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    • 6. 发明申请
    • PROCESS FOR THE PRODUCTION OF AQUEOUS BINDER LATICES
    • 生产水性粘合剂的方法
    • WO2008124141A1
    • 2008-10-16
    • PCT/US2008/004527
    • 2008-04-07
    • E. I. DU PONT DE NEMOURS AND COMPANYRENKES, TanjaTESSARI, FrankBARRERE, Matthieu
    • RENKES, TanjaTESSARI, FrankBARRERE, Matthieu
    • C08F257/02C08F265/00C08F265/02C08F265/04C08F265/06C08F291/00C08L51/00C09D151/00
    • C08F257/02C08F265/00C08F265/02C08F265/04C08F265/06C08F291/00C08L51/00C09D151/00
    • A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt%, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt%, wherein mixture A and/or the at least one mixture B comprise at least one aromatic monomer in a total proportion of 10 to 50 wt.-% relative to the sum of the weights of mixtures A and B, wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt.% of the monomers of mixture A have been polymerized to completion.
    • 一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法,包括以下连续步骤:1)包含酸性单体的单体混合物A的自由基聚合,其比例对应于酸值为10-100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量%,2)中和工艺步骤1)中形成的聚合物的酸基和3)至少一种包含酸性单体的单体混合物B的自由基聚合 以对应于0至低于5mg KOH / g的混合物B的酸值的比例,羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和0.5-5重量%的烯属多不饱和单体,其中混合物A和/或至少一种混合物B包含至少一种芳族单体,总比例为10至50重量%,相对于 总和的重量 的混合物A和B,其中混合物A与至少一种混合物B的重量比为15:85至85:15,并且其中在工艺步骤2)中不开始中和,直到至少90重量%的 混合物A的单体已经聚合完成。
    • 8. 发明申请
    • NON-AQUEOUS, LIQUID COATING COMPOSITIONS CURABLE BY FREE-RADICAL POLYMERIZATION OF OLEFINIC DOUBLE BONDS
    • 非水性,液体涂料组合物可通过自由基聚合烯烃双酚
    • WO2007092399A1
    • 2007-08-16
    • PCT/US2007/003067
    • 2007-02-06
    • E. I. DU PONT DE NEMOURS AND COMPANYFLOSBACH, CarmenRENKES, Tanja
    • FLOSBACH, CarmenRENKES, Tanja
    • C09D4/00C09D175/00
    • C09D4/00C08G18/3206C08G18/3212C08G18/722C08G18/792C08G18/8175C08G2150/20
    • Non-aqueous, liquid coating compositions curable by free-radical polymerization of olefinic double bonds with a resin solids content consisting of 50 to 100 wt.% of a binder solids content curable by free-radical polymerization of olefinic double bonds, 0 to 30 wt.% of one or more crosslinking agents C and 0 to 50 wt.% of one or more components D, wherein the weight percentages add up to 100 wt.%, wherein the binder solids content consists of above 95 wt.% to 99.5 wt.% of one or more components A curable by free-radical polymerization of olefinic double bonds and 0.5 to below 5 wt.% of one or more polyurethane resins B curable by free-radical polymerization of olefinic double bonds, wherein the weight percentages of the at least one component A and the at least one polyurethane resin B add up to 100 wt.%, wherein the at least one component A is liquid and/or is present in dissolved form and wherein the at least one polyurethane resin B is present as particles having a melting temperature of 40 to 160°C.
    • 通过烯属双键的自由基聚合可固化的非水性液体涂料组合物,其中树脂固体含量由50-100重量%的通过烯属双键的自由基聚合可固化的粘合剂固体含量,0-30重量% %的一种或多种交联剂C和0至50重量%的一种或多种组分D,其中重量百分比加起来为100重量%,其中粘合剂固体含量由高于95重量%至99.5重量% 。通过烯属双键的自由基聚合可固化的一种或多种组分A%和0.5至低于5重量%的通过烯属双键的自由基聚合固化的一种或多种聚氨酯树脂B,其中重量百分数 至少一种组分A和至少一种聚氨酯树脂B合计为100重量%,其中至少一种组分A是液体和/或以溶解形式存在,并且其中至少一种聚氨酯树脂B以 具有熔融温度的颗粒 重量为40至160°C。
    • 9. 发明申请
    • PROCESS FOR THE PRODUCTION OF AQUEOUS BINDER LATICES
    • 生产水性粘合剂的方法
    • WO2008124137A1
    • 2008-10-16
    • PCT/US2008/004520
    • 2008-04-07
    • E. I. DU PONT DE NEMOURS AND COMPANYRENKES, TanjaTESSARI, FrankBARRERE, Matthieu
    • RENKES, TanjaTESSARI, FrankBARRERE, Matthieu
    • C08F265/00C08F265/02C08F265/04C08F265/06C08F257/02C08F291/00C08F283/10C08L51/00C09D151/00C08F2/22
    • C08F2/22C08F2/001C08F220/14C08F257/02C08F265/00C08F265/04C08F291/00C08L51/003C09D151/003C08L2666/02C08F2220/1825C08F220/20C08F220/06C08F220/40C08F2220/325C08F212/08
    • A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt%, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt%, wherein the monomer composition of mixtures A and B is selected in such a manner that the calculated glass transition temperature (Tg) of a copolymer composed of a combination of only the olefinically monounsaturated monomers of mixtures A and B is in the range from 30 to 100 °C, wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt.% of the monomers of mixture A have been polymerized to completion.
    • 一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法,包括以下连续步骤:1)包含酸性单体的单体混合物A的自由基聚合,其比例对应于酸值为10-100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量%,2)中和工艺步骤1)中形成的聚合物的酸基和3)至少一种包含酸性单体的单体混合物B的自由基聚合 以对应于0至低于5mg KOH / g的混合物B的酸值的比例,羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和烯属多不饱和单体的比例为0.5-5重量%,其中混合物A和B的单体组成选择为使得由以下组成的共聚物的计算的玻璃化转变温度(Tg) 混合物A和B仅烯烃单不饱和单体的组合在30至100℃的范围内,其中混合物A与至少一种混合物B的重量比为15:85至85:15,其中中和 直到至少90重量%的混合物A的单体已经聚合完成,才在工艺步骤2)中开始。
    • 10. 发明申请
    • PROCESS FOR THE PRODUCTION OF AQUEOUS BINDER LATICES
    • 生产水性粘合剂的方法
    • WO2008124136A1
    • 2008-10-16
    • PCT/US2008/004519
    • 2008-04-07
    • E. I. DU PONT DE NEMOURS AND COMPANYRENKES, TanjaTESSARI, FrankBARRERE, Matthieu
    • RENKES, TanjaTESSARI, FrankBARRERE, Matthieu
    • C08F265/10C08F265/04C08F265/06C08F265/02C08F257/02C08F283/10C09D151/00C08L51/00C08F2/00
    • C08F265/04C08F257/02C08F265/00C08F265/02C08F265/06C08F283/10C08L51/00C09D151/00
    • A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt%, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt%, wherein mixture A and/or the at least one mixture B comprise at least one epoxy-functional, olefinically monounsaturated, free-radically polymerizable monomer in a total proportion of 2 to 20 wt.-% relative to the sum of the weights of mixtures A and B, wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt.% of the monomers of mixture A have been polymerized to completion.
    • 一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法,包括以下连续步骤:1)包含酸性单体的单体混合物A的自由基聚合,其比例对应于酸值为10-100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量%,2)中和工艺步骤1)中形成的聚合物的酸基和3)至少一种包含酸性单体的单体混合物B的自由基聚合 以对应于0至低于5mg KOH / g的混合物B的酸值的比例,羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和烯属多不饱和单体,其比例为0.5-5重量%,其中混合物A和/或至少一个混合物B包含至少一种环氧官能的烯属单不饱和的可自由基聚合的单体 总比例为2至20重量%,相对于混合物A和B的重量之和,其中混合物A与至少一种混合物B的重量比为15:85至85:15,其中中和 直到至少90重量%的混合物A的单体已经聚合完成,才在工艺步骤2)中开始。