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    • 2. 发明申请
    • FLUORINATED POLYURETHANE COMPOSITION
    • 氟化聚氨酯组合物
    • WO2011131547A1
    • 2011-10-27
    • PCT/EP2011/055876
    • 2011-04-14
    • SOLVAY SOLEXIS S.P.A.FORGIONE, GerardoROVINETTI, SaraBELTRAMIN, Marco
    • FORGIONE, GerardoROVINETTI, SaraBELTRAMIN, Marco
    • C08G18/08C08G18/50C08G18/66
    • C08G18/5015C08G18/0804C08G18/0819C08G18/0823C08G18/6692
    • The present invention pertains to an aqueous composition comprising: (A) at least one functional fluorinated polymer [polymer (F)] selected from: - a fluorinated ionisable polyurethane polymer [polymer (PUR)] comprising at least one fluorinated block comprising a (per)fluoropolyoxyalkylene chain [chain (R OF )] and at least one functional block comprising a hydrocarbon chain [chain (R H )] optionally comprising one or more aromatic or cycloaliphatic groups, said chain (R H ) comprising at least one ionisable group, said blocks being linked by urethane moieties having formula (I) here below: wherein E is a divalent hydrocarbon group, linear or branched, optionally comprising one or more cycloaliphatic or aromatic groups, and - a fluorinated polymer [polymer (P)] comprising one or more perfluoroalkyl chains [chain (R F )] linked by one or more ester moieties having formula (II) and/or urethane moieties having formula (III) and/or urea moieties having formula (IV) here below: (B) at least one functional hydrogenated polymer [polymer (H)] different from said polymer (F), said polymer (H) comprising at least one functional group; (C) at least one cross-linking agent; wherein the weight ratio of the polymer (F) to the polymer (H) is higher than 0.75.
    • 本发明涉及一种水性组合物,其包含:(A)至少一种选自以下的功能性氟化聚合物[聚合物(F)]: - 含氟可电离聚氨酯聚合物[聚合物(PUR)],其包含至少一个含 )含氟聚氧亚烷基链[链(ROF)]和至少一个包含任选包含一个或多个芳族或脂环族基团的烃链[链(RH)]的官能团,所述链(RH)包含至少一个可离子化基团,所述嵌段 通过下文具有式(I)的氨基甲酸酯部分连接:其中E是直链或支链的任选包含一个或多个脂环族或芳族基团的二价烃基,和 - 包含一个或多个全氟烷基的氟化聚合物[聚合物(P) 由具有式(II)的一个或多个酯部分和/或具有式(III)的氨基甲酸酯部分和/或具有式(IV)的脲部分)连接的链(链)(链)(链)(以下):(B)至少一个乐趣 不同于所述聚合物(F)的氢化聚合物[聚合物(H)],所述聚合物(H)包含至少一个官能团; (C)至少一种交联剂; 其中聚合物(F)与聚合物(H)的重量比高于0.75。