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1. 发明申请

WO2013123157A3 SYNTHESIS OF PHOTOVOLTAIC CONJUGATED POLYMERS 审中-公开
公开(公告)号：WO2013123157A3
公开(公告)日：2013-08-22
申请号：PCT/US2013/026092
申请日：2013-02-14
申请人： PHILLIPS 66 COMPANY , SOLARMER ENERGY, INC. , WANG, Shuangxi , SHI, Chenjun , CHEN, Ruby , ZHANG, Junlian , HUANG, Hui , WU, Yue , WANG, Wei , PALKAR, Amit , HE, Ting
发明人： WANG, Shuangxi , SHI, Chenjun , CHEN, Ruby , ZHANG, Junlian , HUANG, Hui , WU, Yue , WANG, Wei , PALKAR, Amit , HE, Ting
IPC分类号： C07D339/00
摘要： A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.

2. 发明申请

WO2013123157A2 SYNTHESIS OF PHOTOVOLTAIC CONJUGATED POLYMERS 审中-公开
标题翻译：光聚合聚合物的合成
公开(公告)号：WO2013123157A2
公开(公告)日：2013-08-22
申请号：PCT/US2013026092
申请日：2013-02-14
申请人： PHILLIPS 66 CO , SOLARMER ENERGY INC , WANG SHUANGXI , SHI CHENJUN , CHEN RUBY , ZHANG JUNLIAN , HUANG HUI , WU YUE , WANG WEI , PALKAR AMIT , HE TING
发明人： WANG SHUANGXI , SHI CHENJUN , CHEN RUBY , ZHANG JUNLIAN , HUANG HUI , WU YUE , WANG WEI , PALKAR AMIT , HE TING
IPC分类号： H01L51/00
CPC分类号： C08G61/126 , C07D409/02 , C07D495/04 , C08G2261/12 , C08G2261/124 , C08G2261/1412 , C08G2261/1426 , C08G2261/1428 , C08G2261/146 , C08G2261/149 , C08G2261/18 , C08G2261/3223 , C08G2261/3243 , C08G2261/91 , H01L51/0036 , H01L51/0037 , H01L51/0043 , H01L51/42 , H01L51/4253 , H01L2251/308 , Y02E10/50 , Y02E10/549 , Y02P70/521
摘要： A method of making a fluorothieno[3,4-b]thiophene derivatives and photovoltaic polymers containing same using 3-bromothiophene-2-carboxylic acid as a starting material. This synthetic route provides an easier synthesis as well as greater yield and a purer product, which produces superior results over the prior art less pure products. The resulting materials can be used in a variety of photovoltaic applications and devices, especially solar cells.
摘要翻译：使用3-溴噻吩-2-羧酸作为原料制备含氟噻吩并[3,4-b]噻吩衍生物和含有它们的光伏聚合物的方法。这种合成路线提供了更容易的合成以及更高的产率和更纯的产物，其产生比现有技术较少的纯产品优异的结果。所得材料可用于各种光伏应用和设备，特别是太阳能电池。

3. 发明申请

WO2007109545A3 COPOLYMERS OF ALKOXYTHIOPHENE 审中-公开
公开(公告)号：WO2007109545A3
公开(公告)日：2007-09-27
申请号：PCT/US2007/064179
申请日：2007-03-16
申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA , PEI, Qibing , YANG, Yang , SHI, Chenjun
发明人： PEI, Qibing , YANG, Yang , SHI, Chenjun
IPC分类号： C08G61/00
摘要： The synthesis, characterization, optical and electrochemical properties of a regioregular copolymer, poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5- diyl) (POT-co-DOT), and an alternating regioregular copolymer poly{(9,9- dioctylfluorene)-2,7-diyl-a/f-[4,7-bis(3-decyloxythien-2-yl)-2, 1,3-benzothiadiazole]- 5',5"-diyl} (PF-co-DTB) is disclosed. The incorporation of 3-alkoxythiophene units onto the conjugated backbones enhances the electron-donating property of the polymer and lowers its bandgap. The fabrication and performance of photovoltaic cells with bulk heterojunction architecture based on blends of these copolymers with PCBM are also described.

4. 发明申请

WO2007109545A2 COPOLYMERS OF ALKOXYTHIOPHENE 审中-公开
标题翻译：烷氧基聚乙二醇的共聚物
公开(公告)号：WO2007109545A2
公开(公告)日：2007-09-27
申请号：PCT/US2007064179
申请日：2007-03-16
申请人： UNIV CALIFORNIA , PEI QIBING , YANG YANG , SHI CHENJUN
发明人： PEI QIBING , YANG YANG , SHI CHENJUN
IPC分类号： C08G61/12
CPC分类号： C08G61/126 , C08G61/02 , C08G61/12 , C08G61/123
摘要： The synthesis, characterization, optical and electrochemical properties of a regioregular copolymer, poly(3-octylthiophene-2,5-diyl-co-3-decyloxythiophene-2,5- diyl) (POT-co-DOT), and an alternating regioregular copolymer poly{(9,9- dioctylfluorene)-2,7-diyl-a/f-[4,7-bis(3-decyloxythien-2-yl)-2, 1,3-benzothiadiazole]- 5',5"-diyl} (PF-co-DTB) is disclosed. The incorporation of 3-alkoxythiophene units onto the conjugated backbones enhances the electron-donating property of the polymer and lowers its bandgap. The fabrication and performance of photovoltaic cells with bulk heterojunction architecture based on blends of these copolymers with PCBM are also described.
摘要翻译：聚苯乙烯共聚物，聚（3-辛基噻吩-2,5-二基 - 共-3-癸氧基噻吩-2,5-二基）（POT-co-DOT）的合成，表征，光学和电化学性质以及交替区域分布共聚物聚{（9,9-二辛基芴）-2,7-二基-α/ f- [4,7-双（3-癸氧基噻吩-2-基）-2,1,3-苯并噻二唑] -5'，5 公开了“-diyl”（PF-co-DTB），在共轭骨架上引入3-烷氧基噻吩单元，增强了聚合物的给电子性能，降低了其带隙，制造了具有体异质结结构的光伏电池的性能也描述了这些共聚物与PCBM的共混物。

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