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    • 1. 发明申请
    • ELASTOMERIC POLYMER BLENDS AND PROCESSES FOR THEIR PRODUCTION
    • 弹性聚合物混合物及其生产方法
    • WO2011102946A1
    • 2011-08-25
    • PCT/US2011022754
    • 2011-01-27
    • EXXONMOBIL CHEMICAL PARENTS INCKOLB RAINERCHU JOHN WKISS GABORREYNOLDS ROBERT PSCHAUDER JEAN-ROCHSUN THOMAS T
    • KOLB RAINERCHU JOHN WKISS GABORREYNOLDS ROBERT PSCHAUDER JEAN-ROCHSUN THOMAS T
    • C08L23/14
    • C08L23/142C08L2205/02C08L2314/06C08L2666/06
    • Elastomeric polymer blends and processes for their production are described. Specifically, the polymer blends comprise a first polymer and a second polymer, where the first polymer comprises from 70 wt% to 90 wt% units derived from propylene and from 10 wt% to 30 wt% units derived from ethylene and/or a C4-C10 alpha-olefin, and the second polymer comprises from 88 wt% to 98 wt% units derived from propylene and from 2 wt% to 12 wt% units derived from ethylene and/or a C4-C 10 alpha-olefin. The elastomeric polymer blends are further characterized by having two or more of the following properties: an overall propylene content of between 75 wt% and 90 wt%, a melting point between 110°C and 145°C, a Vicat softening point greater than 45°C, a tensile stress at 300% strain of less than 500 psi (3447 kPa), as determined by a stress strain test according to ASTM D412, or an average maximum force for pellet separation of less than 10 N in an accelerated storage stability test. The polymer blends are produced in a dual reactor process, in which the first polymer and the second polymer are prepared using differing catalyst systems.
    • 描述了弹性聚合物共混物及其生产方法。 具体地说,聚合物共混物包括第一聚合物和第二聚合物,其中第一聚合物包含70重量%至90重量%的衍生自丙烯的单元和10重量%至30重量%的衍生自乙烯和/或C4- C10α-烯烃,第二聚合物包含衍生自丙烯的88重量%至98重量%的单元和来自乙烯和/或C 4 -C 10α-烯烃的2重量%至12重量%的单元。 弹性体聚合物共混物的进一步特征在于具有以下性质中的两种或更多种:总丙烯含量为75重量%至90重量%,熔点为110℃至145℃,维卡软化点大于45 ℃,通过根据ASTM D412的应力应变测试确定的小于500psi(3447kPa)的300%应变下的拉伸应力或在加速储存稳定性中颗粒分离的平均最大力小于10N 测试。 聚合物共混物在双重反应器方法中制备,其中使用不同的催化剂体系制备第一聚合物和第二聚合物。
    • 4. 发明申请
    • A HEAT-SEAL RESIN AND PACKAGE FORMED THEREFROM
    • 一种热密封树脂和其形成的包装
    • WO2012083104A1
    • 2012-06-21
    • PCT/US2011/065332
    • 2011-12-16
    • EXXONMOBIL RESEARCH AND ENGINEERING COMPANYLOHSE, David, J.SUN, Thomas, T.MEHTA, Aspy, K.KISS, GaborREYNOLDS, Robert, P.CHU, John, W.VARMA-NAIR, Manika
    • LOHSE, David, J.SUN, Thomas, T.MEHTA, Aspy, K.KISS, GaborREYNOLDS, Robert, P.CHU, John, W.VARMA-NAIR, Manika
    • C08L23/08C08L23/14C08L23/22
    • C08L23/142C08L2205/025
    • Provided is a heat-seal resin. The resin includes 5 wt% to 95 wt% of a first copolymer and 95 wt% to 5 wt% of a second copolymer based on the total weight of the resin. The first copolymer and the second copolymer together are 90 wt% or more of the total weight of the resin. The first copolymer includes a first monomer of an alphaolefin of 2 to 4 carbon atoms and a second monomer selected from a second monomer of an alphaolefin of 2 to 8 carbon atoms. The first monomer and the second monomer of the first copolymer are different. The first copolymer has an MFR of from 5 to 1000 g/ 10 minutes and a T fm of 66°C to 80°C. The second copolymer includes a first monomer of an alphaolefin of 2 to 4 carbon atoms and a second monomer selected from a second monomer of an alphaolefin of 2 to 8 carbon atoms. The first monomer and the second monomer of the second copolymer are different. The second copolymer has an MFR of from 0.5 to 5 g/ 10 minutes and a T fm of 45°C to 66°C, wherein the first copolymer has an MFR of at least 2 g/10 minutes greater and a T fm of at least 10°C greater than the second copolymer. There is also a package formed partly or entirely of the resin.
    • 提供一种热封树脂。 基于树脂的总重量,树脂包含5重量%至95重量%的第一共聚物和95重量%至5重量%的第二共聚物。 第一共聚物和第二共聚物一起是树脂总重量的90重量%以上。 第一共聚物包括2至4个碳原子的α-烯烃的第一单体和选自2至8个碳原子的α-烯烃的第二单体的第二单体。 第一共聚物的第一单体和第二单体是不同的。 第一共聚物的MFR为5〜1000g / 10分钟,Tfm为66〜80℃。 第二共聚物包括2至4个碳原子的α-烯烃的第一单体和选自2至8个碳原子的α-烯烃的第二单体的第二单体。 第二共聚物的第一单体和第二单体是不同的。 第二共聚物的MFR为0.5-5g / 10分钟,Tfm为45℃至66℃,其中第一共聚物的MFR至少为2g / 10分钟,Tfm为至少10 °C比第二共聚物大。 还有一部分或全部由树脂形成的包装。