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1. 发明申请

WO2021228895A1 CATIONIC LATEX MODIFIED HYDROCARBON BINDER EMULSIONS AND THEIR USE IN THE PREPARATION OF BITUMINOUS PRODUCTS 审中-公开
公开(公告)号：WO2021228895A1
公开(公告)日：2021-11-18
申请号：PCT/EP2021/062540
申请日：2021-05-11
申请人： EUROVIA , SCOTT BADER COMPANY LIMITED
发明人： LEBARBE, Thomas , DELFOSSE, Frédéric , PARISOT, Juliette , JOURDAN, Camille , MARCAULT, Damien , ALGER, Luke
IPC分类号： C08L9/06 , C08L95/00 , C10C3/00
摘要： A process for preparing a cationic latex modified hydrocarbon binder emulsion comprising the steps of: (a) preparing a cationic copolymer latex emulsion by an emulsion polymerisation of polymerizable monomers, said polymerizable monomers comprising A- one or more non-ionic acrylate ester and/or methacrylate ester monomer(s), and B- optionally styrene monomer and/or one or more non-ionic styrene derivative monomer(s), C- optionally one or more cross-linking monomer(s) having two or more ethylenically unsaturated (C=C) double bonds susceptible to free radical copolymerisation, D- optionally one or more epoxy functional monomer (s) having one C=C double bond susceptible to free radical copolymerisation and one epoxide functional group, wherein said polymerizable monomers do not comprise any aliphatic conjugated diene monomer, in presence of a cationic stabilizing surfactant, and (b) adding the cationic copolymer latex emulsion resulting from step (a) to a cationic hydrocarbon binder emulsion, or (b') adding the cationic copolymer latex emulsion resulting from step (a) to an emulsifier solution, said emulsifier solution comprising water, one or more cationic surfactant(s), one or more acid(s) and optionally additives to provide a mixture, and adding the resulting mixture to hydrocarbon binder; to form a cationic latex modified hydrocarbon binder emulsion.

2. 发明申请

WO2011104510A1 METHACRYLATE-BASED ADHESIVE COMPOSITIONS 审中-公开
标题翻译：基于甲基丙烯酸酯的胶粘剂组合物
公开(公告)号：WO2011104510A1
公开(公告)日：2011-09-01
申请号：PCT/GB2011/000256
申请日：2011-02-24
申请人： SCOTT BADER COMPANY LIMITED , OSAE, Samuel, Boadu , BROWN, Steven, Lochiel , PHILLIPPS, Roy, Gordon
发明人： OSAE, Samuel, Boadu , BROWN, Steven, Lochiel , PHILLIPPS, Roy, Gordon
IPC分类号： C09J4/06 , C09J123/28
CPC分类号： C09J4/06 , C08L2666/02 , C09J123/286 , C09J151/04 , C09J175/14
摘要： An adhesive composition, especially suitable for a two- part adhesive system curable via free radical polymerisation comprises; (A) (meth) acrylate ester monomer; (B) chlorinated elastomeric polymer; (C) core-shell impact modifier; and (D) urethane (meth) acrylate oligomer. Example adhesive compositions include urethane (meth) acrylate oligomer (D) derived from (i) a di- or higher isocyanate having at least two isocyanate groups which differ in reactivity; (ii) a chain-extending reagent which has at least two groups selected from hydroxyl and/ or amino groups, each capable of reaction with an isocyanate group of (i); (iii) a hydroxymethacrylate component or hydroxyacrylate component. Also urethane (meth) acrylate oligomers, suitable for use in adhesive compositions, and derived from: (i) a diisocyanate having two isocyanate groups which differ in reactivity; (ii) a chain-extending reagent which is a polyether polyol selected from ethoxylated and propoxylated derivatives of tri- and tetra- functional polyols; and (iii) a hydroxyl (meth) acrylate selected from polyethylene glycol (meth) acrylate and polypropylene glycol (meth) acrylate, are disclosed.
摘要翻译：特别适用于通过自由基聚合可固化的两部分粘合剂体系的粘合剂组合物包括：（A）（甲基）丙烯酸酯单体; （B）氯化弹性聚合物; （C）核壳抗冲击改性剂; 和（D）氨基甲酸酯（甲基）丙烯酸酯低聚物。实例性粘合剂组合物包括衍生自（i）具有至少两个反应性不同的异氰酸酯基团的二异氰酸酯或更高级异氰酸酯的氨基甲酸酯（甲基）丙烯酸酯低聚物（D）（ii）具有至少两个选自羟基和/或氨基的基团的链延长试剂，每个能与（i）的异氰酸酯基团反应; （iii）羟甲基丙烯酸酯组分或羟基丙烯酸酯组分。也适用于粘合剂组合物的聚氨酯（甲基）丙烯酸酯低聚物，衍生自：（i）具有两个反应性不同的异氰酸酯基团的二异氰酸酯; （ii）扩链试剂，其是选自三官能和四官能多元醇的乙氧基化和丙氧基化衍生物的聚醚多元醇; 和（iii）选自聚乙二醇（甲基）丙烯酸酯和聚丙二醇（甲基）丙烯酸酯）的羟基（甲基）丙烯酸酯。

3. 发明申请

WO2022207696A1 INVERSE EMULSION THICKENERS 审中-公开
公开(公告)号：WO2022207696A1
公开(公告)日：2022-10-06
申请号：PCT/EP2022/058393
申请日：2022-03-30
申请人： SCOTT BADER COMPANY LIMITED
发明人： WILLIAMS, Clive Noel , COOK, Victoria Jane
IPC分类号： A61K8/06 , A61K8/31 , A61K8/73 , A61K8/81 , A61Q19/00 , C08F220/58 , C08L33/24 , A61K2800/10 , A61K2800/48 , A61K8/064 , A61K8/066 , A61K8/737 , A61K8/8158 , C08F2/22 , C08F2/32 , C08F220/14 , C08F220/585 , C08F2800/00
摘要： An inverse emulsion copolymer thickener composition comprises (A) an aqueous phase comprising a cross-linked hydrophilic polyelectrolyte copolymer (A') obtained by the free radical copolymerisation of : (i) at least one anionic ethylenically unsaturated monomer bearing a negatively charged group and one polymerisable C=C double bond, or at least one cationic ethylenically unsaturated monomer bearing a positively charged group and one polymerisable C=C double bond, and (ii) at least one non-ionic ethylenically unsaturated cross-linking monomer bearing at least two polymerisable C=C double bonds, and (iii) optionally, one or more hydrophilic non-ionic ethylenically unsaturated monomers bearing one polymerisable C=C double bond, (B) an oil phase comprising a carrier oil (C), (D) (i) at least one water-in-oil emulsifying surfactant, and (D) (ii) at least one oil-in-water emulsifying surfactant; characterised in that the inverse emulsion copolymer composition further comprises (E) a natural gum selected from (i) diutan gum, konjac gum, guar gum, locust bean gum and mixtures thereof and / or (ii) a natural gum that is other than xanthan gum, sodium alginate or sodium carboxymethyl cellulose. The compositions are effective for use as thickeners for thickening aqueous solutions, including solutions which contain dissolved salts.

4. 发明申请

WO2009053287A1 NEW PROCESS FOR THE PREPARATION OF INVERSE LATEX OF ACRYLAMIDE-BASED POLYMERS AND COMPOSITION COMPRISING SAID LATEX 审中-公开
标题翻译：用于制备基于丙烯酰胺的聚合物的反相的新方法和包含合成的聚合物的组合物
公开(公告)号：WO2009053287A1
公开(公告)日：2009-04-30
申请号：PCT/EP2008/063876
申请日：2008-10-15
申请人： SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC , SCOTT BADER COMPANY LIMITED , MALLO, Paul , BRAUN, Olivier , GUY, François , BONNARDEL, Audrey
发明人： MALLO, Paul , BRAUN, Olivier , GUY, François , BONNARDEL, Audrey
IPC分类号： C08F220/56 , C08F2/32 , C08L33/26
CPC分类号： A61K47/32 , A61K8/8158 , A61K8/8188 , A61Q1/02 , A61Q1/04 , A61Q1/14 , A61Q5/00 , A61Q5/12 , A61Q17/04 , A61Q19/002 , A61Q19/005 , A61Q19/008 , A61Q19/04 , A61Q19/06 , C08F2/32 , C08F220/56
摘要： Process for the preparation of a composition comprising an oil phase, an aqueous phase, at least one emulsifying system of water-in-oil (W/O) type, optionally at least one emulsifying system of oil-in-water (O/W) type, in the form of an inverse latex comprising from 20% to 70% by weight and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the said polyelectrolyte is a copolymer of 2-acrylamido-2-methylpropanesulfonic acid partially or totally salified with acrylamide and optionally one or more monomers chosen from monomers containing a partially or totally salified weak acid function and/or from neutral monomers other than acrylamide, said production process being characterized in that the preparation of said aqueous phase comprises the dissolution in the aqueous medium of solid 2-acrylamido- 2-methyl propanesulfonic acid before neutralization. Cosmetic, dermopharmaceutical or pharmaceutical composition comprising the inverse latex directly obtained by said process.
摘要翻译：用于制备包含油相，水相，至少一种油包水（W / O）型乳化系统，任选至少一种水包油乳化系统（O / W）的组合物的方法）型，以包含20％至70％重量，优选25％至50％重量的支链或交联聚电解质的反相胶乳的形式，其特征在于所述聚电解质是2-丙烯酰胺基 - 用丙烯酰胺和任选的一种或多种选自含有部分或完全成盐的弱酸功能的单体和/或除丙烯酰胺以外的中性单体的单体任选地一种或多种2-甲基丙烷磺酸，所述制备方法的特征在于所述水性相包括在中和之前溶解在固体2-丙烯酰胺基-2-甲基丙磺酸的水性介质中。包括通过所述方法直接获得的反相胶乳的化妆品，皮肤药物或药物组合物。

5. 发明申请

WO2010073003A1 GELCOAT COMPOSITION AND ARTICLES COMPRISING THE SAME 审中-公开
标题翻译： GELCOAT组合物和包含该组合物的文章
公开(公告)号：WO2010073003A1
公开(公告)日：2010-07-01
申请号：PCT/GB2009/002930
申请日：2009-12-18
申请人： SCOTT BADER COMPANY LIMITED , PANTHER, Richard, Austin , CLARKE, Simon
发明人： PANTHER, Richard, Austin , CLARKE, Simon
IPC分类号： C08G18/28 , C08G18/67 , C09D175/16
CPC分类号： C08G18/672 , C08G18/2815 , C08G2220/00 , C09D175/16 , Y10T428/31551 , Y10T428/31562 , C08G18/48 , C08G18/42
摘要： The present invention is concerned with gelcoats comprising unsaturated urethane resins containing both acrylate and allyl ether functional groups, which in embodiments provide a desirable combination of a back up time of less than one hour and a longer interval between back up time and tack-free time. In particular, the present invention provides a polymerisable reaction product of: (1) an isocyanate component having two or more isocyanate groups; and (2) ethylenically unsaturated components comprising: (i) an acrylate component having at least one functional group that is reactive with an isocyanate group and at least one acrylate group; and (ii) an allyl component having at least one functional group that is reactive with an isocyanate group and at least one allyl group, wherein the reaction product is in the presence of a reactive diluent monomer suitable for reaction therewith to form a thermoset gel coat.
摘要翻译：本发明涉及包含含有丙烯酸酯和烯丙基醚官能团的不饱和聚氨酯树脂的凝胶涂层，其在实施方案中提供了少于1小时的备用时间和备用时间和无粘性时间之间较长间隔的期望组合。特别地，本发明提供了以下可聚合反应产物：（1）具有两个或更多个异氰酸酯基团的异氰酸酯组分; 和（2）烯属不饱和组分，其包含：（i）具有至少一个与异氰酸酯基团和至少一个丙烯酸酯基团反应的官能团的丙烯酸酯组分; 和（ii）具有至少一个与异氰酸酯基团和至少一个烯丙基基团反应的官能团的烯丙基成分，其中反应产物在适于与其反应的反应性稀释剂单体的存在下形成热固性凝胶涂层。

6. 发明申请

WO2009074513A1 NEW PROCESS FOR THE PREPARATION OF INVERSE LATEX OF ACRYLAMIDE-BASED POLYMERS AND COMPOSITION COMPRISING SAID LATEX 审中-公开
标题翻译：用于制备基于丙烯酰胺的聚合物的反相的新方法和包含合成的聚合物的组合物
公开(公告)号：WO2009074513A1
公开(公告)日：2009-06-18
申请号：PCT/EP2008/066863
申请日：2008-12-05
申请人： SOCIETE D'EXPLOITATION DE PRODUITS POUR LES INDUSTRIES CHIMIQUES SEPPIC , SCOTT BADER COMPANY LIMITED , MALLO, Paul , BRAUN, Olivier , BONNARDEL, Audrey , GUY, François
发明人： MALLO, Paul , BRAUN, Olivier , BONNARDEL, Audrey , GUY, François
IPC分类号： C08F220/56 , C08F2/32 , C08L33/26
CPC分类号： A61K8/72 , A61K8/06 , A61K8/8158 , A61Q1/02 , A61Q1/04 , A61Q1/14 , A61Q5/00 , A61Q5/12 , A61Q17/04 , A61Q19/00 , A61Q19/002 , A61Q19/005 , A61Q19/008 , A61Q19/04 , A61Q19/06 , C08F2/32 , C08F220/56 , C09D133/26
摘要： Process for the preparation of a an inverse latex comprising from 20% to 70% by weight and preferably from 25% to 50% by weight of a branched or crosslinked polyelectrolyte, characterized in that the said polyelectrolyte is a copolymer of 2- acrylamido-2-methylpropanesulfonic acid partially or totally salified with acrylamide and optionally one or more monomers chosen from monomers containing a partially or totally salified weak acid function and/or from neutral monomers other than acrylamide, said production process comprising the control of the pH in the initial aqueous phase; Cosmetic, dermopharmaceutical or pharmaceutical composition comprising the inverse latex directly obtained by said process.
摘要翻译：用于制备反相胶乳的方法，其包含20重量％至70重量％，优选25重量％至50重量％的支链或交联聚电解质，其特征在于所述聚电解质是2-丙烯酰胺基-2 甲基丙磺酸部分或全部用丙烯酰胺和任选的一种或多种选自含有部分或全部成盐的弱酸功能的单体和/或来自除丙烯酰胺以外的中性单体的单体成盐，所述制备方法包括控制初始水溶液中的pH 相; 包括通过所述方法直接获得的反相胶乳的化妆品，皮肤药物或药物组合物。

7. 发明申请

WO2010035006A1 CROSSLINKABLE MOULDING COMPOSITION 审中-公开
标题翻译：可交联成型组合物
公开(公告)号：WO2010035006A1
公开(公告)日：2010-04-01
申请号：PCT/GB2009/002301
申请日：2009-09-29
申请人： SCOTT BADER COMPANY LIMITED , PANTHER, Richard, Austin
发明人： PANTHER, Richard, Austin
IPC分类号： C08G18/67 , C08G18/79 , C08L75/16 , C08F299/02 , C08J5/24
CPC分类号： C08G18/673 , C08F283/006 , C08F290/06 , C08F290/067 , C08F290/14 , C08F290/147 , C08F299/00 , C08F299/02 , C08G18/791 , C08G18/792 , C08G18/798 , C08J5/04 , C08J2375/16 , C08L75/16
摘要： A crosslinkable moulding composition comprises: (1) a functionalised isocyanate product having at least six ethylenically unsaturated groups which is the reaction product of (i) an isocyanate component having an isocyanate functionality of two or more, and (ii) an ethylenically unsaturated component having at least one functional group that is reactive with an isocyanate group of the isocyanate component and at least two ethylenically unsaturated groups; and (2) a monomer component comprising a cross-linking monomer having at least two ethylenically unsaturated groups, wherein at least one of an ethylenically unsaturated component (ii) and/or a monomer component (2) are selected to have at least three ethylenically unsaturated groups. The moulding compositions are especially suitable for reinforcement and thermal curing. Example crosslinked resins derived from such moulding compositions are shown to be capable of achieving high heat deflection temperatures, often in excess of 260 °C.
摘要翻译：交联性成型组合物包括：（1）具有至少6个烯键式不饱和基团的官能化异氰酸酯产物，其是（i）异氰酸酯官能度为2以上的异氰酸酯组分和（ii）具有2个以上异氰酸酯官能团的异氰酸酯组分的反应产物，至少一个与异氰酸酯组分的异氰酸酯基反应的官能团和至少两个烯属不饱和基团; 和（2）包含具有至少两个烯键式不饱和基团的交联单体的单体组分，其中烯键式不饱和组分（ii）和/或单体组分（2）中的至少一种选自具有至少三个烯属不饱和基团不饱和基团。成型组合物特别适用于增强和热固化。衍生自这种模塑组合物的交联树脂的实例显示能够实现高的热变形温度，通常超过260℃。

8. 发明申请

WO2008119973A1 THERMOSETTING RESIN COMPOSITION 审中-公开
标题翻译：热固性树脂组合物
公开(公告)号：WO2008119973A1
公开(公告)日：2008-10-09
申请号：PCT/GB2008/001120
申请日：2008-03-31
申请人： SCOTT BADER COMPANY LIMITED , PANTHER, Richard, Austin
发明人： PANTHER, Richard, Austin
IPC分类号： C08F283/00 , C08F290/14 , C08G18/67
CPC分类号： C08F290/06 , C08F283/006 , C08F290/061 , C08F290/067 , C08F290/14 , C08G18/673 , C08G18/7831 , C08G18/792 , C08G18/798 , C08J5/043
摘要： The present invention provides a cross-linkable functionalised isocyanate composition comprising (1) a functionalised isocyanate product being the reaction product of (i) an isocyanate component having at least two isocyanate groups and (ii) an ethylenically unsaturated component having at least one functional group that is reactive with an isocyanate group of the isocyanate component and at least one ethylenically unsaturated group, wherein the isocyanate component and the ethylenically unsaturated component are selected so that the functionalised isocyanate product has at least three ethylenically unsaturated groups, (2) a monomer component comprising a cross-linking monomer having at least two ethylenically unsaturated groups, and (3) a reinforcing component. Embodiments of the invention being resins that have been cross-linked and cured demonstrate high heat deflection temperature and excellent tensile and flexural properties.
摘要翻译：本发明提供了一种可交联官能化的异氰酸酯组合物，其包含（1）官能化的异氰酸酯产物，其是（i）具有至少两个异氰酸酯基团的异氰酸酯组分和（ii）具有至少一个官能团的烯键式不饱和组分其与异氰酸酯组分的异氰酸酯基团和至少一个烯键式不饱和基团反应，其中选择异氰酸酯组分和烯属不饱和组分，使得官能化的异氰酸酯产物具有至少三个烯键式不饱和基团，（2）单体组分包含具有至少两个烯键式不饱和基团的交联单体，和（3）增强组分。本发明的实施方案是已经交联和固化的树脂显示出高的热变形温度和优异的拉伸和弯曲性能。

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