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    • 6. 发明申请
    • ADHESIVE COMPOSITIONS COMPRISING A SILSESQUIOXANE POLYMER CROSSLINKER, ARTICLES AND METHODS
    • 包含SILSESQUIOXANE聚合物交联剂的粘合剂组合物,制品和方法
    • WO2015195391A1
    • 2015-12-23
    • PCT/US2015/034669
    • 2015-06-08
    • 3M INNOVATIVE PROPERTIES COMPANY
    • CHATTERJEE, JoonRATHORE, Jitendra S.GADDAM, Babu N.SETH, JayshreeLIPSCOMB, Corinne E.
    • C08F220/10C09J4/06C09J133/06C09J183/00
    • C09J4/06C08F220/10C08G77/442C09J11/04C09J133/06C09J183/10
    • Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslmker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10°C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The free-radically polymerizable solvent monomer, polymerized units of the solute (meth)acrylic polymer, or a combination thereof comprise a low Tg ethylenically unsaturated monomer. Also described are pressure sensitive adhesive articles and method of preparing adhesive articles.
    • 描述了包含至少一种低Tg烯键式不饱和单体和至少一种包含多个烯属不饱和基团的倍半硅氧烷聚合物交联剂的压敏粘合剂组合物。 低Tg烯属不饱和单体通常具有不高于10℃的Tg。 在一些实施方案中,组合物包含至少50,55,60,65或70重量%的低Tg烯属不饱和单体。 低Tg烯键式不饱和单体通常为包含4至20个碳原子的(甲基)丙烯酸烷基酯。 在另一个实施方案中,描述了包含糖浆的粘合剂组合物。 糖浆包含i)可自由基聚合的溶剂单体; ii)包含衍生自一种或多种(甲基)丙烯酸烷基酯单体的聚合单元的溶质(甲基)丙烯酸聚合物,和iii)至少一种包含多个烯键式不饱和基团的倍半硅氧烷聚合物交联剂。 可自由基聚合的溶剂单体,溶质(甲基)丙烯酸类聚合物的聚合单元或其组合包含低Tg烯属不饱和单体。 还描述了压敏粘合剂制品和制备粘合剂制品的方法。