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    • 2. 发明申请
    • FUEL CELL GAS DIFFUSION LAYER
    • 燃料电池气体扩散层
    • WO2005034271A2
    • 2005-04-14
    • PCT/US2004/028750
    • 2004-09-03
    • 3M INNOVATIVE PROPERTIES COMPANY
    • MEKALA, David R.,STEGINK, David W.,DAVID, Moses M.,FRISK, Joseph W.,
    • H01M8/02
    • H01M8/0239H01M8/023H01M8/0234H01M8/0243H01M8/0245H01M2008/1095Y02P70/56Y10T428/3154
    • The present invention provides a fuel cell gas diffusion layer comprising a hydrophilic surface layer having a thickness of no more than 1 micron, and, thereunder, a hydrophobic second layer comprising a fluoropolymer having a thickness of at least 5 microns. Additionally, the present invention provides a method of making a fuel cell gas diffusion layer comprising the steps of a) providing a carbon fiber construction; b) coating at least the upper surface of the carbon fiber construction with composition which comprises a fluoropolymer; and c) exposing the upper surface to at least one plasma, such as a silane plasma, so as to generate a hydrophilic surface layer having a thickness of no more than 1 micron. The present invention also provides a method additionally comprising the step of partially covering the upper surface with a mask having windows according to a pattern, such that the hydrophilic surface layer is applied according to the pattern. The present invention also provides a method wherein the carbon fiber construction is provided as a roll good and the step of exposing said upper surface to at least one plasma is performed in continuous roll-to-roll fashion.
    • 本发明提供一种燃料电池气体扩散层,其包括厚度不超过1微米的亲水性表面层,并且其后,包含厚度至少为5微米的含氟聚合物的疏水性第二层。 另外,本发明提供一种制造燃料电池气体扩散层的方法,包括以下步骤:a)提供碳纤维结构; b)至少涂覆含有含氟聚合物的组合物的碳纤维结构的上表面; 和c)将上表面暴露于至少一种等离子体,例如硅烷等离子体,以产生厚度不大于1微米的亲水性表面层。 本发明还提供一种方法,其还包括用根据图案的具有窗口的掩模部分地覆盖上表面的步骤,使得根据图案施加亲水性表面层。 本发明还提供了一种方法,其中碳纤维结构被提供为辊状,并且以连续的卷对卷方式进行将所述上表面暴露于至少一个等离子体的步骤。