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    • 8. 发明申请
    • POLYMER AND USE THEREOF IN THE PRODUCTION OF PAPER AND BOARD
    • 聚合物及其在纸和纸板生产中的应用
    • WO02095128A9
    • 2003-01-23
    • PCT/FI0200428
    • 2002-05-20
    • RAISIO CHEM LTDTAMMI ANNA-LIISANURMI KARI
    • TAMMI ANNA-LIISANURMI KARI
    • D21H17/29D21H17/24D21H17/37D21H21/20
    • D21H17/29
    • As additive for the production of paper and board to improve the strength of a wet web a copolymer stabilized with a cationic polysaccharide is proposed in which copolymer an acrylamide of metacrylamide, vinylic craboxyl acid and optionally other vinylic monomers are used as monomers. The west strength of a web means the strength of a paper or board web during production at a dry solids content of 20-60%. The additive according to the invention improves, in addition to the wet strength of the web, also the surface resistance of the product. Compared to the additives of the prior art, a small relative ratio of the number of the side chains to the cationic groups is used, because a polysaccharide having a higher cationic character provides better stability.
    • 作为用于生产纸和纸板的添加剂,为了提高湿纸幅的强度,提出了用阳离子多糖稳定的共聚物,其中使用甲基丙烯酰胺,乙烯基异氰酸酯和任选的其它乙烯基单体的丙烯酰胺作为单体的共聚物。 网的西部强度意味着在干固体含量为20-60%的生产期间纸或纸板的强度。 根据本发明的添加剂除了纤维网的湿强度之外,还提高了产品的表面电阻。 与现有技术的添加剂相比,使用侧链数与阳离子基团的相对比例小,因为具有较高阳离子性质的多糖具有更好的稳定性。
    • 9. 发明申请
    • PROCESS FOR THE PREPARATION OF 3-SUBSTITUTED THIOPHENES
    • 制备三取代噻吩的方法
    • WO1993012106A1
    • 1993-06-24
    • PCT/FI1992000333
    • 1992-12-08
    • NESTE OYJÄRVINEN, HanneleLAHTINEN, LeilaHORMI, OsmoNÄSMAN, JanTAMMI, Anna-Liisa
    • NESTE OY
    • C07D333/08
    • C07D333/08
    • The invention relates to a process for the preparation of 3-substituted thiophenes in which the substituent is a C4-C18-alkyl group. According to the invention, the preparation is carried out by allowing an alkali metal salt of a C4-C18-alkyl-succinic acid to react with a compound of sulfur and phosphorus, e.g. tetraphosphorus decasulfide, in an organic solvent at a temperature of 100-180 DEG C, the product obtained being 3-(C4-C18-alkyl)thiophene. The said reaction may be the last step in a process in which the initial material is maleic acid anhydride with which alpha -C4-C18-alkene is combined so that C4-C18-alkenylsuccinic acid anhydride is obtained, whereafter this is hydrogenated catalytically to produce C4-C18-alkylsuccinic acid anhydride. This is thereafter reacted with an alkali metal hydroxide so that an alkali salt of the C4-C18-alkylsuccinic acid is obtained, which salt is reacted with a compound of sulfur and phosphorus to produce 3-(C4-C18-alkyl)thiophene, which constitutes the final product.
    • 本发明涉及一种制备其中取代基为C 4 -C 18 - 烷基的3-取代噻吩的方法。 根据本发明,通过使C4-C18-烷基 - 琥珀酸的碱金属盐与硫和磷的化合物反应来进行制备。 十四烷基四硫化物,在有机溶剂中,温度为100-180℃,所得产物为3-(C 4 -C 18 - 烷基)噻吩。 所述反应可以是其中初始材料是马来酸酐与其中α-C 4 -C 18 - 烯烃组合使得得到C 4 -C 18 - 烯基琥珀酸酐的方法中的最后一个步骤,然后将其氢化催化以产生 C4-C18-烷基琥珀酸酐。 然后与碱金属氢氧化物反应,得到C4-C18-烷基琥珀酸的碱金属盐,该盐与硫和磷的化合物反应生成3-(C 4 -C 18烷基)噻吩,其中 构成最终产品。