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1. 发明申请

WO2011018412A1 PRINTING UNIT AND PRINTING METHOD 审中-公开
标题翻译：打印单元和打印方法
公开(公告)号：WO2011018412A1
公开(公告)日：2011-02-17
申请号：PCT/EP2010/061449
申请日：2010-08-05
申请人： AGC GLASS EUROPE , JUNG, Dieter , SCHÖNBERGER, Andreas , HORNICKEL, Christian
发明人： JUNG, Dieter , SCHÖNBERGER, Andreas , HORNICKEL, Christian
IPC分类号： G03G15/16
CPC分类号： G03G15/1605 , G03G15/1625
摘要： The invention relates to a printing unit having a photoconductor which is in contact with a transfer belt, the transfer belt being deflected over deflection rolls and being capable of being brought into contact with a substrate to be printed in the region of a transfer zone. For the effective printing of electrically nonconductive substrates, in particular in mass production printing, the invention provides that, in the region of the transfer zone on the side of the transfer belt facing away from the substrate to be printed, there is arranged a transfer apparatus to which an electric voltage is applied in order to generate an electric charge in the region of the transfer zone. In this case, a high-frequency alternating current charge with a superimposed direct current charge is preferably generated.
摘要翻译：本发明涉及一种具有与转印带接触的光电导体的印刷单元，该转印带在偏转辊上偏转并且能够与转印区域中要印刷的基板接触。为了有效地印刷非导电性基材，特别是在大规模生产印刷中，本发明提供了在转印带背离待印刷基板一侧的转印区域的区域，设置有转印装置施加电压以在转印区域的区域中产生电荷。在这种情况下，优选地产生具有叠加的直流电荷的高频交流电荷。

2. 发明申请

WO2008128648A1 DEVELOPER UNIT FOR AN ELECTROPHOTOGRAPHIC PRINTING DEVICE FOR PRINTING ON GLASS OR CERAMIC MATERIAL 审中-公开
标题翻译：用于印刷玻璃或陶瓷材料的电子印刷印刷设备的开发单元
公开(公告)号：WO2008128648A1
公开(公告)日：2008-10-30
申请号：PCT/EP2008/002810
申请日：2008-04-10
申请人： AGC FLAT GLASS EUROPE SA , JUNG, Dieter , SCHÖNBERGER, Andreas , HORNICKEL, Christian
发明人： JUNG, Dieter , SCHÖNBERGER, Andreas , HORNICKEL, Christian
IPC分类号： G03G15/08 , G03G15/09
CPC分类号： G03G15/0907 , G03G15/0813 , G03G15/0818 , G03G2215/00312 , G03G2221/163
摘要： The invention relates to a developer unit for an electrophotographic printing device for printing on glass or ceramic material having a toner supply and a magnetic roll (22) for applying toner to a photoconductor (10), which is connected to a substrate to be printed, directly or with the interposition of a transfer device (20). According to the invention, a conditioning medium (24) for transferring the toner acts between the magnetic roll (22) and the photoconductor (10).
摘要翻译：本发明涉及一种用于印刷玻璃或陶瓷材料的电子照相印刷装置的显影装置，该装置具有调色剂供应装置和用于将调色剂施加到与待印刷的基板连接的光电导体（10）的磁性辊（22）直接或通过插入传送设备（20）。根据本发明，用于转印调色剂的调理介质（24）作用在磁辊（22）和感光体（10）之间。

3. 发明申请

WO2008128649A1 DEVELOPER UNIT FOR AN ELECTROPHOTOGRAPHIC PRINTING DEVICE FOR PRINTING ON GLASS OR CERAMIC MATERIAL 审中-公开
标题翻译：用于印刷玻璃或陶瓷材料的电子印刷印刷设备的开发单元
公开(公告)号：WO2008128649A1
公开(公告)日：2008-10-30
申请号：PCT/EP2008/002811
申请日：2008-04-10
申请人： AGC FLAT GLASS EUROPE SA , JUNG, Dieter , SCHÖNBERGER, Andreas , HORNICKEL, Christian
发明人： JUNG, Dieter , SCHÖNBERGER, Andreas , HORNICKEL, Christian
IPC分类号： G03G15/08
CPC分类号： G03G15/0805
摘要： The invention relates to a developer unit for an electrophotographic printing device for printing on glass or ceramic material having a toner supply (30, 32) and a toner application device (38), toner being discharged onto a developer device (18) by means of the toner application device (38) and it being possible for the developer device (18) to be brought into flat contact with a photoconductor (10). According to the invention, the developer device (18) has a fibre coating (19) of electrically conductive fibres, which picks up the toner and is in contact with the photoconductor (10) in order to transfer the toner.
摘要翻译：本发明涉及一种用于在具有调色剂供给（30,32）和调色剂施加装置（38）的玻璃或陶瓷材料上印刷的电子照相印刷装置的显影剂单元，调色剂通过以下方式排放到显影剂装置（18）上：调色剂施加装置（38），并且显影装置（18）可以与感光体（10）平坦接触。根据本发明，显影装置（18）具有导电纤维的光纤涂层（19），其拾取调色剂并与感光体（10）接触以转印调色剂。

4. 发明申请

WO2008141682A1 SYNTHESIS OF OLIGONUCLEOTIDES 审中-公开
标题翻译：合成寡核苷酸
公开(公告)号：WO2008141682A1
公开(公告)日：2008-11-27
申请号：PCT/EP2007/062660
申请日：2007-11-21
申请人： GIRINDUS AG , LANGE, Meinolf , HOHLFELD, Andreas , SCHÖNBERGER, Andreas , KIRCHHOFF, Christina , GRÖSSEL, Olaf
发明人： LANGE, Meinolf , HOHLFELD, Andreas , SCHÖNBERGER, Andreas , KIRCHHOFF, Christina , GRÖSSEL, Olaf
IPC分类号： C07H21/00
CPC分类号： C07H21/00
摘要： A method for preparing an oligonucleotide comprising the steps of a) providing a hydroxyl containing compound having the formula (1), wherein B is a heterocyclic base and the radicals R 2 , R 3 and R 5 are as defined in the description; b) reacting said compound with a phosphitylating agent in the presence of an activator having the formula (I) (activator I)), wherein R = alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl; R 1 , R 2 = either H or form a 5 to 6-membered ring together; X 1 , X 2 = independently either N or CH; Y = H or Si(R 4 ) 3 , with R 4 = alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl; B = deprotonated acid; to prepare a phosphitylated compound; c) reacting said phosphitylated compound without isolation with a second compound having the formula (1), wherein R 5 , R 3 , R 2 , B are independently selected, but have the same definition as above in the presence of an activator II selected from the group of imidazole imidazolium salts and mixtures thereof.
摘要翻译：一种制备寡核苷酸的方法，包括以下步骤：a）提供具有式（1）的含羟基化合物，其中B是杂环碱基，R 2，R 3， SUB＆gt;和R 5 5如说明书中所定义; b）在具有式（I）的活化剂（活化剂I））的存在下使所述化合物与磷酸酯化剂反应，其中R =烷基，环烷基，芳基，芳烷基，杂烷基，杂芳基; R 1，R 2，H或H或一起形成5至6元环; X 1，X 2独立地是N或CH; Y = H或Si（R 4）3，其中R 4 =烷基，环烷基，芳基，芳烷基，杂烷基，杂芳基; B =去质子酸制备磷酸化化合物; c）使所述磷化物化合物与所述式（1）的第二化合物分离而不分离，其中R 5，R 3，R 2， B独立选择，但在选自咪唑咪唑盐及其混合物的活化剂II的存在下具有与上述相同的定义。

5. 发明申请

WO2006094963A1 SYNTHESIS OF OLIGONUCLEOTIDES 审中-公开
标题翻译：合成寡核苷酸
公开(公告)号：WO2006094963A1
公开(公告)日：2006-09-14
申请号：PCT/EP2006/060489
申请日：2006-03-06
申请人： GIRINDUS AG , LANGE, Meinolf , SCHÖNBERGER, Andreas , HOHLFELD, Andreas , GRÖSSEL, Olaf , KIRCHHOFF, Christine , LINK, Fritz
发明人： LANGE, Meinolf , SCHÖNBERGER, Andreas , HOHLFELD, Andreas , GRÖSSEL, Olaf , KIRCHHOFF, Christine , LINK, Fritz
IPC分类号： C07H21/00
CPC分类号： C07H21/00 , Y02P20/55
摘要： A method for preparing an oligonucleotide comprising the steps of a) providing a hydroxyl containing compound having the formula (A), wherein B is a heterocyclic base and i) R 2 is H, a protected 2'-hydroxyl group, F, a protected amino group, an O-alkyl group, an O-substituted alkyl, a substituted alkylamino or a C4 '-O2 ' methylen linkage; R 3 is OR' 3 , NHR" 3 , NR" 3 R' 3 , wherein R 3 is a hydroxyl protecting group, a protected nucleotide or a protected oligonucleotide, R" 3 , R" 3 are independently amine protecting groups, and R 5 is OH or ii) R 2 is H, a protected 2'-hydroxyl group, F, a protected amino group, an O-alkyl group, an O-substituted alkyl, a substituted alkylamino or a C4'-O2 'methylen linkage; R 3 is OH and R 5 is OR' 5 and R' 5 is a hydroxyl protecting group, a protected nucleotide or a protected oligonucleotide or iii) R 2 is OH, R 3 is OR' 3 , NHR" 3 , NR" 3 R'" 3 , wherein R 3 is a hydroxyl protecting group, a protected nucleotide or a protected oligonucleotide, R" 3 , R" 3 are independently amine protecting groups, and R 5 is OR' 5 and R' 5 is a hydroxyl protecting group, a protected nucleotide or a protected oligonucleotide b) reacting said compound with a phosphitylating agent in the presence of an activator having the formula (I) (activator I) wherein R = alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl; R 1 , R 2 = either H or form a 5 to 6-membered ring together; X 1 , X 2 = independently either N or CH; Y = H or Si(R 4 ) 3 , with R 4 = alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl; B = deprotonated acid to prepare a phosphitylated compound; c) reacting said phosphitylated compound without isolation with a second compound having the formula (A) wherein R 5 , R 3 , R 2 , B are independently selected, but have the same definition as above in the presence of an activator II different from activator I.
摘要翻译：一种制备寡核苷酸的方法，包括以下步骤：a）提供具有式（A）的含羟基化合物，其中B是杂环碱基，i）R 2是H，被保护的2'- 羟基，F，被保护的氨基，O-烷基，O-取代的烷基，取代的烷基氨基或C 4'-O 2'亚甲基键; R 3是OR 3，NHR“3”，“NR”3 R“3” 其中R 3是羟基保护基，被保护的核苷酸或被保护的寡核苷酸，R“3，R”3个独立地是胺保护基，R 5是OH或ii）R 2是H，被保护的2'-羟基，F，被保护的氨基，O-烷基基团，O-取代的烷基，取代的烷基氨基或C4'-O2'亚甲基键; R 3是OH，R 5是OR 5，并且R 5是羟基保护基，受保护的核苷酸或受保护的寡核苷酸或iii）R 2是OH，R 3是OR 3，NHR“3，其中R 3是羟基保护基，受保护的核苷酸或受保护的寡核苷酸，R 3，R 3，R 3，R 3， “3”，R“3”3“独立地为胺保护基，R 5为OR'5和R' b）羟基保护基，受保护的核苷酸或受保护的寡核苷酸b）使所述化合物与磷酸化剂在存在下具有式（I）的活化剂（活化剂I）（其中R =烷基，环烷基，芳基，芳烷基，杂烷基，杂芳基; R 1，R 2 = H或一起形成5至6元环; X 1， X 2独立地是N或CH; Y = H或Si（R 4）3，其中R 1， 4 = alk 芳基，芳烷基，杂烷基，杂芳基; B =脱质子酸以制备磷酸化化合物; c）使所述磷化物化合物与不与其分离的具有式（A）的第二化合物反应，其中R 5，R 3，R 2，B，在不同于活化剂I的活化剂II的存在下，它们具有与上述相同的定义。

6. 发明申请

WO2006064039A1 SYNTHESIS OF PHOSPHITYLATED COMPOUNDS USING A QUATERNARY HETEROCYCLIC ACTIVATOR 审中-公开
标题翻译：使用四元杂环激活剂合成磷酸化合物
公开(公告)号：WO2006064039A1
公开(公告)日：2006-06-22
申请号：PCT/EP2005/056815
申请日：2005-12-15
申请人： GIRINDUS AG , LANGE, Meinolf , SCHÖNBERGER, Andreas , KIRCHHOFF, Christina , GRÖSSEL, Olaf , OMELCENKO, Nadja , HOHLFELD, Andreas , LINK, Fritz
发明人： LANGE, Meinolf , SCHÖNBERGER, Andreas , KIRCHHOFF, Christina , GRÖSSEL, Olaf , OMELCENKO, Nadja , HOHLFELD, Andreas , LINK, Fritz
IPC分类号： C07H21/00 , C07D233/54
CPC分类号： C07H21/04 , B01J31/0271 , C07H19/10 , C07H19/20 , C07H21/00 , C07H21/02
摘要： A method for preparing a phosphitylated compound comprising the step of: - reacting a hydroxy! containing compound with a phosphitylating agent in the presence of an activator having the formula (I) wherein R = alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl R 1 , R 2 = either H or form a 5 to 6-membered ring together. X 1, X 2 = independently either N or CH Y = H or Si(R 4 ) 3 , with R 4 = alkyl, cycloalkyl, aryl, aralkyl, heteroalkyl, heteroaryl B = deprotonated acid. The hydroxyl containing compound is preferably a sugar moiety or a nucleoside or an oligomer derived therefrom.
摘要翻译：一种制备磷酸化化合物的方法，包括以下步骤： - 使羟基在具有式（I）的活化剂存在下，将含磷酸化合物与磷酸化剂反应，其中R =烷基，环烷基，芳基，芳烷基，杂烷基，杂芳基R 1，R 2 > = H或形成5至6元环。 X 1，X 2独立地是N或CHY = H或Si（R 4）3， R 4 =烷基，环烷基，芳基，芳烷基，杂烷基，杂芳基B =去质子化的酸。含羟基化合物优选为糖部分或核苷或由其衍生的低聚物。

7. 发明申请

WO2006079660A1 PURIFICATION OF OLIGONUCLEOTIDES 审中-公开
标题翻译：纯化寡核苷酸
公开(公告)号：WO2006079660A1
公开(公告)日：2006-08-03
申请号：PCT/EP2006/050503
申请日：2006-01-30
申请人： GIRINDUS AG , LANGE, Meinolf , GRÖSSEL, Olaf , LINK, Fritz , SCHÖNBERGER, Andreas , HOHLFELD, Andreas
发明人： LANGE, Meinolf , GRÖSSEL, Olaf , LINK, Fritz , SCHÖNBERGER, Andreas , HOHLFELD, Andreas
IPC分类号： C07H21/00
CPC分类号： C07H21/00
摘要： A method for purifying a protected oligonucleotide comprising the steps of: a) - providing a solution of the protected oligonucleotide in at least one solvent A having a boiling point below the boiling point of a solvent B, - heating the solution at a temperature of at least 30°C and below the boiling point of the at least solvent A, - adding solvent B until precipitation of a material is visible in the solution, said solvent B being an alcohol having 1 to 6 C-atoms or a diol having 2 to 6 C-atoms, - allowing the solution to cool down under stirring until formation of a supernatant and a residue, - removing the supernatant or b) - providing solvent B, said solvent B being an alcohol having 1 to 6 C- atoms or a diol having 2 to 6 C-atoms, - heating solvent B at a temperature above 30°C and below the boiling point of solvent B, - adding a solution of a protected oligonucleotide in at least one solvent A until precipitation of a material is visible in the solution, - allowing the solution to cool down under stirring until formation of a supernatant and a residue, - removing the supernatant.
摘要翻译：一种用于纯化受保护的寡核苷酸的方法，包括以下步骤：a） - 将受保护的寡核苷酸的溶液提供在沸点低于溶剂B的沸点的至少一种溶剂A中， - 在至少30℃且低于至少溶剂A的沸点， - 加入溶剂B，直到在溶液中可见材料沉淀，所述溶剂B是具有1至6个C原子的醇或具有2至 6个C原子， - 允许溶液在搅拌下冷却直到形成上清液和残余物， - 去除上清液或b）提供溶剂B，所述溶剂B是具有1-6个C原子的醇或具有2至6个C原子的二醇， - 在高于30℃且低于溶剂B的沸点的温度下加热溶剂B， - 在至少一种溶剂A中加入受保护的寡核苷酸的溶液，直到材料沉淀可见在解决方案中， - 允许soluti 在搅拌下冷却直到形成上清液和残余物， - 除去上清液。

8. 发明申请

WO2004013154A1 METHOD FOR PREPARING OLIGONUCLEOTIDES 审中-公开
标题翻译：制备寡核苷酸的方法
公开(公告)号：WO2004013154A1
公开(公告)日：2004-02-12
申请号：PCT/EP2003/008447
申请日：2003-07-30
申请人： GIRINDUS AG , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , UNIVERSITY OF MONTPELLIER II , ADAMO, Ilaria , DUEYMES, Cécile , SCHÖNBERGER, Andreas , IMBACH, Jean-Louis , MEYER, Albert , MORVAN, Francois , DEBART, Francoise , VASSEUR, Jean-Jacques , LANGE, Meinolf , LINK, Fritz
发明人： ADAMO, Ilaria , DUEYMES, Cécile , SCHÖNBERGER, Andreas , IMBACH, Jean-Louis , MEYER, Albert , MORVAN, Francois , DEBART, Francoise , VASSEUR, Jean-Jacques , LANGE, Meinolf , LINK, Fritz
IPC分类号： C07H21/00
CPC分类号： C07H21/00 , C07H21/02 , C07H21/04 , Y02P20/55 , Y02P20/582
摘要： A method for preparing an oligonucleotide comprising the steps ofa) providing a 3 -protected compound having the formula: whereinB is a heterocyclic baseR2 is H, a protected 2 -hydroxyl group, F, a protected amino group, an O-alkyl group, an O-substituted alkyl, a substituted alkylamino or a C4′- O2′methylen linkage R3 is OR′3, NHR′′3, NR′′3R′′′3, a 3′-protected nucleotide or a 3′-protected oligonucleotide,R′3 is a hydroxyl protecting group,R′′3, R′′′3 are independently an amine protecting group, b) reacting said compound with a nucleotide derivative having a 5 -proctection group in the presence of a solid supported activator to give an elongated oligonucleotide with a P(III)-internucleotide bondc) optionally processing the elongated oligonucleotide with a P(III)-internucleotide bond by either or both of steps c1) and c2) in any sequencec1) capping preferably by reacting with a solid supported capping agentc2) oxidizing preferably by reacting the oligonucleotide with a solid supported oxidizing reagent d) removing the 5′ -protection group.
摘要翻译：一种制备寡核苷酸的方法，包括以下步骤：a）提供具有下式的3-保护的化合物：其中B是杂环碱基R2是H，受保护的2-羟基，F，被保护的氨基，O-烷基， O-取代的烷基，取代的烷基氨基或C 4'- O 2'亚甲基键R3是OR'3，NHR'3，NR''3R“'，3'-保护的核苷酸或3'-保护的寡核苷酸 R'3为羟基保护基，R“3”，“3”独立地为胺保护基团，b）在固体支持的活化剂存在下使所述化合物与具有5-保护基团的核苷酸衍生物反应给出具有P（III） - 核苷酸键的细长寡核苷酸c）任选地通过任何序列c1）和c2）中的任一个或两个步骤c1）和c2）用P（III） - 核苷酸键处理细长寡核苷酸，优选通过与固体负载的封端剂c2）优选通过使寡核苷酸与支持的固体反应而氧化氧化剂d）除去5'保护基。

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