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    • 2. 发明申请
    • チアゾロトリアゾール誘導体、その中間体および該誘導体を有効成分とする除草剤
    • 三唑衍生物,其中间体和含有衍生物作为活性成分的除草剂
    • WO2002102809A1
    • 2002-12-27
    • PCT/JP2002/005778
    • 2002-06-11
    • 科研製薬株式会社矢野 智行吉井 知子伊藤 博志植田 拓也
    • 矢野 智行吉井 知子伊藤 博志植田 拓也
    • C07D513/04
    • C07D513/04A01N43/90
    • Thiazolotriazole derivatives represented by the general formula (‖) or salts thereof; herbicides containing the derivatives or the salts as the active ingredient; and intermediates for the preparation of the derivatives: (‖) (A−1) (A−2) [wherein R 1 is H or the like; and A is a substituted vinyl group represented by the general formula (A−1) (wherein X is O, CHR 3 or NR 4 ; Y is O or S; R 2 is ZR 5 or NR 6 R 7 ; n is an integer of 0 to 3; Z is O or S; R 3 is H or the like; R 4 is H or the like; and R 5 to R 7 are each independently H or the like, and R 6 and R 7 may be the same or different from each other, or R 6 and R 7 together with the nitrogen atom to which they are bonded may form a heterocyclic group), or a substituted vinyl group represented by the general formula (A−2) (wherein R 8 to R 10 are each independently H or the like; and R 2 and n are each as defined above)]. The thiazolotriazole derivatives exhibit excellent herbicidal activity against weeds obstructing the raising of crops without doing chemical damage to crops including rice plants, when applied even in a lowered dosage.
    • 由通式(‖)表示的噻唑并三唑衍生物或其盐; 含有衍生物或盐的除草剂作为活性成分; 和衍生物的制备中间体:(‖)(A-1)(A-2)[其中R 1是H等; A为由通式(A-1)表示的取代乙烯基(其中X为O,CHR 3或NR 4); Y为O或S; R 2 是ZR 或NR 6,其中n是0至3的整数; Z是O 或S; R 3是H等; R 4是H等等; R 5和R 7之间, / sp>各自独立地为H等,并且R 6和R 7彼此可以相同或不同,或者R 6 = sp 和R 7与它们所键合的氮原子一起形成杂环基)或由通式(A-2)表示的取代的乙烯基(其中R 8为 对于R 10 各自独立地为H等;并且R sp 2和n各自如上所定义)。 当施用甚至降低剂量时,噻唑三唑衍生物显示出优异的除草作用,阻碍了作物的升高而不会对包括稻植物在内的作物造成化学损害。