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1. 发明申请

WO2010070030A3 CATALYST AND PROCESS FOR SELECTIVE HYDROGENATION OF ALKYNES AND DIENES. 审中-公开
标题翻译：催化剂和碱选择性氢化方法。
公开(公告)号：WO2010070030A3
公开(公告)日：2010-09-23
申请号：PCT/EP2009067373
申请日：2009-12-17
申请人： TOTAL PETROCHEMICALS RES FELUY , VULPESCU GEORGE , GENIN FRANCINE , HORTMANN KAI , DATH JEAN-PIERRE
发明人： VULPESCU GEORGE , GENIN FRANCINE , HORTMANN KAI , DATH JEAN-PIERRE
IPC分类号： B01J23/44 , B01J23/66 , B01J27/224 , B01J37/02
CPC分类号： B01J37/0201 , B01J23/44 , B01J23/66 , B01J27/224
摘要： Selective hydrogenation process comprising: ° contacting in the presence of hydrogen an hydrocarbon feedstock comprising at least one unsaturated compound selected from the group consisting of al kynes and dienes and mixtures thereof with a first hydrogenation catalyst in a first reaction zone to produce a first product stream having a reduced proportion of alkynes and/or dienes; and ° contacting the first product stream in a second reaction zone having an inlet and an outlet, in the presence of optional additional hydrogen, with a second hydrogenation catalyst to produce a second product stream, wherein, the first hydrogenation catalyst comprises: ° a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and optionally a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, and said first constituent and optional second constituent are on a carrier made essentially of SiC or of an alkaline earth metal silicate. Hydrogenation catalyst comprising : ° a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11 -14 of the Periodic Table of Elements, and ° said first constituent and second constituent are on a carrier made essentially of an alkaline earth metal silicate or of SiC, ° the second constituent is optional if the carrier is made essentially of SiC.
摘要翻译：选择性氢化方法，包括：在氢的存在下，在第一反应区中，将包含至少一种选自由炔烃和二烯的不饱和化合物和其混合物与第一氢化催化剂组成的烃原料接触，以产生第一产物流炔和/或二烯的比例降低; 并且在具有入口和出口的第二反应区中，在任选的附加氢存在下，使第一产物流与第二氢化催化剂接触以产生第二产物流，其中第一氢化催化剂包括：至少一种金属或金属基组分的组分，其选自由元素周期表第1-10族（新的IUPAC符号）组成的元素和任选的至少一种金属或金属基成分的第二组分，所述金属或金属基组分选自由元素周期表第11-14部分组成的元素，以及所述第一组分和任选的第二组分在基本上由SiC或碱土金属硅酸盐制成的载体上。氢化催化剂，其包含：选自由元素周期表第1-10族（新的IUPAC符号）组成的元素中的至少一种金属或金属基成分的第一组分和至少一种金属或金属的第二组分基元素选自由元素周期表第11-14族组成的元素，且所述第一组分和第二组分位于基本上由碱土金属硅酸盐或SiC制成的载体上，第二组分是任选的如果载体基本上由SiC制成。

2. 发明申请

WO2010070030A2 CATALYST AND PROCESS FOR SELECTIVE HYDROGENATION OF ALKYNES AND DIENES. 审中-公开
标题翻译：烷烃和二烯烃选择加氢的催化剂和方法。
公开(公告)号：WO2010070030A2
公开(公告)日：2010-06-24
申请号：PCT/EP2009/067373
申请日：2009-12-17
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VULPESCU, George , GENIN, Francine , HORTMANN, Kai , DATH, Jean-Pierre
发明人： VULPESCU, George , GENIN, Francine , HORTMANN, Kai , DATH, Jean-Pierre
IPC分类号： B01J23/44 , B01J23/66 , B01J27/224 , B01J37/02
CPC分类号： B01J37/0201 , B01J23/44 , B01J23/66 , B01J27/224
摘要： Selective hydrogenation process comprising: • contacting in the presence of hydrogen an hydrocarbon feedstock comprising at least one unsaturated compound selected from the group consisting of al kynes and dienes and mixtures thereof with a first hydrogenation catalyst in a first reaction zone to produce a first product stream having a reduced proportion of alkynes and/or dienes; and • contacting the first product stream in a second reaction zone having an inlet and an outlet, in the presence of optional additional hydrogen, with a second hydrogenation catalyst to produce a second product stream, wherein, the first hydrogenation catalyst comprises: • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and optionally a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, and said first constituent and optional second constituent are on a carrier made essentially of SiC or of an alkaline earth metal silicate. Hydrogenation catalyst comprising : • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11 -14 of the Periodic Table of Elements, and • said first constituent and second constituent are on a carrier made essentially of an alkaline earth metal silicate or of SiC, • the second constituent is optional if the carrier is made essentially of SiC.
摘要翻译：选择性氢化方法包括：·在氢气存在下，使包含至少一种选自烷烃和二烯烃的不饱和化合物和它们的混合物的烃原料与第一氢化催化剂在第一氢化催化剂反应区以产生具有减少的炔烃和/或二烯烃比例的第一产物流; 和·使第一产物流在具有入口和出口的第二反应区中在存在任选的额外氢气的情况下与第二氢化催化剂接触以产生第二产物流，其中第一氢化催化剂包含：·第一至少一种选自元素周期表第1-10族的元素（新的IUPAC符号）的金属或基于金属的组分的组分和任选的第二组分选自至少一种金属或金属基组分，所述金属或金属基组分选自由元素周期表第11-14族组成的元素，并且所述第一组分和任选的第二组分在基本上由SiC或碱土金属硅酸盐制成的载体上。氢化催化剂包括：·选自元素周期表第1-10族（新的IUPAC符号）的至少一种金属或金属基成分的第一成分和至少一种金属或金属 - 基元素，其选自元素周期表第11-14族的元素，以及·所述第一成分和第二成分在基本上由碱土金属硅酸盐或SiC制成的载体上，·第二成分是可选的如果载体基本由SiC制成。

3. 发明申请

WO2010072789A1 METHOD TO PURIFY OLEFIN-CONTAINING HYDROCARBON FEEDSTOCKS 审中-公开
标题翻译：含有含烯烃的碳氢化合物的方法
公开(公告)号：WO2010072789A1
公开(公告)日：2010-07-01
申请号：PCT/EP2009/067803
申请日：2009-12-22
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , GAUTHIER, William j. , MISERQUE, Olivier , VULPESCU, George , GENIN, Francine , HORTMANN, Kai , DATH, Jean-Pierre
发明人： GAUTHIER, William j. , MISERQUE, Olivier , VULPESCU, George , GENIN, Francine , HORTMANN, Kai , DATH, Jean-Pierre
IPC分类号： C07C7/163 , C07C7/167 , C07C11/02 , C07C11/06 , B01J23/755
CPC分类号： B01J23/755 , B01J35/0026 , B01J35/1014 , B01J35/1019 , C07C7/167 , C07C2523/755 , Y02P20/52 , C07C11/02 , C07C11/06
摘要： A process for purifying an olefin-containing hydrocarbon feedstock comprising the steps of: (a)passing the said hydrocarbon feedstock in the presence of hydrogen over a first catalyst bed material comprising nickel deposited on a support material wherein said nickel is present as both nickel oxide and metallic nickel (b)recovering the feedstock having a substantially reduced acetylenics (in particular methylacetylene) and allenes (in particular propadiene) content.
摘要翻译：一种用于纯化含烯烃的原料的方法，包括以下步骤：（a）在氢气存在下使所述烃原料通过沉积在载体材料上的包含镍的第一催化剂床材料，其中所述镍作为氧化镍存在和金属镍（b）回收具有显着降低的炔属（特别是甲基乙炔）和丙烯（特别是丙二烯）含量的原料。

4. 发明申请

WO2010070031A1 CATALYST AND PROCESS FOR HYDROGENATION OF HYDROCARBON FEEDSTOCKS 审中-公开
标题翻译：催化剂和氢化烃进料方法
公开(公告)号：WO2010070031A1
公开(公告)日：2010-06-24
申请号：PCT/EP2009/067376
申请日：2009-12-17
申请人： TOTAL PETROCHEMICALS RESEARCH FELUY , VULPESCU, George , GENIN, Francine , HORTMANN, Kai , DATH, Jean-Pierre
发明人： VULPESCU, George , GENIN, Francine , HORTMANN, Kai , DATH, Jean-Pierre
IPC分类号： B01J23/44 , B01J23/66 , B01J27/224 , B01J37/02
CPC分类号： B01J23/66 , B01J23/44 , B01J27/224 , B01J37/0201
摘要： Hydrogenation process comprising: contacting in the presence of hydrogen an hydrocarbon feedstock comprising at least one unsaturated compound selected from the group consisting of alkynes and dienes and mixtures thereof with an hydrogenation catalyst in a reaction zone to produce a product stream having a reduced proportion of alkynes and/or dienes, wherein, the hydrogenation catalyst comprises : • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, • said first constituent and second constituent are on a carrier made essentially of SiC or of an alkaline earth metal silicate and • the second constituent is optional if the carrier is made essentially of SiC. Hydrogenation catalyst comprising : • a first constituent of at least one metal or metal-based component selected from the elements consisting of Groups 1-10 of the Periodic Table of Elements (new IUPAC notation) and a second constituent of at least one metal or metal-based component selected from the elements consisting of Groups 11-14 of the Periodic Table of Elements, and • said first constituent and second constituent are on a carrier made essentially of an alkaline earth metal silicate or of SiC, • the second constituent is optional if the carrier is made essentially of SiC.
摘要翻译：氢化方法包括：在氢气存在下，将包含至少一种选自炔烃和二烯的不饱和化合物的烃原料及其与加氢催化剂的混合物在反应区中接触以产生具有减少的炔烃比例的产物流和/或二烯，其中所述氢化催化剂包含：至少一种金属或金属基组分的第一组分，所述金属或金属基组分选自元素周期表第1-10组（新的IUPAC符号）和第二组分至少一种选自元素周期表第11-14族元素的金属或金属基成分的组分，所述第一组分和第二组分位于基本上由SiC或碱土金属硅酸盐制成的载体上如果载体基本上由SiC制成，则第二组分是可选的。氢化催化剂，其包含：选自由元素周期表第1-10族（新的IUPAC符号）组成的元素中的至少一种金属或金属基成分的第一组分和至少一种金属或金属的第二组分基元素选自由元素周期表第11-14族组成的元素，且所述第一组分和第二组分位于基本上由碱土金属硅酸盐或SiC制成的载体上，第二组分是任选的如果载体基本上由SiC制成。

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