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    • 1. 发明申请
    • PROCESS FOR PREPARING RUTHENIUM(0)-OLEFIN COMPLEXES
    • 制备钌(0) - 烯烃配合物的方法
    • WO2011057780A3
    • 2011-08-25
    • PCT/EP2010006858
    • 2010-11-11
    • UMICORE AG & CO KGDOPPIU ANGELINORIVAS-NASS ANDREASKARCH RALFWINDE ROLANDWOERNER EILEEN
    • DOPPIU ANGELINORIVAS-NASS ANDREASKARCH RALFWINDE ROLANDWOERNER EILEEN
    • C07F15/00A61K31/28B01J31/00C23C16/18
    • C07F15/0046
    • The present invention relates to a process for preparing ruthenium(0)-olefin complexes of the (arene)(diene)Ru(0) type by reacting a ruthenium starting compound of the formula Ru(+II)(X)p(Y)q (in which X = an anionic group, Y = an uncharged two-electron donor ligand, p = 1 or 2, q = an integer from 1 to 6), with a cyclohexadiene derivative or a diene mixture comprising a cyclohexadiene derivative, in the presence of a base. In this process, the arene bound in the (arene)(diene)Ru(0) complex is formed from this cyclohexadiene derivative by oxidation. Suitable ruthenium(II) starting compounds are, for example, RuCl2(acetonitrile)4, RuCl2(pyridine)4 or RuCl2(DMSO)4. The bases used are inorganic or organic bases. The ruthenium(0)-olefin complexes prepared by the process according to the invention have a high purity and can be used as precursors for homogeneous catalysts, for preparation of functional ruthenium- or ruthenium oxide-containing layers and for therapeutic applications.
    • 本发明涉及通过使式Ru(+ II)(X)p(Y)的钌起始化合物与式(I)的钌起始化合物反应来制备(芳烃)(二烯)Ru (其中X =阴离子基团,Y =不带电荷的双电子供体配体,p = 1或2,q = 1至6的整数)与环己二烯衍生物或包含环己二烯衍生物的二烯混合物在 基地的存在。 在该过程中,(芳烃)(二烯)Ru(0)络合物中的芳烃通过氧化由该环己二烯衍生物形成。 合适的钌(II)起始化合物为例如RuCl 2(乙腈)4,RuCl 2(吡啶)4或RuCl 2(DMSO)4。 所用的碱是无机碱或有机碱。 通过根据本发明的方法制备的钌(0) - 烯烃络合物具有高纯度并且可以用作均相催化剂的前体,用于制备功能性的含钌或钌氧化物的层以及用于治疗应用。
    • 8. 发明申请
    • PROCESS FOR PREPARING RUTHENIUM(0)-OLEFIN COMPLEXES
    • 制备(0) - 烯烃复合物的方法
    • WO2011057780A2
    • 2011-05-19
    • PCT/EP2010/006858
    • 2010-11-11
    • UMICORE AG & CO. KGDOPPIU, AngelinoRIVAS-NASS, AndreasKARCH, RalfWINDE, RolandWOERNER, Eileen
    • DOPPIU, AngelinoRIVAS-NASS, AndreasKARCH, RalfWINDE, RolandWOERNER, Eileen
    • C07F15/00C23C16/18B01J31/00A61K31/28
    • C23C16/18A61K31/28B01J31/00
    • The present invention relates to a process for preparing ruthenium(0)-olefin complexes of the (arene)(diene)Ru(0) type by reacting a ruthenium starting compound of the formula Ru(+II)(X) p (Y) q (in which X = an anionic group, Y = an uncharged two-electron donor ligand, p = 1 or 2, q = an integer from 1 to 6), with a cyclohexadiene derivative or a diene mixture comprising a cyclohexadiene derivative, in the presence of a base. In this process, the arene bound in the (arene)(diene)Ru(0) complex is formed from this cyclohexadiene derivative by oxidation. Suitable ruthenium(II) starting compounds are, for example, RuCl 2 (acetonitrile) 4 , RuCl 2 (pyridine) 4 or RuCl 2 (DMSO) 4 . The bases used are inorganic or organic bases. The ruthenium(0)-olefin complexes prepared by the process according to the invention have a high purity and can be used as precursors for homogeneous catalysts, for preparation of functional ruthenium- or ruthenium oxide-containing layers and for therapeutic applications.
    • 本发明涉及一种制备(芳烃)(二烯)Ru(O)型钌(O) - 烯烃络合物的方法,通过使式钌(+ II)(X)p(Y) q(其中X =阴离子基团,Y =不带电荷的双电子供体配体,p = 1或2,q = 1至6的整数)与环己二烯衍生物或包含环己二烯衍生物的二烯混合物 一个基地的存在。 在该方法中,通过氧化由该环己二烯衍生物形成(芳烃)(二烯)Ru(O)络合物中的芳烃。 合适的钌(II)起始化合物是例如RuCl 2(乙腈)4,RuCl 2(吡啶)4或RuCl 2(DMSO)4。 使用的碱是无机或有机碱。 通过本发明方法制备的钌(O) - 烯烃络合物具有高纯度,可用作均相催化剂的前体,用于制备功能性含钌或氧化钌层并用于治疗应用。