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1. 发明申请

WO2005008786A3 USE OF CERIUM OXIDE MATERIALS FOR PHOTOVOLTAIC APPLICATIONS 审中-公开
标题翻译：用于光伏应用的氧化铈材料的使用
公开(公告)号：WO2005008786A3
公开(公告)日：2009-04-02
申请号：PCT/FR2004001818
申请日：2004-07-09
申请人： CONSEJO SUPERIOR INVESTIGACION , RHODIA CHIMIE SA , UNIV VALENCIA POLITECNICA , CHANE-CHING JEAN-YVES , CORMA AVELINO , GARCIA HERMENEGIDO
发明人： CHANE-CHING JEAN-YVES , CORMA AVELINO , GARCIA HERMENEGIDO
IPC分类号： H01G9/20
CPC分类号： H01G9/2036 , H01G9/2027 , Y02E10/542
摘要： The invention concerns the use of cerium oxide materials, as photovoltaic materials, and in particular the use of said materials for constituting photoreceptor electrodes for collecting current carriers in photovoltaic devices, in particular in solar cells. The invention also concerns said photovoltaic devices.
摘要翻译：本发明涉及作为光伏材料的氧化铈材料的使用，特别是所述材料用于构成感光体电极的用途，用于在太阳能电池中尤其在太阳能电池中收集电流载流子。本发明还涉及所述光伏器件。

2. 发明申请

WO2006125889A3 ORGANOSILICIUM COMPOUNDS AND RELATED PREPARATION METHOD 审中-公开
标题翻译：有机硅化合物及相关制备方法
公开(公告)号：WO2006125889A3
公开(公告)日：2007-01-25
申请号：PCT/FR2006001109
申请日：2006-05-17
申请人： RHODIA CHIMIE SA , STERIN SEBASTIEN
发明人： STERIN SEBASTIEN
IPC分类号： C07F7/18
CPC分类号： C07F7/1836 , C07F7/0854
摘要： The invention concerns synthesis of functionalized organosilicium compounds comprising at least one activated azo group of formula (I): [(G 0 ) 3 SiO 1/2 ] m [(G 0 ) 2 SiO 2/2 ] n [G 0 SiO 3/2 ] o [SiO 4/2 ] p [(G 2 ) a (G 1 ) a' (Z-CO-HN=NH-CO-A)SiO (3-a-a')/2 ]. Said compounds can for example be a mixture of silane species of formula (i a ): (C 2 H 5 O) 3 Si-(CH 2 ) 3 -NH-CO-N=N-COOC 2 H 3 ; with siloxane species of formulae: (2i.1 a ): [(CH 3 ) 3 SiO 1/2 ] [(C 2 H 5 O) 2 {(CH 2 ) 3 -NH-CO-N=N-COOC 2 H 5 } SiO 1/2 ] et (2i.2 a ): [(CH 3 ) 3 SiO 1/2 ] 2 [(C 2 H 5 O) {(CH 2 ) 3 -NH-CO-N=N-COOC 2 H 5 } SiO 2/2 ]. The invention also concerns the method for preparing said compounds (I), which consists in using at least one hydrazino precursor (II) (-HN-NH-) of compound (I), oxidizing the precursor (II) into an azo group for the compound (I) using at least one oxidizing agent (Ox) and at least one vase (B), said method consisting in selecting the base B among mineral bases and Ox among halogens, cyanurated compounds and chlorinated compounds and mixtures thereof, and in using a supplementary reagent selected among silanes (alone or mixed together) of formula (III): (G°) 4-p1 Si (G 2' ) p1 [or example, (CH 3 ) 3 (C 2 H 5 O)Si].
摘要翻译：本发明涉及包含至少一种式（I）活化的偶氮基团的官能化有机硅化合物的合成：[（G O）3 [（G 0）0 2 2 2 > [SiO 2] SiO 3/2/2 [SiO 4/2] p （Z-CO-HN = NH 2） -CO-A）SiO（3-a-a'）/ 2]。所述化合物可以例如是式（ⅰ）的硅烷物质的混合物：（C 2 H 5 O）3 SI-（CH _{2 ）_{3 -NH-CO-N = N-COOC _{2 ħ_{3 ; 具有下式的硅氧烷种类：（2i，1）：[（CH 3 3）3 SiO 1/2 1/2 ] [（C H O 5 N 2 -NH-CO-N = N-COOC 2 H 5 1/2/2＆lt; 1/2＆ a）（[（CH 3））3 2 2 [（C 2（H 2 O）3（-NH 2）3 -NH-CO-N = N-COOC 2> 2 5 2 2/2 本发明还涉及制备所述化合物（I）的方法，其包括使用至少一种化合物（I）的肼基前体（II）（-HN-NH-），将前体（II）氧化成偶氮基团使用至少一种氧化剂（Ox）和至少一个花瓶（B）的化合物（I），所述方法包括在卤素，氰化合物和氯化化合物及其混合物中选择矿物碱中的碱B和Ox，并且使用选自式（III）的硅烷（单独或混合在一起）的补充试剂：（G°）4-p1 Si（G 2）2 p1 （例如，（CH 3）3）（C 2 H 5 O）Si] 。}}}}

3. 发明申请

WO2007000514A2 GAS PROCESSING METHOD FOR CATALYTICALLY OXIDISING CARBON MONOXIDE AND HYDROCARBONS USING A COMPOUND BASED ON A METAL AND A SILICA-CONTAINING ZIRCONIA 审中-公开
标题翻译：使用基于金属和含二氧化硅的ZIRCONIA的化合物催化氧化一氧化碳和碳氢化合物的气体加工方法
公开(公告)号：WO2007000514A2
公开(公告)日：2007-01-04
申请号：PCT/FR2006001491
申请日：2006-06-27
申请人： RHODIA CHIMIE SA , ROHART EMMANUEL , VERDIER STEPHAN , HUANG AIMIN
发明人： ROHART EMMANUEL , VERDIER STEPHAN , HUANG AIMIN
IPC分类号： B01D53/94
CPC分类号： B01D53/944 , B01D2255/102 , B01D2255/206 , B01D2255/20715 , B01D2255/30 , B01D2257/502 , B01D2257/702 , B01J21/066 , B01J23/10 , B01J23/42 , B01J23/63 , B01J37/03 , B01J37/036 , Y02A50/2341
摘要： The invention relates to a gas processing method, in particular the exhaust gas of an internal combustion engine, for catalytically oxidising a carbon monoxide and hydrocarbons contained therein into an oxygen-rich medium, wherein said method consists in using a compound based on an oxidation catalyst metal such as a platinum and a silica-containing zirconia in the form of a catalyst. The inventive method is particularly suitable for processing exhaust gases of a diesel engine or a petrol lean mixture operating engine.
摘要翻译：本发明涉及一种气体处理方法，特别是内燃机的废气，用于将一氧化碳和其中所含的烃催化氧化成富氧介质，其中所述方法包括使用基于氧化催化剂的化合物金属，如催化剂形式的铂和二氧化硅的氧化锆。本发明的方法特别适用于处理柴油发动机或汽油稀混合操作发动机的废气。

4. 发明申请

WO2006072704A3 USE OF SPECIFIC SILICAS FOR INCREASING THE RIGIDITY OF A THERMOPLASTIC WHILE MAINTAINING OR IMPROVING ITS IMPACT RESISTANCE 审中-公开
标题翻译：使用特定的硅树脂来提高热塑性塑料的韧性，同时保持或提高其抗冲击性
公开(公告)号：WO2006072704A3
公开(公告)日：2006-09-28
申请号：PCT/FR2005003289
申请日：2005-12-27
申请人： RHODIA CHIMIE SA , BOMAL YVES , GUIU ANTOINE
发明人： BOMAL YVES , GUIU ANTOINE
IPC分类号： C08K3/36 , C08J3/20 , C08L23/12
CPC分类号： C08K3/36 , C08L23/12 , Y10T428/2982
摘要： The invention relates to the use of a silica having a BET specific surface of at least 60 m 2 /g for increasing the rigidity of a thermoplastic polymeric material while maintaining i.e. improving its impact resistance. The silica used is of the type obtained according to a method involving the drying of a silica suspension obtained by reacting a silicate with an acidulant according to the following successive steps: (i) forming an aqueous starter having a pH between 2 and 5; (ii) simultaneously adding silicate and the acidulant while keeping the pH between 2 and 5; (iii) continuing with only the addition of silicate until a pH between 7 and 10 has been reached; (iv) simultaneously adding silicate and acidulant while keeping the pH of the reaction medium between 7 and 10, and; (v) continuing with only the addition of the acidulant until a pH value lower than 6 has been obtained. The invention also relates to the materials obtained within this scope.
摘要翻译：本发明涉及具有至少60m 2 / g / g的BET比表面的二氧化硅用于增加热塑性聚合物材料的刚性同时保持即提高其抗冲击性的用途。所使用的二氧化硅是根据涉及通过硅酸盐与酸化剂反应而获得的二氧化硅悬浮液的干燥的方法获得的类型，所述二氧化硅悬浮液根据以下连续步骤：（i）形成具有2至5的pH的水性起始剂; （ii）同时加入硅酸盐和酸化剂，同时保持pH在2和5之间; （iii）继续仅加入硅酸盐直至pH达到7至10; （iv）同时加入硅酸盐和酸化剂，同时保持反应介质的pH在7和10之间; （v）仅继续添加酸化剂直至pH值低于6。本发明还涉及在该范围内获得的材料。

5. 发明申请

WO2006066922A2 ELASTOMERIC COMPOSITION COMPRISING FUNCTIONALIZED BUTADIENIC ELASTOMERS AND HIGH DISPERSIBLE ALUMINIUM-BASED SILICA 审中-公开
标题翻译：包含功能化丁二烯弹性体和高分散性铝基二氧化硅的弹性体组合物
公开(公告)号：WO2006066922A2
公开(公告)日：2006-06-29
申请号：PCT/EP2005013885
申请日：2005-12-22
申请人： RHODIA CHIMIE SA , JSR CORP , COCHET PHILIPPE , PETIT DOMINIQUE , TADAKI TOSHIHIRO , KOBAYASHI NAOKAZU
发明人： COCHET PHILIPPE , PETIT DOMINIQUE , TADAKI TOSHIHIRO , KOBAYASHI NAOKAZU
IPC分类号： C08L9/06 , B60C1/00 , C08K3/36 , C08L19/00
CPC分类号： C08K9/02 , C08K3/36 , C08K13/04 , C08L9/00 , C08L19/006 , C08L9/06 , C08L2666/08
摘要： The instant invention relates to elastomeric compositions especially useful for manufacturing articles for tires which comprise: (1) at least one butadienic elastomer E, containing a functionalized butadienic elastomer prepared in solution, and modified by a polyfunctional alkoxy silane coupling agent; and (2) a specific precipitated silica having high dispersibility properties and containing aluminium, as at least one reinforcing filler in said butadienic elastomer.
摘要翻译：本发明涉及特别适用于制造轮胎制品的弹性体组合物，该组合物包含：（1）至少一种丁二烯系弹性体E，其含有在溶液中制备并用多官能烷氧基硅烷偶联剂改性的官能化丁二烯系弹性体; 和（2）具有高分散性和含铝的特定沉淀二氧化硅作为所述丁二烯弹性体中的至少一种增强填料。

6. 发明申请

WO2006045916A3 PREPARATION OF FUNCTIONALISED SILANES AND SILICONES BY MEANS OF ENZYMATIC CATALYSIS 审中-公开
标题翻译：通过酶催化法制备功能性硅烷和硅
公开(公告)号：WO2006045916A3
公开(公告)日：2006-06-22
申请号：PCT/FR2005002546
申请日：2005-10-14
申请人： RHODIA CHIMIE SA , FLEURY ETIENNE , GAMBUT LUCILE , GELO-PUJIC MIRJANA
发明人： FLEURY ETIENNE , GAMBUT LUCILE , GELO-PUJIC MIRJANA
IPC分类号： C08G77/38 , C07F7/18 , C08G77/08 , C12P1/00 , C12P9/00
CPC分类号： C08G77/38 , C07F7/0889 , C08G77/08
摘要： The invention relates to a method of preparing a monomer, an oligomer, a polymer or a copolymer of an organosiloxane or a functionalised silane (A), comprising the following steps consisting in: a) reacting at least one monomer, oligomer, polymer or copolymer of an organosiloxane or a silane (B) bearing at least one reactive group (Y) containing at least one epoxy function (Ep) with a nucleophile bearing at least one function (Nu) that can react with an epoxy function (Ep) in the presence of at least one enzyme that catalyses the nucleophilic opening of epoxy function(s) and, optionally, in the presence of a polymerisation inhibitor; and b) isolating the product (A).
摘要翻译：本发明涉及一种制备有机硅氧烷或官能化硅烷（A）的单体，低聚物，聚合物或共聚物的方法，包括以下步骤：a）使至少一种单体，低聚物，聚合物或共聚物的有机硅氧烷或含有至少一个含至少一个具有至少一个环氧官能团（Ep）的反应性基团（Y）的硅烷（B），具有至少一个可与环氧官能团（Ep）反应的至少一个功能（Nu）的亲核试剂存在至少一种催化环氧官能团的亲核性开口的酶，以及任选的在聚合抑制剂存在下的酶; 和b）分离产物（A）。

7. 发明申请

WO2006008368A3 COSMETIC COMPOSITION COMPRISING POLYORGANOSILOXANE AND USES THEREOF 审中-公开
标题翻译：包含聚硅氧烷的化妆品组合物及其用途
公开(公告)号：WO2006008368A3
公开(公告)日：2006-05-04
申请号：PCT/FR2005001490
申请日：2005-06-15
申请人： RHODIA CHIMIE SA , MANUSZAK MELISSA , LORENTZ GILLES
发明人： MANUSZAK MELISSA , LORENTZ GILLES
IPC分类号： A61K8/895 , A61K8/898 , A61Q5/00 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00
CPC分类号： A61K8/898 , A61Q3/00 , A61Q5/004 , A61Q5/02 , A61Q5/12 , A61Q17/04 , A61Q19/00
摘要： The invention relates to a cosmetic composition comprising a cosmetically acceptable vector and polyorganosiloxane. The polyorganosiloxane comprises a group that includes a sterically hindered amine.
摘要翻译：本发明涉及包含美容上可接受的载体和聚有机硅氧烷的化妆品组合物。聚有机硅氧烷包括包含空间位阻胺的基团。

8. 发明申请

WO2005058922A2 METHOD FOR PRODUCING ORGANO ALCOXYDIALKYLSILANE 审中-公开
标题翻译：生产有机酰氧基二烷基硅烷的方法
公开(公告)号：WO2005058922A2
公开(公告)日：2005-06-30
申请号：PCT/FR2004003185
申请日：2004-12-10
申请人： RHODIA CHIMIE SA , PEVERE VIRGINIE , RAMDANI KAMEL
发明人： PEVERE VIRGINIE , RAMDANI KAMEL
IPC分类号： C07F7/18
CPC分类号： C07F7/1892
摘要： The invention relates to producing an organo alcoxydialkylsilane by a method which consists in introducing by pouring an alcanol in a dialkylhalogenosilane omega-halogenalkyl + an organic solvent (s) phase mixture and in removing a halogen acid formed by entrainment with the aid of said organic solvent(s) phase and is characterised, in particular (i) by selecting a particular phase of solvent(s), for example based on cyclohexane, (2i) by carrying out an alcanol introduction mode which makes it possible to control the drawing off the halogen acid formed during reaction and by (3i) controlling the halogen acid quantity in a reaction medium. The thus obtained dialkylhalogenosilane omega-halogenalkyl is usable, in particular as an initial product for preparing organosilisic sulphur-containing compounds of general formula (IV) by a sulfidising reaction carried out on a alkali metal polysulfur.
摘要翻译：本发明涉及通过以下方法生产有机烷氧基二烷基硅烷，所述方法包括通过将烷醇胺（alkanohalogenosilane）ω-卤代烷基ω-卤代烷基酯+有机溶剂（一种或多种）相混合物中注入烷醇并且借助于所述有机溶剂除去通过夹带形成的卤素酸其特征在于，（i）通过选择例如基于环己烷的溶剂的特定相，（2i）通过实施烷醇引入模式，该模式使得能够控制（3i）控制反应介质中的卤素酸量。由此获得的二烷基卤代硅烷ω-卤代烷基尤其可以用作通过在碱金属多硫上进行硫化反应来制备通式（IV）的有机硅含硫化合物的初始产物。

9. 发明申请

WO2005023731A3 METHOD FOR FORMING A CARBON-CARBON OR CARBON-HETEROATOM BOND 审中-公开
标题翻译：形成碳碳或碳 - 杂环键的方法
公开(公告)号：WO2005023731A3
公开(公告)日：2005-05-12
申请号：PCT/FR2004002021
申请日：2004-07-28
申请人： RHODIA CHIMIE SA , SPINDLER JEAN-FRANCIS , TAILLEFER MARC , CRISTAU HENRI-JEAN , CELLIER PASCAL PHILIPPE , OUALI ARMELLE
发明人： SPINDLER JEAN-FRANCIS , TAILLEFER MARC , CRISTAU HENRI-JEAN , CELLIER PASCAL PHILIPPE , OUALI ARMELLE
IPC分类号： C07B37/04 , C07B41/04 , C07B41/08 , C07B41/12 , C07B43/06 , C07C41/16 , C07C67/04 , C07C67/343 , C07D231/12
CPC分类号： C07D231/12 , C07B37/04 , C07B41/04 , C07C41/16 , C07C67/343 , C07C69/612 , C07C43/275
摘要： The invention relates to a method for forming a carbon-carbon or carbon-heteroatom bond by reacting an unsaturated compound carrying a leaving group and a nucleophilic compound, in the absence of a ligand. The aim of the invention is especially to form carbon-nitrogen bonds according to a method for the arylation of nitrogenated organic derivatives. According to the inventive method, a carbon-carbon or carbon-heteroatom bond is formed by reacting an unsaturated compound carrying a leaving group with a nucleophilic compound donating a carbon atom or a heteroatom (HE) that can substitute the leaving group, thus forming a C-C or C-HE bond, in the presence of a copper-based catalyst and a base. Said metal is characterised in that the reaction takes place in the absence of a ligand and in a nitrile-type solvent.
摘要翻译：本发明涉及通过在不存在配体的情况下使带有离去基团的不饱和化合物与亲核化合物反应形成碳 - 碳或碳 - 杂原子键的方法。本发明的目的尤其是根据氮化有机衍生物的芳基化方法形成碳 - 氮键。根据本发明的方法，通过使带有离去基团的不饱和化合物与赋予碳原子的亲核化合物或可以代替离去基团的杂原子（HE）反应形成碳 - 碳或碳 - 杂原子键，从而形成 CC或C-HE键，在铜基催化剂和碱的存在下进行。所述金属的特征在于反应在不存在配体的情况下和腈类溶剂中进行。

10. 发明申请

WO2005003041A2 COMPOSITIONS COMPRISING STABILISED SOLUTIONS OF ALUMINIUM POLYCHLORIDE AND IRON SALT FOR THE TREATMENT OF AQUEOUS EFFLUENTS 审中-公开
标题翻译：包含用于处理水溶液的聚氯乙烯和铁盐的稳定溶液的组合物
公开(公告)号：WO2005003041A2
公开(公告)日：2005-01-13
申请号：PCT/FR2004001472
申请日：2004-06-11
申请人： RHODIA CHIMIE SA , FAVREAU VINCENT , PESCHER YVETTE
发明人： FAVREAU VINCENT , PESCHER YVETTE
IPC分类号： B01F17/00 , C01F7/00 , C01G49/00 , C02F1/52 , C02F1/56
CPC分类号： C02F1/56 , B01F17/005 , C01F7/007 , C01G49/00 , C02F1/5245 , C02F2303/02
摘要： The invention relates to stable liquid compositions comprising, in solution, a mixture of aluminium polychloride and an iron salt, the solution stabilised by the presence of a cationic polyelectrolyte, such as for example, a polymer with quaternary ammonium groups. The invention further relates to a method for production of said compositions and the use thereof for the treatment of aqueous media, in particular, for elimination or reduction of odours from aqueous effluents such as the residual water from sewage plants.
摘要翻译：本发明涉及在溶液中包含多氯化铝和铁盐的混合物的稳定液体组合物，所述溶液通过阳离子聚电解质（例如具有季铵基团的聚合物）的存在而稳定。本发明还涉及用于生产所述组合物的方法及其用于处理水性介质的用途，特别是用于从诸如来自污水处理厂的残余水的水性流出物中除去或降低气味。

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