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    • 1. 发明申请
    • STERICALLY STABILIZED NON-AQUEOUS DISPERSION AND COATING MATERIAL MADE FROM IT
    • 空间上稳定的非水分散性好,种衣剂在此基础上
    • WO1997031952A1
    • 1997-09-04
    • PCT/EP1997000833
    • 1997-02-21
    • BASF LACKE UND FARBEN AKTIENGESELLSCHAFTVOGDANIS, LazarosSCHMITZ, Arno
    • BASF LACKE UND FARBEN AKTIENGESELLSCHAFT
    • C08D163/00
    • C09D163/00C08G59/066C08L2666/28C08L61/04
    • The invention concerns a coating material containing: a) a sterically stabilized non-aqueous dispersion produced by reacting, in an organic solvent in the presence of a dispersion stabilizer, at least one epoxy resin (A) containing an average of at least two epoxy groups per molecule with at least one diol (B) of the formula HOROH (I), in which R is a group of the formula -Ph-D-Ph- (II) in which Ph- is a phenylene group and D a methylene or propylene group, and optionally with a further reagent (C) containing groups which react with epoxy or hydroxy groups, and b) at least one cross-linking agent and, optionally, solvents, pigments, fillers and other auxiliaries and additives, the diol (I) being in the form of a non-aqueous dispersion which is sterically stabilized by a stabilizer containing isoprene or a compound derived from polyisoprene.
    • 本发明涉及包含具有每分子平均至少2个环氧基团与至少一种二醇的分散体稳定剂的存在下)位稳定,非水性)分散体,其可通过混合至少一种环氧树脂(A来制备(在有机溶剂中的涂料组合物 B)是式HOROH(I),其中R是下式基团-Ph-D-PH(II)其中Ph是亚苯基,D为亚甲基或亚丙基,并任选地进一步用的的 与环氧或羟基反应性基团具有(C)成分,进行反应,和b)至少一种交联剂,和任选的溶剂,颜料,填料和常规助剂和添加剂,其中,在非形式的化合物(I) 水性分散体存在时,其空间位由含有稳定剂异戊二烯或聚异戊二烯从组分衍生的基团稳定化。
    • 2. 发明申请
    • COATING AGENTS BASED ON A STERICALLY STABLIZED, NON-AQUEOUS DISPERSION, PROCESS FOR THEIR PREPARATION AND THEIR USE FOR COATING PACKAGING
    • 基于空间位涂层剂稳定的非水性分散体,方法用于涂覆EMBALLAGEN生产和使用
    • WO1996016133A1
    • 1996-05-30
    • PCT/EP1995004127
    • 1995-10-21
    • BASF LACKE + FARBEN AGVOGDANIS, LazarosSCHMITZ, Arno
    • BASF LACKE + FARBEN AG
    • C09D163/00
    • C09D163/00C08G59/066C08G59/621C08L61/04
    • The invention concerns coating agents based on a sterically stabilized, non-aqueous dispersion which can be prepared by reacting, in an organic solvent in the presence of a dispersion stabilizer, at least one epoxy resin (A) having on average at least 2 epoxy groups per molecule, with at least one diol (B) of the formula HOROH (I), in which R is a group of the formula -Ph-D-Ph- (II), wherein -Ph- is a phenylene group and D is a methylene or propylene group, and optionally with a further component (C), which comprises groups which are reactive to epoxy or hydroxyl groups. The invention is characterized in that: i) the non-aqueous dispersion is prepared in that: 1) in a first step the epoxy resin component (A) is reacted with at least one diol (B) and optionally the component (C) to form a reaction product which contains as end groups phenolic hydroxyl groups and has a phenoxy equivalent weight of at least 246; and 2) subsequently, in step (2), 50 to 100 % of the phenolic hydroxyl groups present in the reaction product obtained in step (1) are reacted with another epoxy resin component (A) and/or component (C); and ii) the coating agent contains at least one phenolic resin.
    • 本发明涉及一种基于在其上,从而产生了空间稳定的非水分散体的涂料组合物是,在分散稳定剂,至少一种环氧树脂(A)的存在下,在有机溶剂(至少在每分子的装置(2)的环氧基团与至少一种二醇乙 )通式HOROH(I),其中R是下式基团-Ph-D-PH(II)其中-PH-为亚苯基,D为亚甲基或亚丙基,并任选地进一步用的的 与环氧或羟基反应性基团具有(C)成分,进行反应,其特征在于:i)所述非水分散体已经制备1)的环氧树脂组分(a)与至少一种二醇的第一阶段 (B)和任选的组分(C),以含羟基的酚端基为具有至少246 Phenoxyequivalentgewicht的反应产物,实施的瓦特 被奥登和2)然后(在步骤2)中获得的反应产物的50至100%(在步骤1)中包含进一步的环氧树脂成分(A)和/或组分(C酚羟基基团)已经反应,以及ii)所述 涂层剂至少含有酚醛树脂。
    • 3. 发明申请
    • COATING AGENT, PROCESS FOR PRODUCING THE SAME AND ITS USE, IN PARTICULAR FOR LACQUERING THE OUTSIDE OF PACKAGES
    • 包衣剂生产和涂料的通过方法,尤其是在户外绘画EMBALLAGEN
    • WO1998012272A1
    • 1998-03-26
    • PCT/EP1997004623
    • 1997-08-25
    • PPG INDUSTRIES, INC.KÖSTER, BernhardKEWELOH, LudgerKIPP, JörgVOGDANIS, LazarosCHMIELEWSKI, Dietmar
    • PPG INDUSTRIES, INC.
    • C09D167/00
    • C09D167/00Y10T428/31529C08L2666/14
    • A coating agent which contains one or several hydroxyl group-containing, optionally modified polyesters and one or several cross-linking agents which react with the hydroxyl groups is characterised in that the coating agent contains as binder a mixture of A1) 35 to 95 wt % one or several hydroxyl groups-containing polyesters (A1) with an OH number from 15 to 210 mgKOH/g, an acid number from 10 to 120 mgKOH/g and a number average molecular weight from 500 to 6000 g/mol; A2) 2 to 50 wt % one or several water-dilutable, modified epoxy resin esters (A2); and A3) 0 to 20 wt % one or several water-dilutable, hydroxyl groups-containing, epoxy resin-modified alkyd resins (A3). The sum of the weight percentages of components (A1) to (A3) equals 100 wt % and the weight percentages are given in relation to the solids in the binders (A1) to (A3).
    • 本发明是一种涂布剂,含有一种或多种改性或未改性的聚酯和一种或朝向羟基的交联剂反应性更强的含羟基的,其特征在于,所述涂层剂作为粘合剂A1的混合物)35%至95%(重量)的一种或多种的 含羟基的聚酯具有15-210毫克KOH /克,10至120毫克KOH /克和500至6000g / mol的数均分子量的酸值的OH值(A1); 包含A2)2〜50重量%的一种或多种水,改性环氧树脂酯(A2)和A3)0至20重量%的一种或多种水可稀释的,含羟基的,epoxidharzmodifizierter醇酸树脂(A3),其中所述比例(重量)的总和 组分(A1)至(A3)是在每种情况下100%(重量),并且其中在所述粘合剂(A1)至(A3)的固体含量每种情况下,重量百分比。
    • 4. 发明申请
    • METHOD OF PRODUCING A STERICALLY STABILIZED NON-AQUEOUS DISPERSION OF A POLYEPOXIDE, AND COATING MATERIALS CONTAINING SUCH A DISPERSION
    • 一种用于生产多环氧化物的立体化学稳定的非水性分散体和本分散液中种衣剂
    • WO1996001292A1
    • 1996-01-18
    • PCT/EP1995002531
    • 1995-06-29
    • BASF LACKE + FARBEN AGVOGDANIS, LazarosCIBURA, KlausBREMSER, Wolfgang
    • BASF LACKE + FARBEN AG
    • C08L63/00
    • C08G59/066C09D163/00
    • The invention concerns a method of producing a sterically stabilized non-aqueous dispersion of a polyepoxide, the method calling for at least one epoxy resin (A) with at least two epoxy groups to be reacted, in an organic solvent in the presence of a dispersion stabilizer, with at least one diol (B) of the formula (I) HOROH, in which R is a group of the formula (II) in which D is a methylene or propylene group, and optionally with an additional component (C) having groups which are reactive towards epoxy or hydroxyl groups. The method is characterized in that 1) in a first stage, part of the epoxy resin (A) is reacted with an excess, relative to the amount of epoxy resin used in this stage (1), of the diol (B) of formula (I) and, optionally, of the additional component (C) and 2) the reaction product obtained in stage 1 is subsequently reacted with the remainder of the epoxy resin (A) and/or of the additional component (C) to give the required end product.
    • 本发明是一种制备聚环氧化物的立构稳定化的非水分散体,一种方法,其中在具有化学式中的至少一种二元醇(B)至少两个环氧基的分散稳定剂,至少一种环氧树脂(A)的存在下,在有机溶剂(I) HOROH,其中R是一个式的基团(II),其中D是具有与环氧或羟基反应性基团具有另外的组分(C)的亚甲基或亚丙基,和任选地被转换,其特征在于 即:1)在第一阶段与过量的式(I的二醇(B)的环氧树脂组分(a)的一部分)和任选的组分(C)的基础上,(在该阶段1)的量使用环氧树脂 进行反应,并获得了2),那么它(步骤1)与剩余的环氧树脂成分(A)和/或组分(C反应产物),以所希望的最终产物 实现。