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    • 1. 发明申请
    • GEL-FORM SOLID POLYMER ELECTROLYTE
    • 凝胶型固体聚合物电解质
    • WO1998025275A1
    • 1998-06-11
    • PCT/JP1997004355
    • 1997-11-28
    • MITSUI CHEMICALS, INC.SHINDO, MasaharuSASANO, Takako
    • MITSUI CHEMICALS, INC.
    • H01B01/12
    • H01M10/052H01B1/122H01G11/56H01M6/164H01M6/168H01M10/0565H01M2300/0085Y02E60/13
    • A gel-form solid polymer electrolyte which comprises (a) a matrix consisting of an acrylic ester polymer having structural units derived from at least one acrylic ester selected among those represented by general formulae (I) and (II); (b) a nonaqueous solvent comprising a carbonic ester; and (c) a salt of a Group Ia metal of the Periodic Table, wherein formula (I), R , R and R are the same or different and each represents hydrogen or C1-4 alkyl; R represents C1-4 alkyl; and n is an integer of 1 to 100, and in formula (II), R to R are the same or different and each represents hydrogen or C1-4 alkyl; and p, q and r are the same or different and each is an integer of 1 to 100. Since the electrolyte comprises the acrylic ester polymer as the matrix and the specific nonaqueous solvent contained therein, it has a high ionic conductivity and is electrochemically stable. It is usable in electrochemical elements for primary battery, secondary battery, capacitor, electrochromic display, etc., and in medical actuator, etc.
    • 一种凝胶状固体聚合物电解质,其包含(a)由具有衍生自通式(I)和(II)所示的至少一种丙烯酸酯的结构单元的丙烯酸酯聚合物构成的基体; (b)含有碳酸酯的非水溶剂; 和(c)元素周期表的Ia族金属的盐,其中式(I),R 1,R 2和R 2'相同或不同,各自表示氢或C1-4 烷基; R 3表示C 1-4烷基; n为1〜100的整数,式(II)中,R 4〜R 9相同或不同,分别表示氢或C 1-4烷基; p,q和r相同或不同,各自为1〜100的整数。由于电解质包含丙烯酸酯聚合物作为基体,其中含有特定的非水溶剂,其具有高的离子电导率并且是电化学稳定的 。 它可用于一次电池,二次电池,电容器,电致变色显示器等的电化学元件,以及医疗执行器等。