范围25℃至90℃）的情况下，泡沫暴露于水或水溶液时，b）足够的水解稳定性以保持催化剂共价结合于泡沫体而不浸提叔胺催化剂; 和c）聚氨酯聚合物和其它聚合物（例如聚碳酸酯）之间的稳定的接触界面，其中叔胺催化剂从聚氨酯聚合物到其它聚合物的最小迁移，即使在热和湿度的条件下也在接触点处没有显着的聚合物劣化。

7. 发明申请

WO2016178793A1 DELAYED ACTION GELLING CATALYST COMPOSITIONS AND METHODS FOR MAKING POLYURETHANE POLYMERS 审中-公开
标题翻译：延迟行动胶凝催化剂组合物和制备聚氨酯聚合物的方法
公开(公告)号：WO2016178793A1
公开(公告)日：2016-11-10
申请号：PCT/US2016/026649
申请日：2016-04-08
申请人： AIR PRODUCTS AND CHEMICALS, INC.
发明人： BURDENIUC, Juan Jesus , WENDEL, Stephan Hermann , BRANDL, Christian , PANITZSCH, Torsten , KELLER, Renee Jo
IPC分类号： C08G18/48 , C08G18/63 , C08G18/66 , C08G18/76 , C08G18/20 , C08G18/24 , C08G18/32 , C08G18/34
CPC分类号： C08G18/244 , C08G18/165 , C08G18/1833 , C08G18/1841 , C08G18/2081 , C08G18/24 , C08G18/246 , C08G18/3206 , C08G18/3275 , C08G18/341 , C08G18/4072 , C08G18/4816 , C08G18/4829 , C08G18/4841 , C08G18/632 , C08G18/6674 , C08G18/6688 , C08G18/7621 , C08G18/7664 , C08G2101/0008 , C08G2101/0016 , C08J9/04 , C08J2375/04
摘要： Additives for making polyurethanes are disclosed. The additives are based on combining specific carboxylic acids or carboxylic di-acids together with a gelling catalysts obtained when mixing an isocyanate-reactive tertiary amine catalysts with dimethyl tin di carboxylate salts and/or dimethyltin mercaptide salts.
摘要翻译：公开了制备聚氨酯的添加剂。添加剂基于将特定羧酸或羧酸二酸与将异氰酸酯反应性叔胺催化剂与二甲基二锡二羧酸盐和/或二甲基锡硫醇盐混合时获得的胶凝催化剂组合。

8. 发明申请

WO2013006425A1 ADDITIVES FOR IMPROVING NATURAL OIL BASED POLYURETHANE FOAM PERFORMANCE 审中-公开
标题翻译：改善天然油基聚氨酯泡沫性能的添加剂
公开(公告)号：WO2013006425A1
公开(公告)日：2013-01-10
申请号：PCT/US2012/044892
申请日：2012-06-29
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo , JEON, You-Moon
发明人： BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo , JEON, You-Moon
IPC分类号： C08G18/66 , C08K5/31 , C08K5/315 , C08G18/38
CPC分类号： C08G18/6696 , C08G18/3838 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J9/0028 , C08J2205/06 , C08J2375/04 , C08K5/31 , C08K5/3155 , C08L75/04
摘要： Polyurethane foam compositions and processes to make flexible polyurethane foams are disclosed. Polyurethane foam is produced in the presence of additives comprising guanidine derivatives. Improvements in physical properties such as air flow, dimensional stability, tensile, tear, elongation and foam hardness is observed when these additives are present in polyurethane formulations. In addition, these additives can minimize polymer degradation under humid ageing conditions resulting in foam products with better mechanical properties.
摘要翻译：公开了聚氨酯泡沫组合物和制备柔性聚氨酯泡沫体的方法。在包含胍衍生物的添加剂的存在下生产聚氨酯泡沫。当这些添加剂存在于聚氨酯配方中时，观察到物理性能如气流，尺寸稳定性，拉伸，撕裂，伸长率和泡沫硬度的改善。此外，这些添加剂可以在潮湿老化条件下使聚合物降解最小化，从而产生具有更好机械性能的泡沫产品。

9. 发明申请

WO2013006413A1 PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM USING NATURAL OIL POLYOLS 审中-公开
标题翻译：使用天然油多酚生产柔性聚氨酯泡沫的方法
公开(公告)号：WO2013006413A1
公开(公告)日：2013-01-10
申请号：PCT/US2012/044860
申请日：2012-06-29
申请人： AIR PRODUCTS AND CHEMICALS, INC. , BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo
发明人： BURDENIUC, Juan Jesus , TOBIAS, James Douglas , KELLER, Renee Jo
IPC分类号： C08G18/30 , C08G18/32 , C08G18/48 , C08G18/66 , C08G18/76
CPC分类号： C08G18/14 , C08G18/302 , C08G18/3206 , C08G18/343 , C08G18/36 , C08G18/4841 , C08G18/6696 , C08G18/7621 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08J2205/06 , C08K5/0008 , C08K5/05 , C08K5/06 , C08K5/20 , C08K5/315 , C08K5/3445 , C08K5/41 , C08K5/45
摘要： A composition and process useful to make flexible polyurethane foams and in particular flexible molded polyurethane foams is disclosed. The usage of dipolar aprotic liquids such as DMSO, DMI, sulfolane, N-methyl-acetoacetamide, N, N-dimethylacetoacetamide as well as glycols containing hydroxyl numbers OH#
摘要翻译：公开了用于制备柔性聚氨酯泡沫，特别是柔性模塑聚氨酯泡沫的组合物和方法。使用偶极非质子液体如DMSO，DMI，环丁砜，N-甲基 - 乙酰乙酰胺，N，N-二甲基乙酰乙酰胺以及羟基数为OH＃<1100的二醇，作为2-氰基乙酰胺或含有活性的其它类似分子的细胞开放助剂也公开了亚甲基或次甲基以制备聚氨酯泡沫。使用细胞开放助剂的优点导致a）没有泡沫收缩; b）细胞开放剂的使用水平较低; c）泡沫性能重现性d）最佳物理性能。此外，将酸封闭的胺催化剂与开孔剂和开孔剂组合在一起导致较少的腐蚀性混合物，并且提供了不需要机械破碎以进行开孔的方法。

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