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1. 发明申请

WO2010069758A1 POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：可聚合光敏剂和辐射可固化组合物
公开(公告)号：WO2010069758A1
公开(公告)日：2010-06-24
申请号：PCT/EP2009/066155
申请日：2009-12-01
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , VAN MAELE, Luc , VAN LUPPEN, Jaymes , CLAES, Roland
发明人： LOCCUFIER, Johan , VAN MAELE, Luc , VAN LUPPEN, Jaymes , CLAES, Roland
IPC分类号： C07C69/54 , C07C69/716 , C07C69/78 , C07C233/20 , C07D209/86 , C07D335/16 , C07D295/108 , G03F7/027
CPC分类号： C07D335/16 , C07C69/54 , C07C233/20 , C07C235/08 , C07C323/12 , C07C2601/14 , C07C2602/42 , C07D209/86 , C07D295/108 , G03F7/027 , G03F7/031
摘要： A polymerizable photoinitiator represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w = 1 to (p-z) and z = O to (p-w); L represents an optionally substituted (p÷y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation. Radiation curable compositions including the polymerizable photoinitiator and methods of preparing the polymerizable photoinitiator are also disclosed.
摘要翻译：由式（I）表示的可聚合光引发剂：其中R 1，R 2和R 3独立地选自氢，任选取代的烷基和任选取代的芳基，或者R 1和R 3表示必要的原子以形成五至八元环; p，w，y和z都是整数，y代表值1到6; p表示w和z的和; p表示1到6的值; w = 1〜（p-z），z = 0〜（p-w）; L表示包含1至14个碳原子的任选取代的（p÷y）价连接基团; A表示选自丙烯酸酯基，甲基丙烯酸酯基，苯乙烯基，丙烯酰胺基，甲基丙烯酰胺基，马来酸酯基，富马酸酯基，衣康酸酯基，乙烯基醚基中的自由基聚合性基团烯丙基醚基，烯丙基酯基和乙烯基酯基; 并且X表示光引发部分，其包含至少一个能够在暴露于光化辐射时引发自由基聚合反应的基团。还公开了包含可聚合光引发剂的可辐射固化组合物和制备可聚合光引发剂的方法。

2. 发明申请

WO2009147057A1 POLYMERIZABLE TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS 审中-公开
标题翻译：可聚合型II型光敏剂和可固化组合物
公开(公告)号：WO2009147057A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/056531
申请日：2009-05-28
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , VAN LUPPEN, Jaymes
IPC分类号： C07C219/08 , C07C219/14 , C07D295/18 , C07D311/86 , C09D11/00
CPC分类号： C07D335/16 , C07C217/22 , C07C219/08 , C07C219/14 , C09D11/101 , C09D11/322
摘要： A polymerizable Type Il photoinitiator according to Formula (I): wherein: A represents a Norrish Type Il initiating group; L represents a divalent linking group positioning the Norrish Type Il initiating group A and the CR2R3-group in a 1-5 to a 1-8 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 8 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks including the polymerizable Type Il photoinitiator are also disclosed.
摘要翻译：根据式（I）的可聚合II型光引发剂：其中：A表示Norrish II型起始基团; L表示在1-5至1-8位置定位Norrish II型起始基团A和CR 2 R 3基团的二价连接基团，其中位置1定义为A的芳族或脂环族环中的第一个原子，其中L 共价键合，位置5至8定义为L共价结合的CR 2 R 3 - 基团的碳原子，条件是L不含有胺。还公开了包含可聚合II型光引发剂的可辐射固化组合物和油墨。

3. 发明申请

WO2010029016A1 RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：辐射可固化组合物
公开(公告)号：WO2010029016A1
公开(公告)日：2010-03-18
申请号：PCT/EP2009/061442
申请日：2009-09-04
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , CLAES, Roland , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , CLAES, Roland , VAN LUPPEN, Jaymes
IPC分类号： C08F2/50 , C08F4/00
CPC分类号： C08F2/50 , C08F4/00
摘要： A polymerizable Norrish Type Il photoinitiator according to Formula (I) wherein groups A, L, R 1 and R 2 are as specified in claim 1 and radiation curable compositions and inkjet inks containing it are disclosed exhibiting improved compatibility with and solubility in radiation curable compositions and injet inks, and exhibiting low extractable amounts of the photoinitiator and its residues after curing.
摘要翻译：根据式（I）的可聚合Norrish II型光引发剂，其中基团A，L，R 1和R 2如权利要求1中所定义，并且公开了可辐射固化组合物和含有它的喷墨油墨，其显示出与辐射固化组合物和喷墨油墨的改善的相容性和溶解性，并且在固化后显示低可提取量的光引发剂及其残留物。

4. 发明申请

WO2009147054A1 MULTIFUNCTIONAL TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS 审中-公开
标题翻译：多功能型II型光敏元件和可固化组合物
公开(公告)号：WO2009147054A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/056517
申请日：2009-05-28
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , VAN LUPPEN, Jaymes
IPC分类号： C07C229/16 , C07D311/86 , C07D295/185 , C09D11/00
CPC分类号： C07D295/185 , C07C217/22 , C07C219/14 , C07C229/12 , C07D311/86 , C09D11/101
摘要： A multifunctional Type Il photoinitiator according to Formula (I): wherein X represents a structural moiety according to Formula (II) : wherein: A represents a Norrish Type Il initiating group; and L represents a divalent linking group positioning the Norrish Type Il initiating group A and the CR2R3-group in a 1-5 to a 1-9 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 9 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks including the multifunctional Type Il photoinitiator are also disclosed.
摘要翻译：根据式（I）的多官能II型光引发剂：其中X表示根据式（II）的结构部分：其中：A表示Norrish II型引发基团; L表示在1-5至1-9位置定位Norrish II型起始基团A和CR 2 R 3基团的二价连接基团，其中位置1定义为A的芳族或脂环族环中的第一个原子， L共价键合，位置5至9定义为L共价结合的CR 2 R 3 - 基团的碳原子，条件是L不含胺。还公开了包括多功能II型光引发剂的可辐射固化组合物和油墨。

5. 发明申请

WO2010029017A1 POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：可聚合光敏剂和辐射可固化组合物
公开(公告)号：WO2010029017A1
公开(公告)日：2010-03-18
申请号：PCT/EP2009/061444
申请日：2009-09-04
申请人： AGFA GRAPHICS NV , LOCCUFIER, Johan , CLAES, Roland , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , CLAES, Roland , VAN LUPPEN, Jaymes
IPC分类号： C07D335/10 , C07C49/84 , C08F220/26
CPC分类号： C07D335/10 , C07C69/76 , C08F220/26 , C08F220/30 , C08F220/34 , C08F220/38 , C08F226/00 , C08F228/02
摘要： A new type of polymerizable Norrish Type II photoinitiators having an optionally substituted benzophenone group or an optionally substituted thioxanthone group is disclosed exhibiting improved compatibility with and solubility in radiation curable compositions. Radiation curable compositions and inkjet inks containing these polymerizable Norrish Type Il photoinitiators, exhibiting low extractable amounts of the photoinitiators and their residues after curing, are also disclosed.
摘要翻译：公开了具有任选取代的二苯甲酮基团或任选取代的噻吨酮基团的新型可聚合Norrish II型光引发剂，其显示出与可辐射固化组合物的相容性和溶解度的改善。还公开了含有这些可聚合Norrish II型光引发剂的可辐射固化组合物和喷墨油墨，其表现出低可提取量的光引发剂及其固化后的残留物。

6. 发明申请

WO2008074758A1 NOVEL RADIATION CURABLE COMPOSITIONS 审中-公开
标题翻译：新型可辐射固化组合物
公开(公告)号：WO2008074758A1
公开(公告)日：2008-06-26
申请号：PCT/EP2007/064024
申请日：2007-12-17
申请人： Agfa Graphics NV , LOCCUFIER, Johan , CLAES, Roland , VAN LUPPEN, Jaymes
发明人： LOCCUFIER, Johan , CLAES, Roland , VAN LUPPEN, Jaymes
IPC分类号： C08F2/00
CPC分类号： C08F2/50
摘要： A radiation curable composition comprising a curable compound, a photo-initiator and a co-initiator characterized in that said co-initiator is represented by Formula (I), wherein MA is the residue of a mono- or oligofunctional Michael acceptor; L is a divalent linking group positioning the two tertiary amines in a 1-3 to 1-10 position, with the proviso that both amines are aliphatic; R1, R2 and R3 independently represent an optionally substituted alkyl group, an optionally substituted alkenyl group, an optionally substituted alkynyl group or an optionally substituted (hetero) alkaryl group; any two of R1, R2 and R3 may represent the necessary atoms to form a ring; any two of R1, R2 and R3 may represent the necessary atoms to form a ring with any of the atoms of the linking group L; n is an integer ranging from 1 to 6.
摘要翻译：一种包含可固化化合物，光引发剂和共引发剂的可辐射固化组合物，其特征在于所述共引发剂由式（I）表示，其中MA是单官能或低官能迈克尔受体的残基; L是二价连接基团，将两个叔胺定位在1-3至1-10个位置，条件是两个胺都是脂族的; R1，R2和R3独立地表示任选取代的烷基，任选取代的烯基，任选取代的炔基或任选取代的（杂）烷芳基; R1，R2和R3中的任何两个可以表示形成环的必要原子; R1，R2和R3中的任何两个可以表示与连接基团L的任何原子形成环的必要原子; n为1〜6的整数。

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