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1. 发明申请

WO2011144995A1 A POLYMERIZATION CATALYST FOR POLYTHIOURETHANES, POLYMERIZABLE LIQUID COMPOSITION AND PROCESS FOR THE PRODUCTION OF ORGANIC POLYTHIOURETHANE GLASS WITH A HIGH REFRACTIVE INDEX 审中-公开
标题翻译：聚异氰脲酸聚合催化剂，可聚合液体组合物和生产具有高折射率指数的有机聚四氟乙烯玻璃的方法
公开(公告)号：WO2011144995A1
公开(公告)日：2011-11-24
申请号：PCT/IB2011/001087
申请日：2011-05-20
申请人： ACOMON AG , RENZI, Fiorenzo , FORESTIERI, Roberto , VECCHIONE, Andrea , BOS, Willem
发明人： RENZI, Fiorenzo , FORESTIERI, Roberto , VECCHIONE, Andrea , BOS, Willem
IPC分类号： C08G18/16 , C08G18/38 , C08G18/75 , G02B1/04 , C08G18/08
CPC分类号： G02B1/041 , C08G18/089 , C08G18/18 , C08G18/3876 , C08G18/758 , C08G2125/00 , G02B1/04 , G02B1/043 , G11B7/2533 , C08L75/04 , C08L81/00
摘要： Polymerization catalysts are described for organic polythiourethane glass which do not contain organometallic compounds, and consisting of a mixture of a tertiary aliphatic amine and a disubstituted phosphoric acid in a molar ratio ranging from 1/1.3 to 1/20. Polymerizable liquid compositions of the polythiourethane type are also described, essentially consisting of three components (A), (B) and (C), wherein component (A) contains at least one cycloaliphatic diisocyanate monomer wherein the weight percentage of free isocyanate groups in said component (A) ranges from about 20% to about 50% by weight, preferably from about 25% to about 40% by weight, with respect to the total weight of component (A); component (B) contains at least one polythiol having a molecular weight ranging from 50 to 1,200 g/moles, preferably from 100 to 1000 g/moles, and a functionality ranging from 2 to 5, preferably from 2 to 4, said components (A) and (B) being present in a weight ratio varying from 0.5:1 to 2:1; component (C) being said polymerization catalyst.The process is also described for the production of organic glass starting from said polymerizable liquid compositions of the polythiourethane type.
摘要翻译：对不含有机金属化合物的有机聚硫氨酯玻璃描述聚合催化剂，并由1 / 1.3〜1/20摩尔比的叔脂族胺和二取代磷酸的混合物组成。还描述了聚硫氨酯类型的可聚合液体组合物，其基本上由三种组分（A），（B）和（C）组成，其中组分（A）含有至少一种脂环族二异氰酸酯单体，其中所述组分（A）相对于组分（A）的总重量为约20重量％至约50重量％，优选约25重量％至约40重量％。组分（B）含有至少一种分子量为50至1200g / mol，优选为100至1000g / mol，官能度为2至5，优选2至4的多硫醇，所述组分（A ）和（B）以0.5:1至2:1的重量比存在; 组分（C）是所述聚合催化剂。还描述了从聚硫氨酯类型的所述可聚合液体组合物开始制备有机玻璃的方法。

2. 发明申请

WO2010043392A1 POLYMERIZABLE LIQUID COMPOSITION AND PROCESS FOR THE PRODUCTION OF ORGANIC GLASS STARTING FROM POLYMERIZABLE LIQUID COMPOSITIONS OF THE POLYURETHANE TYPE 审中-公开
标题翻译：可聚合液体组合物和从聚氨酯类聚合物组合物开始生产有机玻璃的方法
公开(公告)号：WO2010043392A1
公开(公告)日：2010-04-22
申请号：PCT/EP2009/007389
申请日：2009-10-14
申请人： ACOMON AG , BOS, Willem , RENZI, Fiorenzo , FORESTIERI, Roberto , VECCHIONE, Andrea
发明人： BOS, Willem , RENZI, Fiorenzo , FORESTIERI, Roberto , VECCHIONE, Andrea
IPC分类号： C08G18/08 , C08G18/16 , C08G18/32 , C08G18/75 , G02B1/04
CPC分类号： C08G18/089 , C08G18/168 , C08G18/3206 , C08G18/75 , G02B1/041 , Y10T428/1036 , Y10T428/31551 , C08L75/04
摘要： Polymer izable liquid compositions of the polyurethane type, consisting of two components (A) and (B), wherein component (A) contains at least one cyclo-aliphatic diisocyanate monomer or a mixture of one cyclo-aliphatic diisocyanate monomer and a pre -polymer obtained by reaction, in the presence of an acid phosphate ester catalyst, between said cyclo-aliphatic diisocyanate monomer and one or more polyols having two or more hydroxy 1 groups per molecule and a molecular weight ranging from 50 to 2,000 g/mole; the second component (B) contains one or more polyols having a molecular weight ranging from 50 to 2,000 g/mole and a functionality between 2 and 5; in the absence of polyalkoxylated tertiary diamines and or- ganometallic catalysts, said components (A) and (B) being present in a weight ratio which varies from 1:1 to 2:1 and the process for the production of organic glass starting from polymerizable liquid compositions of the polyurethane type.
摘要翻译：聚氨酯类型的可聚合液体组合物由两种组分（A）和（B）组成，其中组分（A）含有至少一种环脂族二异氰酸酯单体或一种环脂族二异氰酸酯单体和预聚物的混合物通过在酸式磷酸酯催化剂的存在下，在所述环脂族二异氰酸酯单体和一种或多种每分子具有两个或多个羟基1的多元醇和分子量为50-2,000g / mol之间反应得到; 第二组分（B）含有一种或多种分子量范围为50-2,000g / mol且官能度在2和5之间的多元醇; 在不存在聚烷氧基化叔胺和有机金属催化剂的情况下，所述组分（A）和（B）以1:1至2:1的重量比存在，以及从可聚合的聚氨酯类型的液体组合物。

3. 发明申请

WO2008092597A2 POLYMERIZABLE LIQUID COMPOSITION AND PROCESS FOR THE PRODUCTION OF ORGANIC GLASS OF THE POLYURETHANE TYPE 审中-公开
标题翻译：聚氨酯类有机玻璃的可聚合液体组合物和方法
公开(公告)号：WO2008092597A2
公开(公告)日：2008-08-07
申请号：PCT/EP2008/000523
申请日：2008-01-23
申请人： ACOMON AG , RENZI, Fiorenzo , FORESTIERI, Roberto , VECCHIONE, Andrea , BOS, Willem
发明人： RENZI, Fiorenzo , FORESTIERI, Roberto , VECCHIONE, Andrea , BOS, Willem
CPC分类号： C08G18/758 , C08G18/10 , C08G18/222 , C08G18/3206 , C08J5/00 , C08J2375/04 , G02B1/04 , G02B1/041 , C08L75/04
摘要： The present invention relates to a polymerizable liquid composition and a process for the production of organic glass of the polyurethane type, which envisages a casting and polymerization process of polymerizable liquid compositions, comprising the following phases: a) mixing two components (A) and (B), wherein component (A) consists of a mixture of a cyclo-aliphatic diisocyanate monomer and a pre-polymer obtained by reaction between said cyclo- aliphatic diisocyanate monomer and one or more polyols and two or more hydroxyl groups and component (B) con- sists of one or more polyols; b) addition of a polymerization catalyst to the polymerizable liquid composition obtained in phase a); c) mixing for a time varying from 5 to 10 minutes, at an absolute pressure ranging from 5 to 10 mbar and a temperature ranging from 10°C to 25°C; d) filling one or more moulds and polymerization of the liquid composition by thermal treatment.
摘要翻译：本发明涉及可聚合液体组合物和聚氨酯类有机玻璃的制备方法，其中设想了可聚合液体组合物的浇铸和聚合方法，其包括以下阶段：a）将两种组分（A）和（ B），其中组分（A）由环脂族二异氰酸酯单体和通过所述环脂族二异氰酸酯单体与一种或多种多元醇和两个或更多个羟基和组分（B）之间的反应获得的预聚物的混合物组成，由一种或多种多元醇组成; b）向在相a）中获得的可聚合液体组合物中加入聚合催化剂; c）混合时间为5至10分钟，绝对压力为5至10毫巴，温度为10℃至25℃; d）通过热处理填充一个或多个模具和液体组合物的聚合。

4. 发明申请

WO2004090002A1 LIQUID COMPOSITION POLYMERIZABLE INTO ORGANIC GLASS HAVING GOOD OPTICAL AND PHYSICO-MECHANICAL CHARACTERISTICS 审中-公开
标题翻译：液体组合物可聚合成具有良好光学和机械特性的有机玻璃
公开(公告)号：WO2004090002A1
公开(公告)日：2004-10-21
申请号：PCT/EP2004/003673
申请日：2004-04-06
申请人： GREAT LAKES CHEMICAL (EUROPE) GMBH , RENZI, Fiorenzo , BOS, Willem , POSTMUS, Simon , FORESTIERI, Roberto
发明人： RENZI, Fiorenzo , BOS, Willem , POSTMUS, Simon , FORESTIERI, Roberto
IPC分类号： C08F218/00
CPC分类号： C08F218/00 , G02B1/041
摘要： A liquid composition is described, which can undergo radicalic polymerization into organic glass, comprising: 1) the product obtained from the transesterification of diallyl carbonate (A) with a blend of one or more linear or branched aliphatic diols (B), containing from three to ten carbon atoms in the molecule, with a linear or branched aliphatic polyol (C), containing from four to twenty carbon atoms and from three to six hydroxyl groups in the molecule, in an overall concentration ranging from 70 to 100% by weight with respect to the total weight of the mixture of components 1) and 2); 2) one or more comonomers of the acrylic, methacrylic, vinylic or allylic type and mixtures thereof, in an overall concentration ranging from 0 to 30% by weight with respect to the total weight of the mixture of components 1) and 2); 3) a polymerization initiator or a mixture of two or more polymerization initiators, stable at room temperature, belonging to the group of peroxides, in an overall concentration ranging from 0.03 to 0.1 moles per 1 kg of final composition
摘要翻译：描述了可以经历自由基聚合成有机玻璃的液体组合物，其包括：1）由二烯丙基碳酸酯（A）与一种或多种直链或支链脂族二醇（B）的共混物的酯交换获得的产物，其含有三与分子中含有4至20个碳原子和3至6个羟基的直链或支链脂族多元醇（C）的总碳浓度在70至100重量％之间，分子中具有10个碳原子，相对于组分1）和2）的混合物的总重量; 2）一种或多种丙烯酸，甲基丙烯酸，乙烯酯或烯丙基类型的共聚单体及其混合物，其总浓度相对于组分1）和2）的混合物的总重量为0至30重量％。 3）聚合引发剂或两种或多种聚合引发剂的混合物，其在室温下稳定，属于过氧化物基团，总浓度范围为每1kg最终组合物为0.03至0.1摩尔

5. 发明申请

WO2004090003A1 LIQUID COMPOSITION POLYMERIZABLE INTO ORGANIC GLASS HAVING A LOW COLOURING AND GOOD PHYSICO-MECHANICAL PROPERTIES. 审中-公开
标题翻译：液体组合物可聚合成有机玻璃，具有低着色和良好的物理机械性能。
公开(公告)号：WO2004090003A1
公开(公告)日：2004-10-21
申请号：PCT/EP2004/003675
申请日：2004-04-06
申请人： GREAT LAKES CHEMICAL (EUROPE) GMBH , RENZI, Fiorenzo , BOS, Willem , POSTMUS, Simon , FORESTIERI, Roberto
发明人： RENZI, Fiorenzo , BOS, Willem , POSTMUS, Simon , FORESTIERI, Roberto
IPC分类号： C08F218/00
CPC分类号： G02B1/041 , C08F218/00
摘要： A liquid composition is described which can undergo radical polymerization into organic glass, comprising: 1) an allyl monomer or mixtures of two or more allyl monomers in an overall concentration ranging from 70 to 99% by weight with respect to the total weight of the mixture of components 1) and 2); 2) a vinyl ester in an overall concentration ranging from 1 to 30% by weight with respect to the total weight of the mixture of components 1) and 2); 3) a polymerization initiator or a mixture of two or more polymerization initiators belonging to the group of peroxides, in an overall concentration ranging from 0.05 to 0.15 moles per 1 kg of final composition.
摘要翻译：描述了可以进行自由基聚合成有机玻璃的液体组合物，其包括：1）烯丙基单体或两种或多种烯丙基单体的混合物，总浓度范围为70-99重量％，相对于混合物的总重量的部件1）和2）; 2）相对于组分1）和2）的混合物的总重量，总浓度为1至30重量％的乙烯基酯; 3）聚合引发剂或属于该组过氧化物的两种或更多种聚合引发剂的混合物，总浓度为每1kg最终组合物0.05至0.15摩尔。

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