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    • 1. 发明申请
    • METHOD FOR PRODUCING LEATHER
    • 生产皮革的方法
    • WO2004037589A3
    • 2004-06-24
    • PCT/EP0311368
    • 2003-10-14
    • BASF AGTAEGER TILMAN LUEDECKEPABST GUNTHERLAMALLE PHILIPPEHUEFFER STEPHANSCHROEDER STEFAN
    • TAEGER TILMAN LUEDECKEPABST GUNTHERLAMALLE PHILIPPEHUEFFER STEPHANSCHROEDER STEFAN
    • C14C1/06C14C3/16C14C1/08
    • C14C1/065
    • The invention relates to a method for producing leather, comprising at least two of the following method steps A) to D): A) using one or more polyelectrolytes during the production of semifinished or intermediate products, involving the addition of one or more polyelectrolytes in at least one of steps (a) to (d): (a) together with 0 to 1.5 % by weight of lime, with regard to the weight of salt, immediately before or in the lime pit; (b) before or during deliming; (c) before or during bating; (d) together with, in total, 0 to 3 % by weight of alkaline salt or alkaline earth salt, with regard to the pelt weight, immediately before or in the pickle solution; B) in the lime pit, treating the skins in an aqueous liquor with one or more compounds of general formula (B.1) or with their corresponding alkali metal salts, alkaline earth metal salts, ammonium salts or phosphonium salts, whereby variables R and X to X have the meanings as cited in the description, with the provision that at least two mercapto groups are contained in the compound or compounds B.1; C) using degreasing agents of general formula (C.1) for degreasing pelts, skins or other intermediate stages and semifinished products during the production of leather, whereby variables n and R to R have the meanings as cited in the description; D) tanning by using a tanning agent that can be produced by reacting at least one aldehyde of general formula (D.1) with at least one other identical or different aldehyde of formula (D.1) in the presence of an acid catalyst and, optionally, in the presence of at least one additional carbonyl compound of formula (D.2), whereby variables Z and R to R have the meanings as cited in the description, with the provision that, in the event Z corresponds to a chemical single bond or to a radical without alpha -hydrogen atoms, at least one additional aldehyde of formula (D.1), in which radical Z contains alpha -hydrogen atoms, or at least one additional carbonyl compound of formula (D.2) is present. The invention also relates to leather that is produced according to the inventive method.
    • 本发明涉及一种用于生产皮革的方法,包括至少两个以下步骤a)至d)组成:a)在生产的半成品或中间产品,该方法包括在至少一种中加入一种或多种聚电解质使用一种或多种聚电解质的 步骤(a)至(d):(一)连同0〜1.5重量%的石灰,基于该盐腌重量,立即之前或期间石灰,(b)之前或期间,脱灰,(c)中 之前或期间酸洗,(d)用合计为0〜3重量%的碱金属或碱土金属的盐,基于所述毛皮重量一起,之前立即或过程中酸洗; B)治疗在含水液体中的石灰含有通式(B.1)或它们的相应的碱金属,碱土金属,铵或鏻盐,其中变量R <10>和X <1>到的一种或多种化合物的皮 X 4具有在说明书中给出的含义,条件是在一种或多种化合物B.1中存在至少两个巯基; C)Entfettungsmittteln的使用通式(C.1)至R <21>的含义引用在脱脂毛皮,皮革,或其它中间体和半成品在制作皮革的描述中,其中,所述变量n和R <16>; d)鞣制使用可以由通式(D.1)的至少一种醛的反应来制备鞣剂,与下式的至少一个另外的相同或不同的醛在酸催化剂的存在下和任选地在至少一个另外的D.1的存在 式(D.2)的羰基化合物中,变量Z和R <22>至R <25>在本说明书中已经给出的含义,条件是对于该情况下Z是具有没有alpha单一化学键或基团,条件 氢对应于式D.1,其中Z含有的α-氢原子,或式D.2的至少一个另外的羰基化合物的存在的至少一个另外的醛。 此外,本发明涉及根据本发明方法生产的皮革。
    • 2. 发明申请
    • METHOD FOR THE PRODUCTION OF BISEPOXIDES AND DITHIOLS
    • 工艺用于生产和双环氧化物二硫酚
    • WO2005033070A3
    • 2005-06-23
    • PCT/EP2004010123
    • 2004-09-10
    • BASF AGBUEHLER HOLGERTELES JOAQUIM HENRIQUEPABST GUNTHERTAEGER TILMAN LUEDECKE
    • BUEHLER HOLGERTELES JOAQUIM HENRIQUEPABST GUNTHERTAEGER TILMAN LUEDECKE
    • C07C321/04C07C323/12C07C323/19C07D301/12C07D303/12C07D303/34C07D407/04C14C1/06
    • C07D407/04C07C323/12
    • The invention relates to a method for the production of bisepoxides, characterised in that a conjugated diene of formula (I) is reacted with at least one peroxide with the application of up to 4 equivalents of peroxide per C-C double bond, where R is selected from hydrogen and C1-C12 alkyl, unsubstituted or substituted with one or several SH or OH groups, in the presence of a catalyst, obtained by the bringing into contact of at least one manganese compound, selected from A2MnX4, AMnX3, MnY, MnX2 and MnX3 with at least one ligand L, of general formula (II), whereby the variables have the following definitions: X may be the same or different and is selected from monovalent anions, Y is a divalent anion, A is selected from alkali metals and optionally alkylated ammonium, R may be different or preferably the same and selected from C1-C20 alkyl and at least one co-ligand, derived from monocarboxylic acids, di- or poly-carboxylic acids or diamines.
    • 一种用于双环氧化物的制备方法,其特征在于,其中R选自通式(I)的共轭二烯<1>选自氢和C 1 -C 12烷基,未取代或取代的选自具有一个或多个SH或OH基团, 在催化剂为通过使从A2MnX4,AMnX3,MNY,MnX2和MnX3选择与式(II)其中变量被定义为至少一个配位体L的至少一种锰化合物制得的存在如下:X相同或不同,并 从一价阴离子,Y是二价阴离子,选自碱金属和铵的选择,其可以是烷基化的,R <2>是不同的或优选相同并选自C1-C20烷基被选择,和至少一种共配体,其中一元羧酸,二 - 衍生自或多元羧酸或二胺,与至少一种过氧化物反应,同时每个碳 - 碳双键的当量一个多达4个当量的过氧化的 连接开始。