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1. 发明申请

WO9621689A2 BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES 审中-公开
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：WO9621689A2
公开(公告)日：1996-07-18
申请号：PCT/EP9502493
申请日：1995-06-27
申请人： BASF AG , WARZELHAN VOLKER , SCHORNICK GUNNAR , BAUMANN EDWIN , SEELIGER URSULA , YAMAMOTO MOTONORI , RAMLOW GERHARD
发明人： WARZELHAN VOLKER , SCHORNICK GUNNAR , BAUMANN EDWIN , SEELIGER URSULA , YAMAMOTO MOTONORI , RAMLOW GERHARD
IPC分类号： C08G18/60 , C08G69/44 , C08G73/04 , C08J9/04 , C08L1/02 , C08L77/12 , C08L101/16 , C09D175/12 , C09J177/12 , D21H19/30
CPC分类号： C08G69/44 , C08G18/606 , Y02W30/43
摘要： The invention concerns biologically degradable polyester amides P1 obtainable through reaction of a mixture consisting essentially of the following: (a1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0-5 mol % a compound containing sulphonate groups (the sum of the individual molar percentages is 100); (a2) a mixture consisting essentially of: (a21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino-C5-C10 cycloalkanol, (a23) 0-50 mol % a diamino C1-C8 alkane; and (a24) 0-50 mol % a 2,2`-bisoxazoline of general formula (I), in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the molar ratio of a1 to a2 is in the range 0.4:1 - 1.5:1). The polyester amides P1 will have a molecular weight (Mn) in the range 4000-40,000 g/mol, a viscosity number in the range 30-350 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-220 DEG C; and a quantity of a compound D equivalent to 0-5 mol % of the molar quantity of components (a1) must also be used for the production of the polyester amides P1, said compound D having at least three groups capable of ester formation. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same, the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch which can be obtained from the polymers or moulding materials according to the invention.
摘要翻译：可生物降解的聚酯酰胺通过基本上由混合物反应P1获得（a1）的基本上35由〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜65摩尔％的对苯二甲酸或其酯形成性衍生物的混合物或其混合物，和0〜5摩尔％磺酸酯化合物的，单独的摩尔百分比的总和为100摩尔％，和（a2）从99.5基本上由（A21）〜0.5摩尔的混合物 - （A22）0.5选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物，的％至99.5摩尔％的氨基C2-C12链烷醇或氨基-C5的 C10-环烷醇，以及（A23）0〜50摩尔％的二氨基C1-C8烷烃，（A24）0〜50摩尔％通式（I）的2,2'-二恶唑啉，其中R <1 >一个单键，（CH 2）●亚烷基其中q = 2，3或4，或亚苯基，其中装置各个摩尔百分比的总和为100摩尔％，并且其中的（a1）至（A2）的范围为0.4的摩尔比：1至1.5：1种选择，条件是该聚酯酰胺P1的分子量（Mn）的范围为4000至40,000克/摩尔，在30至350范围内的粘度数克/毫升（在以0.5重量％的浓度的邻二氯苯/苯酚（50/50重量比）进行测定。 - ％聚酯酰胺P1在25℃的温度），并在50至220℃的范围内的熔点，并与一个从0〜5摩尔％基于组分的摩尔量进一步的条件（A1 ），与能够对聚酯酰胺的制备酯的形成至少三个基团的化合物D P1中使用的以及其它可生物降解的聚合物和热塑性模塑组合物，涉及它们的制备方法，它们用于制备可生物降解的模制品和粘合剂，生物可降解的成型品使用，泡沫和从本发明的聚合物或模塑组合物获得的淀粉混合物。

2. 发明申请

WO1993025513A1 METHOD FOR THE SIMULTANEOUS PREPARATION OF DICARBOXYLIC ACIDS AND DIAMINES BY DECOMPOSING POLYAMIDES INTO THEIR CONSTITUENT MONOMERS 审中-公开
标题翻译：操作法，二羧酸和二胺由分裂的聚酰胺其单体成分同时生产
公开(公告)号：WO1993025513A1
公开(公告)日：1993-12-23
申请号：PCT/EP1993001448
申请日：1993-06-09
申请人： BASF AKTIENGESELLSCHAFT , SEELIGER, Ursula , MUELLER, Wolfgang, F. , HEIMANN, Frank , HUBER, Guenther , HABERMANN, Wolfgang , VOSS, Hartwig , SIEGEL, Hardo
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C209/62
CPC分类号： C25B3/00 , B01D61/44 , B01D61/445 , C07C51/06 , C07C51/43 , C07C209/62 , C08G69/48 , C07C55/14
摘要： Disclosed is a method for the simultaneous preparation of dicarboxylic acids and diamines from (a) polymers based on polyamides made by reacting dicarboxylic acids or derivatives thereof with diamines or (b) compounds containing essentially such polymers, by decomposing these polymers into their constituent monomers by treating the polymers or compounds with a base in an alcoholic solution and subsequently converting electrochemically the dicarboxylic-acid salts thus produced into the corresponding dicarboxylic acids and bases.

3. 发明申请

WO1996025448A1 BIODEGRADABLE POLYMERS, PROCESS FOR PRODUCING THEM AND THEIR USE IN PREPARING BIODEGRADABLE MOULDINGS 审中-公开
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：WO1996025448A1
公开(公告)日：1996-08-22
申请号：PCT/EP1996000458
申请日：1996-02-03
申请人： BASF AKTIENGESELLSCHAFT , WARZELHAN, Volker , PIPPER, Gunter , SEELIGER, Ursula , BAUER, Peter , BEIMBORN, Dieter, Bernhard , YAMAMOTO, Motonori
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08G63/60
CPC分类号： C08G63/91 , A61L15/26 , A61L15/62 , C08G63/20 , C08G63/60 , C08G63/668 , C08G63/672 , Y02W30/43 , C08L67/00
摘要： Biodegradable polyether esters P1 obtainable through the reaction of a mixture consisting essentially of: (a1) a mixture consisting essentially of 20 to 95 mol % adipic acid, ester-forming derivatives thereof or mixtures thereof, 5 to 80 mol % terephthalic acid, ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol % of a compound containing sulphonate groups, in which the sum of the individual mol percentages is 100; and (a2) a mixture of dihydroxy compounds consisting essentially of (a21) 15 to 99.8 mol % of a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols, (a22) 85 to 0.2 mol % of an ether function-containing dihydroxy compound as per formula (I): HO-[(CH2)n-O]m-H, in which n is 2, 3 or 4 and m is a whole number from 2 to 250, or mixtures thereof, the molar ratio of (a1) to (a2) being in the range from 0.4:1 to 1.5:1, provided that the polyether esters have a molecular weight (Mn) in the range from 5000 to 80 000 g/mol, a viscosity index in the range from 30 to 450 g/ml (measured in o-dichlorobenzol/phenol ( weight ratio 50/50), at a concentration of 0.5 wt % polyether esters P1 at a temperature of 25 DEG C) and a melting point in the range from 50 to 200 DEG C, and with the further provisos that from 0.01 to 5 mol % related to the molar quantity of the component (a1) used of a compound D with at least three groups capable of ester formation are used to produce the polyether esters P1, and that the polyether esters P1 contain both hydroxyl and carboxyl terminal groups, the molar ratio of carboxyl to hydroxyl terminal groups being greater than one. The invention also relates to further biodegradable polymers and thermoplastic casting compounds, process for their production, their use in the manufacture of biodegradable casting compounds and adhesives, biodegradable mouldings, foams and blends with starch obtainable from the polymers or casting compounds of the invention.
摘要翻译：通过基本上由的混合物反应得到的可生物降解的聚醚酯P1（a1）的基本上由20〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜80摩尔％的对苯二甲酸或其酯形成性衍生物的混合物或其混合物，和0〜5摩尔％磺酸酯化合物的，单独的摩尔百分比的总和为100摩尔％，和（a2）基本上由（A21）的二羟基化合物为15〜99.8的混合物摩尔％（A22）选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物，为85〜0.2摩尔％的含醚的功能和根据式（I）HO的二羟基化合物中的 - [（ CH 2）NO] mH的，提供了其中n是2,3或4，m为2至250的整数，或它们的混合物，其中（a1）至（A2）中的0.4的范围内的摩尔比： 1至1.5：1个选择与条件是该聚醚酯P1具有的范围内的分子量（Mn）为5000〜80000克/摩尔，在30至450范围内的粘度数克/毫升（邻二氯苯/苯酚测量（50/50重量比）在具有0.5重量％聚醚酯P1的在25℃的温度下）的浓度和在50至200℃的范围内的熔点，并与进一步的条件是从0.01〜5％（摩尔）基于组分（a1）的摩尔量，与能够对聚醚酯P1开始的制备酯的形成至少三个基团的化合物D，以及进一步的条件是所述聚醚酯P1同时具有羟基和羧基末端基团的摩尔比羧基端基与羟基端基的大于一个选择的，以及其它可生物降解的聚合物和热塑性模塑组合物，它们的制备方法，它们用于制备可生物降解的Formkör使用每孔用作粘合剂，可生物降解的模制品，泡沫以及与淀粉共混物从本发明的聚合物或模塑组合物获得。

4. 发明申请

WO1996020220A1 BIODEGRADABLE THERMOPLASTIC STARCHES 审中-公开
标题翻译：可生物降解和热塑性加工的强度
公开(公告)号：WO1996020220A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995005029
申请日：1995-12-19
申请人： BASF AKTIENGESELLSCHAFT , WARZELHAN, Volker , SEELIGER, Ursula , TOMKA, Ivan
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08B31/04
CPC分类号： C08B31/04 , C08G63/664
摘要： Biodegradable thermoplastic starches contain side chains bound by ester groups. The percentage by weight of the side chains equals at least 10 in relation to the molecular weight (numeric mean value Mn) of the biodegradable thermoplastic starches. Global migration is lower than 200 mg/dm when determined in the conditions set by guideline 90/128/EEC.
摘要翻译：通过酯基团的侧链，其中该重量分数中的至少10重量％的侧链的，基于所述分子量（数均Mn）为生物可降解的和可热塑性加工淀粉和全球迁移小于200毫克/分米含结合的可生物降解和可热塑性加工淀粉 <2>，按照在指令所规定的条件90/128 / EEC条件是确定的。

5. 发明申请

WO1996015176A1 BIODEGRADABLE POLYMERS, PROCESS FOR THEIR PREPARATION AND THEIR USE FOR PRODUCING BIODEGRADABLE MOULDED BODIES 审中-公开
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：WO1996015176A1
公开(公告)日：1996-05-23
申请号：PCT/EP1995004374
申请日：1995-11-07
申请人： BASF AKTIENGESELLSCHAFT , WARZELHAN, Volker , BRAUN, Frank , KRONER, Matthias , SEELIGER, Ursula , YAMAMOTO, Motonori , BÜSCHL, Rainer
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08G63/91
CPC分类号： C08G63/916 , C08G63/60 , C08G63/672
摘要： The invention concerns biodegradable polyether esters obtained by reacting a mixture consisting of: (a1) 95 to 99.9 wt % polyether ester P1, obtained by reacting a mixture consisting of: (b1) a mixture consisting of: 20 to 95 mol % adipic acid or esterifying derivatives thereof or mixtures thereof; 5 to 80 mol % terephthalic acid or esterifying derivatives thereof or mixtures thereof; and 0 to 5 mol % of a sulphonate group-containing compound; and (b2) a mixture of dihydroxy compounds, essentially consisting of: (b21) 15 to 99.8 mol % of a dihydroxy compound; and (b22) 85 to 0.2 mol % of an ether function-containing dihydroxy compound as per formula (I) HO-[(CH2)n-O]m-H, in which n stands for 2, 3 or 4 and m stands for an integer from 2 to 250, or mixtures thereof, the molar ratio of (b1) to (b2) ranging from 0.4:1 to 1.5:1; (a2) 0.1 to 5 wt % of a divinylether C1; and (a3) 0 to 5 mol % of compound D; as well as further biodegradable polymers and thermoplastic moulding compounds. The invention also concerns a process for their preparation, their use for producing biodegradable moulded bodies and adhesives, and biodegradable moulded bodies, foams and blends with starch obtained from the polymers and moulding compounds according to the invention.
摘要翻译：通过由（A1）95〜99.9可获得重量％聚醚酯P1的由选自（B1）由20〜95摩尔％的己二酸或其酯形成的混合物的混合物反应的混合物的反应获得的可生物降解的聚醚酯它们的衍生物或它们的混合物，5〜80摩尔％的对苯二甲酸或其酯形成性衍生物或者它们的混合物，以及0〜5摩尔％磺酸酯化合物，和（B2）基本上由二羟基化合物的混合物（B21）15 至99.8％（摩尔）的二羟基化合物（B22）85〜0.2％（摩尔）含有醚官能团的二羟基化合物中的和根据式I HO - [（CH 2）NO] mH的，其中n是2,3或4和 m为2〜250的整数。提供，或者它们的混合物，其中在所述范围从0.4的（B1）的摩尔比（B2）：1至1.5：1种选择，（A2）0.1 到5重量从0二乙烯基醚C1和（a3）的％〜5摩尔％的化合物D的和远 ERE生物可降解聚合物和热塑性模塑组合物，其制备方法，它们用于制备可生物降解的模制品和粘合剂，可生物降解的模制品，泡沫的用途和融合了从本发明的聚合物或模塑组合物获得的淀粉。

6. 发明申请

WO1996015173A1 BIODEGRADABLE POLYMERS, PROCESS FOR THEIR PRODUCTION AND THEIR USE IN PRODUCING BIODEGRADABLE MOULDINGS 审中-公开
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：WO1996015173A1
公开(公告)日：1996-05-23
申请号：PCT/EP1995002491
申请日：1995-06-27
申请人： BASF AKTIENGESELLSCHAFT , WARZELHAN, Volker , SCHORNICK, Gunnar , BRUCHMANN, Bernd , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08G63/20
CPC分类号： C08L3/02 , C08G18/4216 , C08G18/4219 , C08G18/4277 , C08G18/428 , C08G18/4286 , C08G18/4676 , C08G18/6659 , C08G63/20 , C08G63/60 , C08G2230/00 , C08L75/06 , C09D167/00 , C09K17/52 , Y02A40/284 , Y10S525/938 , Y10T428/31547 , Y10T428/31786 , Y10T428/31794 , C08L2666/02 , C08L2666/26 , C08L2666/36
摘要： Biodegradable polyesters P1 obtainable by the reaction of a mixture consisting essentially of (a1) a mixture essentially of 35 to 95 mol% adipic acid or ester-forming derivatives thereof or mixtures thereof, 5 to 65 mol% terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and 0 to 5 mol% of a sulphonate group-containing compound in which the sum of the individual mol percentages is 100, and (a2) a dihydroxy compound selected from the group consisting of C2-C6 alkane diols and C5-C10 cycloalkane diols, in which the molar ratio of (a1) and (a2) is in the range from 0.4:1 to 1.5:1, provided that the polyester P1 have a molecular weight (Mn) in the range from 5000 to 50,000 g/mol, a viscosity index in the range from 30 to 350 g/ml (measured in o-dichlorobenzole/phenol (in a ratio by weight of 50/50) at a concentration of 0.5 wt.% polyester P1 at a temperature of 25 DEG C) and a melting point in the range from 50 to 170 DEG C, and with the further proviso that from 0.01 to 5 mol% in relation to the molar quantity of the component (a1) used of compound D with at least three groups capable of forming esters are used to produce the polyesters P1, and other biodegradable polymers and thermoplastic moulding compounds and adhesives, biodegradable mouldings, foams and blends with starch obtainable from the polymers or moulding compounds of the invention.
摘要翻译：可生物降解聚酯P1由基本上由混合物反应获得（A1）基本上35由〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜65摩尔％的对苯二甲酸或其酯形成性衍生物的混合物或其混合物，和0〜5摩尔％磺酸酯化合物的，单独的摩尔百分比的总和为100摩尔％，和（a2）选自C2-C6烷二醇和C5-C10组成的组中的二羟基化合物 -cycloalkanediols，其中的（a1）至（A2）在0.4的范围内的摩尔比：1至1.5：1种选择，条件是所述聚酯P1具有分子量（Mn）的范围为5000至50000，条件克/摩尔，在范围在聚酯P1 0.5重量％的浓度在25℃的温度的粘度数从30至350微克/毫升（邻二氯苯测定/苯酚（50/50重量比） C）和熔点包含50至170℃，并与进一步的条件是从0.01〜5摩尔％，基于组分（a1）的摩尔量，一化合物D与能够形成酯的至少三个基团为生产聚酯P1中使用的以及其它可生物降解的聚合物和热塑性模塑组合物，其制备方法，它们用于制备可生物降解的模制品和粘合剂，可生物降解的模制品，泡沫的用途，并与本发明的聚合物或模塑组合物获得的淀粉的共混物。

7. 发明申请

WO2006074815A1 BIOLOGISCH ABBAUBARE POLYESTERMISCHUNG 审中-公开
标题翻译：生物可降解聚酯混纺
公开(公告)号：WO2006074815A1
公开(公告)日：2006-07-20
申请号：PCT/EP2005/014162
申请日：2005-12-31
申请人： BASF Aktiengesellschaft , SEELIGER, Ursula , SKUPIN, Gabriel , STÄRKE, Dirk
发明人： SEELIGER, Ursula , SKUPIN, Gabriel , STÄRKE, Dirk
IPC分类号： C08L67/00 , C08G63/00
CPC分类号： C08L67/02 , C08K5/101 , C08K5/20 , C08L25/14 , C08L33/068 , C08L63/00 , C08L67/04 , C08L91/00 , C08L101/06 , C08L2666/02 , C08L2666/14
摘要： Die Erfindung betrifft biologisch abbaubare Polyestermischung, umfassend i) 5 bis 80 Gew.-%, bezogen auf das Gesamtgewicht der Komponenten i bis ii, mindestens eines Polyesters auf Basis von aliphatischen und aromatischen Dicarbonsäuren und aliphatischen Dihydroxyverbindung und ii) 20 bis 95 Gew.-%, bezogen auf das Gesamtgewicht der Komponenten i bis ii, mindestens eines biologisch abbaubarer Homo- oder Copolyester ausgewählt aus der Gruppe bestehend aus Polylactid, Polycaprolacton, Polyhydroxyalkanoate und Polyester aus aliphatischen Dicarbonsäuren und aliphatischen Diolen, und iii) 0,1 bis 15 Gew.-%, bezogen auf das Gesamtgewicht der Komponenten i bis ii, a) eines Epoxidgruppen-haltigen Copolymers auf Basis Styrol, Acrylsäureester und/oder Methacrylsäureester, b) eines Biphenol-A-Epoxids oder c) eines Epoxidgruppen-haltigen natürlichen Öls, Fettsäureesters oder Fettsäureamids und iv) 0 bis 15 Gew.-% Additiv; und v) 0 bis 50 Gew.-% anorganischer oder organischer Füllstoff, sowie Verfahren zu deren Herstellung und Verwendung.
摘要翻译：本发明涉及一种可生物降解的聚酯混合物中，基于脂族和芳族二羧酸和脂族二羟基化合物，和ii）20至95重量份包含从5 i）至80重量％，基于组分i与ii的总重量，至少一种聚酯的基于组分i的与ii的总重量，至少一种可生物降解的均聚物或共聚聚酯选自聚交酯，聚己内酯，聚羟基脂肪酸酯，和脂族二羧酸和脂肪族二醇构成的聚酯的组中选择的，和iii）0.1〜15重量％。 - ％，基于组分i与ii的总重量，a）以环氧的基团的共聚物上的苯乙烯，丙烯酸酯和/或甲基丙烯酸酯，b）一种双酚A环氧化物，或c）环氧天然油基的，脂肪酸酯或脂肪酸酰胺，和iv）0至15重量添加剂％; 和v）0至50重量％的无机或有机填料，以及它们的制备和使用方法。

8. 发明申请

WO1996021691A1 BIOLOGICALLY DEGRADABLE POLYMERS, PROCESSES FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES 审中-公开
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：WO1996021691A1
公开(公告)日：1996-07-18
申请号：PCT/EP1996000064
申请日：1996-01-09
申请人： BASF AKTIENGESELLSCHAFT , WARZELHAN, Volker , SCHORNICK, Gunnar , KRONER, Matthias , SEELIGER, Ursula , YAMAMOTO, Motonori , RAMLOW, Gerhard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08G69/44
CPC分类号： C08K5/09 , B65D65/466 , C08G69/44 , C08G69/48 , C08L3/02 , Y02W30/43 , Y02W90/11 , Y02W90/13 , C08L77/12 , C08L2666/02
摘要： The invention concerns biologically degradable polyether ester amides Q1 with a molecular weight (Mn) in the range 6000-8000 g/mol, a viscosity number in the range 30-450 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyether ester amide Q1 at a temperature of 25 DEG C) and a melting point in the range 50-200 DEG C, obtainable through reaction of a mixture consisting essentially of the following: (a1) 95-99.9 wt.% polyether ester amide P1 with a molecular weight (Mn) in the range 6000-80,000 g/mol, a viscosity number in the range 30-450 g/ml (measured in o-dichlorobenzene/phenol (weight ratio 50/50) at a concentration of 0.5 wt.% polyether ester amide P1 at a temperature of 25 DEG C) and a melting point in the range 50-200 DEG C, obtainable through reaction of a mixture consisting essentially of: (b1) a mixture consisting essentially of: 20-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof; 5-80 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; and 0-5 mol % a compound containing sulphonate groups (the sum of the molar percentages is 100); (b2) a mixture of dihydroxy compounds consisting essentially of: (b21) 15-99.3 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols; (b22) 0.2-85 mol % a dihydroxy compound containing ether functions, of formula I HO-[(CH2)n-O]m-H, wherein n is 2, 3 or 4 and m is an integer between 2 and 250, or mixtures thereof; (b23) 0.5-80 mol % an amino-C2-C12 alkanol or an amino C5-C10 cycloalkanol; and (b24) 0-50 mol % a diamino C1-C8 alkane; (b25) 0-50 mol % a 2,2`-bisoxazoline of general formula II, in which R is a single bond, a (CH2)q-alkylene group in which q = 2, 3 or 4, or a phenylene group (the sum of the individual molar percentages is 100 and the selected molar ratio of b1 to b2 is in the range 0.4:1 - 1.5:1; (a2) 0.1-5 wt.% a divinyl ether C1; and (a3) 0-5 mol % (in relation to components b1 from the production of P1) compound D. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, processes for manufacturing the same and the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles, foams and blends with starch obtainable from the polymers or moulding materials according to the invention.
摘要翻译：生物可降解的聚醚酯酰胺Q1与在范围内的分子量（Mn）为6000〜80000克/摩尔，在30至450范围内的粘度数克/毫升（邻二氯苯/苯酚测量（50/50重量比）在在25℃的温度下0.5重量％聚醚酯酰胺Q1的浓度）和在50的范围内的熔点至200℃，由得到的基本上由（A1）95〜99.9的混合物反应重量％聚醚酯酰胺P1与在范围内的分子量（Mn）为5000〜80000克/摩尔，在30至450范围内的粘度数克/毫升（邻二氯苯/苯酚测量（50/50重量比）在在25℃的温度下0.5重量％聚醚酯酰胺P1的浓度）和在50的范围内的熔点至200℃，由得到的基本上由（B1）的混合物组成的混合物反应基本上由己二酸或EST的20〜95摩尔％其埃尔比勒Dende衍生物或它们的混合物，对苯二甲酸或其酯形成性衍生物或者它们的混合物，以及0〜5摩尔％磺酸酯化合物的5〜80摩尔％时，各自的摩尔百分数的总和为100摩尔％，和（b2）一个基本上由（B21）15〜99.3摩尔％的选自C2-C6烷二醇和C5-C10-环烷二醇的组中选择的二羟基化合物的，（B22）在0.2至85的二羟基化合物的混合物摩尔％的二羟基化合物的含有醚官能团和式（I）HO的 - 是[（CH2）NO] mH的，其中n是2，3或4，且m为2至250的整数，或它们的混合物，（B23）从0.5至80摩尔％的氨基C2-C12链烷醇或氨基C5-C10-环烷醇，以及二氨基-C1-C8烷烃的（B24）0至50摩尔％，（B25）从0到50摩尔％的通式的2,2'-双恶唑啉的（II）式中，R <1>是一个单键，（CH 2）●亚烷基其中q = 2，3或4，或者表示亚苯基，其中，所述各自的摩尔百分数的总和为100摩尔％，其中，在范围从0.4的（B1）的摩尔比（B2）：1至1.5：1的 0.1选择，（A2）5重量的％从制备化合物D P1的，二乙烯基醚C1和（a3）为0〜5摩尔％，基于组分（b1）以及其它可生物降解的聚合物和热塑性模塑组合物，其制备方法，它们用于制备可生物降解的模制品和粘合剂，可生物降解的模制品，泡沫以及与淀粉共混物从本发明的聚合物或模塑组合物获得的用途。

10. 发明申请

WO1996021692A1 BIOLOGICALLY DEGRADABLE POLYMERS, PROCESS FOR MANUFACTURING THE SAME AND THE USE THEREOF FOR PRODUCING BIODEGRADABLE MOULDED ARTICLES 审中-公开
标题翻译：生物降解聚合物，方法的生产和使用，其用于制造生物可降解成型
公开(公告)号：WO1996021692A1
公开(公告)日：1996-07-18
申请号：PCT/EP1996000067
申请日：1996-01-08
申请人： BASF AKTIENGESELLSCHAFT , WARZELHAN, Volker , KRONER, Matthias , HOFMANN, Jürgen , SEELIGER, Ursula , YAMAMOTO, Motonori , BAUER, Peter
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08G69/44
CPC分类号： C08G69/48 , B65D65/466 , C08G69/44 , C08L3/02 , C08L77/12 , C08L2201/06 , Y02W30/43 , Y02W90/13 , C08L2666/02
摘要： The invention concerns biologically degradable polyester amides Q1 obtainable through reaction of a mixture consisting essentially of the following: (a1) 95-99.9 wt % polyester amide P1 obtainable through reaction of a mixture consisting essentially of: (b1) a mixture consisting essentially of: 35-95 mol % adipic acid or ester-forming derivatives thereof or mixtures thereof, 5-65 mol % terephthalic acid or ester-forming derivatives thereof or mixtures thereof; and 0-5 mol % a compound containing sulphonate groups (the sum of the molar percentages is 100); (b2) a mixture of dihydroxy compounds consisting essentially of: (b21) 99.5-0.5 mol % a dihydroxy compound chosen from the group comprising C2-C6 alkane diols and C5-C10 cycloalkane diols, (b22) 0.5-99.5 mol % an amino C2-C12 alkanol or an amino C5-C10 cycloalkanol, (b23) 0-50 mol a diamino C1-C8 alkane, and (b24) 0-50 mol % a 2,2´-bisoxazoline; (a2) 0.1-5 wt % a divinyl ether C1; and (a3) 0-5 mol % (in relation to components b1 from the production of P1) compound D. The invention also concerns other biologically degradable polymers and thermoplastic moulding materials, a process for manufacturing the same and the use thereof for producing biologically degradable moulded articles and adhesives, and biologically degradable moulded articles obtainable from the polymers or moulding materials according to the invention.
摘要翻译：通过基本上由（B1）的混合物中的基本上由混合物反应由基本上由（A1）95〜99.9重量而得到的聚酯酰胺P1的％的混合物的反应获得的可生物降解聚酯Q1 35〜95摩尔％的己二酸或它们的酯形成性衍生物或者它们的混合物，5〜65摩尔％的对苯二甲酸或其酯形成性衍生物或者它们的混合物，以及0〜5摩尔％磺酸酯化合物，个别摩尔的的百分数总和为100摩尔％，和（b2）从99.5到0.5％（摩尔）选自C2-C6烷二醇和C5-C10-环烷二醇，组成的组中的二羟基化合物的（B22基本上由（B21）的混合物中）0.5至99.5％（摩尔）为0〜50摩尔％的二氨基-C1-C8烷烃，（B24的氨基C2-C12链烷醇或氨基C5-C10-环烷醇，以及（B23）的）0至0.1〜50％（摩尔）的2,2'-双恶唑啉，（a2的）。5 - 二乙烯基醚C1的％和（a3）为0〜5摩尔％，基于从制备化合物D P1的，组分（b1）以及其它可生物降解的聚合物和热塑性模塑组合物，它们的制备方法，它们的用途生物用于制备可生物降解的模制品和粘合剂，可生物降解的模制品，本发明的聚合物或模塑组合物获得。

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