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1. 发明申请

WO2009099848A3 PROCESS TO PRODUCE CLEAN GASOLINE/BIO-ETHERS USING ETHANOL 审中-公开
标题翻译：使用乙醇生产清洁汽油/生物工艺的工艺
公开(公告)号：WO2009099848A3
公开(公告)日：2009-10-29
申请号：PCT/US2009032310
申请日：2009-01-29
申请人： CATALYTIC DISTILLATION TECH , XIONG YI-GANG , ROCK KERRY L , JUDZIS ARVIDS , LOESCHER MITCHELL E
发明人： XIONG YI-GANG , ROCK KERRY L , JUDZIS ARVIDS , LOESCHER MITCHELL E
IPC分类号： C10L1/18 , C10G7/00 , C10G11/00
CPC分类号： C10L1/1852 , C10G2300/30 , C10G2300/305 , C10L1/023
摘要： A fuel or fuel blendstock comprising ethanol, ethyl ethers, olefins, and alkanes. In some embodiments, the fuel or fuel blendstock of claim 1, wherein the fuel or fuel blendstock may have an octane number greater than 92 (RON + MON)/2). In other embodiments, the fuel or fuel blendstock may have a Reid vapor pressure less than 7.2 psi. Also disclosed is a process for the production of a fuel, the process including: contacting ethanol and at least one gasoline fraction including alkanes and olefins in the presence of a catalyst to form a fuel mixture including ethyl ethers, alkanes, unreacted olefins, and unreacted ethanol; and recovering the fuel mixture for use as a gasoline or gasoline blendstock without separation of the ethanol from the fuel mixture.
摘要翻译：包含乙醇，乙醚，烯烃和烷烃的燃料或燃料混合料。在一些实施方案中，权利要求1的燃料或燃料混合原料，其中所述燃料或燃料混合原料可具有大于92（RON + MON）/ 2的辛烷值。在其它实施方案中，燃料或燃料混合原料可具有小于7.2psi的Reid蒸气压。还公开了一种生产燃料的方法，该方法包括：在催化剂存在下使乙醇和至少一种包含烷烃和烯烃的汽油馏分接触，形成包括乙醚，烷烃，未反应烯烃和未反应的燃料混合物乙醇; 以及回收燃料混合物以用作汽油或汽油混合料，而不将乙醇与燃料混合物分离。

2. 发明申请

WO2009035844A3 METHOD OF PRODUCING TERTIARY AMYL ETHYL ETHER 审中-公开
公开(公告)号：WO2009035844A3
公开(公告)日：2009-03-19
申请号：PCT/US2008/074188
申请日：2008-08-25
申请人： CATALYTIC DISTILLATION TECHNOLOGIES , BOYER, Christopher, C. , LOESCHER, Mitchell, E. , ROCK, Kerry, L. , GROTEN, Willibrord, A. , MARASCHINO, Mario, J.
发明人： BOYER, Christopher, C. , LOESCHER, Mitchell, E. , ROCK, Kerry, L. , GROTEN, Willibrord, A. , MARASCHINO, Mario, J.
IPC分类号： C07C41/05 , C07C43/03
摘要： A process for the production of tertiary ethers, including: feeding a hydrocarbon stream comprising isoolefins and propionitrile to a distillation column reactor system containing at least one etherification reaction zone; feeding a C2 to C6 monoalcohol or mixture thereof to the distillation column reactor; concurrently in the distillation column reactor system: reacting a portion of the isoolefins with a portion of the alcohols to form a tertiary ether; and separating the tertiary ether from unreacted isoolefins; withdrawing the tertiary ether and propionitrile from the distillation column reactor system as a bottoms; withdrawing the unreacted isoolefins from the distillation column reactor system as an overheads; and operating the distillation column reactor system such that the etherification reaction zone is substantially free of propionitrile.

3. 发明申请

WO2010021771A1 REFORMATE BENZENE REDUCTION VIA TRANSALKYLATION 审中-公开
标题翻译：通过转化降解苯并噻吩
公开(公告)号：WO2010021771A1
公开(公告)日：2010-02-25
申请号：PCT/US2009/044418
申请日：2009-05-19
申请人： CATALYTIC DISTILLATION TECHNOLOGIES , ROCK, Kerry, L. , BOYER, Christopher, C. , SMITH, Lawrence, A.
发明人： ROCK, Kerry, L. , BOYER, Christopher, C. , SMITH, Lawrence, A.
IPC分类号： C07C2/66 , C07B31/00 , B01J29/00 , C10L1/16
CPC分类号： C10G29/205 , C10G2300/1096 , C10G2300/4081 , C10G2400/02
摘要： A process for reducing benzene content in a reformate stream, including: fractionating a full range reformate comprising benzene, C 7 to C 9 monoalkyl aromatics, and C 1O+ polyalkyl aromatics into at least three fractions including a light reformate fraction comprising the benzene; a medium reformate fraction comprising the C 7 to C 9 monoalkyl aromatics; and a heavy reformate fraction comprising the C 10+ polyalkyl aromatics; feeding the light reformate fraction, the heavy reformate fraction and a transalkylation catalyst to a transalkylation reaction zone; contacting the light fraction and the heavy fraction in presence of the transalkylation catalyst in the transalkylation reaction zone to react at least a portion of the benzene with C 1O+ polyalkyl aromatics to form monoalkyl aromatics; separating an effluent from the transalkylation reaction zone to form a catalyst fraction and a liquid fraction comprising the monoalkyl aromatics.
摘要翻译：一种用于还原重整产物流中苯含量的方法，包括：将包含苯，C 7至C 9单烷基芳烃和C 10+多烷基芳族化合物的全范围重整产物分馏成至少三个馏分，包括包含苯的轻重油馏分; 包含C7-C9单烷基芳族化合物的中等重整油馏分; 和包含C10 +多烷基芳烃的重质重质馏分; 将轻重整油馏分，重质量重馏分和烷基转移催化剂加入烷基转移反应区; 在烷基转移反应区中在烷基转移催化剂存在下使轻馏分和重馏分接触，使至少一部分苯与C 1-10烷基芳族化合物反应形成单烷基芳族化合物; 分离来自烷基转移反应区的流出物以形成催化剂级分和包含单烷基芳族化合物的液体级分。

4. 发明申请

WO2009099848A2 PROCESS TO PRODUCE CLEAN GASOLINE/BIO-ETHERS USING ETHANOL 审中-公开
标题翻译：使用乙醇生产清洁汽油/生物工艺的工艺
公开(公告)号：WO2009099848A2
公开(公告)日：2009-08-13
申请号：PCT/US2009/032310
申请日：2009-01-29
申请人： CATALYTIC DISTILLATION TECHNOLOGIES , XIONG, Yi-Gang , ROCK, Kerry, L. , JUDZIS, Arvids , LOESCHER, Mitchell, E.
发明人： XIONG, Yi-Gang , ROCK, Kerry, L. , JUDZIS, Arvids , LOESCHER, Mitchell, E.
IPC分类号： C10L1/18 , C10G11/00 , C10G7/00
CPC分类号： C10L1/1852 , C10G2300/30 , C10G2300/305 , C10L1/023
摘要： A fuel or fuel blendstock comprising ethanol, ethyl ethers, olefins, and alkanes. In some embodiments, the fuel or fuel blendstock of claim 1, wherein the fuel or fuel blendstock may have an octane number greater than 92 (RON + M0N)/2). In other embodiments, the fuel or fuel blendstock may have a Reid vapor pressure less than 7.2 psi. Also disclosed is a process for the production of a fuel, the process including: contacting ethanol and at least one gasoline fraction including alkanes and olefins in the presence of a catalyst to form a fuel mixture including ethyl ethers, alkanes, unreacted olefins, and unreacted ethanol; and recovering the fuel mixture for use as a gasoline or gasoline blendstock without separation of the ethanol from the fuel mixture.
摘要翻译：包含乙醇，乙醚，烯烃和烷烃的燃料或燃料混合料。在一些实施方案中，权利要求1的燃料或燃料混合原料，其中所述燃料或燃料混合原料可具有大于92（RON + M0N）/ 2的辛烷值。在其它实施方案中，燃料或燃料混合原料可具有小于7.2psi的Reid蒸气压。还公开了一种生产燃料的方法，该方法包括：在催化剂存在下使乙醇和至少一种包含烷烃和烯烃的汽油馏分接触，形成包括乙醚，烷烃，未反应烯烃和未反应的燃料混合物乙醇; 以及回收燃料混合物以用作汽油或汽油混合料，而不将乙醇与燃料混合物分离。

5. 发明申请

WO2009035844A2 METHOD OF PRODUCING TERTIARY AMYL ETHYL ETHER 审中-公开
标题翻译：生产仲胺乙醚的方法
公开(公告)号：WO2009035844A2
公开(公告)日：2009-03-19
申请号：PCT/US2008074188
申请日：2008-08-25
申请人： CATALYTIC DISTILLATION TECH , BOYER CHRISTOPHER C , LOESCHER MITCHELL E , ROCK KERRY L , GROTEN WILLIBRORD A , MARASCHINO MARIO J
发明人： BOYER CHRISTOPHER C , LOESCHER MITCHELL E , ROCK KERRY L , GROTEN WILLIBRORD A , MARASCHINO MARIO J
IPC分类号： C07C41/05 , C07C43/03
CPC分类号： C07C41/06 , Y02P20/127 , C07C43/046
摘要： A process for the production of tertiary ethers, including: feeding a hydrocarbon stream comprising isoolefins and propionitrile to a distillation column reactor system containing at least one etherification reaction zone; feeding a C2 to C6 monoalcohol or mixture thereof to the distillation column reactor; concurrently in the distillation column reactor system: reacting a portion of the isoolefins with a portion of the alcohols to form a tertiary ether; and separating the tertiary ether from unreacted isoolefins; withdrawing the tertiary ether and propionitrile from the distillation column reactor system as a bottoms; withdrawing the unreacted isoolefins from the distillation column reactor system as an overheads; and operating the distillation column reactor system such that the etherification reaction zone is substantially free of propionitrile.
摘要翻译：一种生产叔醚的方法，包括：将含有异烯烃和丙腈的烃流进料到含有至少一个醚化反应区的蒸馏塔反应器系统中; 将C2至C6一元醇或其混合物加入蒸馏塔反应器中; 同时在蒸馏塔反应器系统中：使一部分异烯烃与一部分醇反应形成叔乙醚; 并将叔醚与未反应的异烯烃分离; 从蒸馏塔反应器系统中取出叔醚和丙腈作为底部物质; 从蒸馏塔反应器系统中取出未反应的异烯烃作为塔顶馏出物; 并操作蒸馏塔反应器系统，使得醚化反应区基本上不含丙腈。

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