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    • 1. 发明申请
    • METHODS FOR USING LIQUEFIED NATURAL GAS FOR WELL STIMULATION
    • 使用液化天然气进行良性刺激的方法
    • WO2013177114A1
    • 2013-11-28
    • PCT/US2013/041952
    • 2013-05-21
    • LINDE AKTIENGESELLSCHAFTSHIRLEY, Arthur, I.
    • SHIRLEY, Arthur, I.
    • E21B43/25
    • E21B43/26
    • A method for fraccing oil or gas wells to recover natural gas. Liquefied natural gas is vaporized to form a foam or dense fluid. The foam or dense fluid is compressed to high pressures. The high pressure natural gas foam or dense fluid is fed into the oil or gas well and once the well is pressurized to a predetermined pressure and fracturing has begun, the flow of the foam or dense fluid is stopped. After a suitable period for fracturing to occur, the flow is reversed and the natural gas from the well and the foam or dense fluid fracturing fluid is recovered. The recovered and produced natural gas can be treated and made ready for use in other applications.
    • 一种用于压裂油气井以回收天然气的方法。 液化的天然气被蒸发以形成泡沫或致密流体。 泡沫或致密流体被压缩到高压。 将高压天然气泡沫或致密流体输送到油井或气井中,并且一旦将井加压到预定压力并开始压裂,则停止泡沫或致密流体的流动。 在发生压裂的适当时期之后,流动相反,回收井内的天然气和泡沫或致密的流体压裂液。 回收和生产的天然气可以处理并准备用于其他应用。
    • 4. 发明申请
    • BUBBLE-ENHANCED PROPPANT FOR WELL FRACTURING
    • 泡沫增强的优点,用于破裂
    • WO2014062988A1
    • 2014-04-24
    • PCT/US2013/065560
    • 2013-10-18
    • LINDE AKTIENGESELLSCHAFTSHIRLEY, Arthur, I.WEXLER, EugeneSCHNEIDER, PatrickWATTS, Robin
    • SHIRLEY, Arthur, I.WEXLER, EugeneSCHNEIDER, PatrickWATTS, Robin
    • C09K8/80
    • C09K8/665C09K8/703C09K8/80
    • Stable, gas-fil!ed bubbles on the surface of proppant particles are formed by placing proppant in selected organic solvent having a much greater solubility of a selected gas compared to water, pressurizing the solvent with the selected gas, e.g., nitrogen, at pressures equal of greater than the operating pressure for a set time period to achieve saturation, and then replacing the solvent with water before reducing the pressure back to operating pressure level to create a local supersaturation near the solvent-solid interface, which will result in gas-filled bubble formation on the surface of proppant particles. The pressurized mixture of bubble surrounded proppant particles and water can then be combined with a respective fracturing fluid, e.g., slick water or carbon dioxide and/or nitrogen foam or an emulsion, which can be used in oil or gas producing wells to improve efficiency of hydraulic fracturing thereof.
    • 通过将支撑剂置于选定的有机溶剂中形成稳定的,气体填充气泡,所述选择性有机溶剂具有比水更高的选择气体的溶解度,与所选择的气体(例如氮气)在压力下加压溶剂 等于设定时间段内的工作压力达到饱和,然后在将压力降低到工作压力水平之前用水替代溶剂,在溶剂 - 固体界面附近产生局部过饱和,这将导致气 - 支撑剂颗粒表面的填充气泡形成。 支撑剂颗粒和水的加压泡沫混合物然后可以与相应的压裂流体(例如,光滑的水或二氧化碳和/或氮气泡沫或乳液)组合,其可以用于油或气体生产井中以提高效率 水力压裂。