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    • 2. 发明申请
    • A PROCESS FOR THE PRODUCTION OF POTASSIUM NITRATE
    • 一种生产硝酸钾的方法
    • WO0177019A3
    • 2002-02-07
    • PCT/IL0100327
    • 2001-04-05
    • NUTRITION AND GROWTH LTDPIPKO GREGORY
    • PIPKO GREGORY
    • C01D9/04C01D9/12
    • C01D9/04C01D9/12
    • A method for the production of potassium nitrate by its salting out from an aqueous solution comprising the ions K , C1 , M and NO3 wherein M represents Ca and/or Mg , comprising the following steps; (a) dissolving at least one mineral selected from the group consisting of calcium carbobate, magnesium carbonate, magnesium oxide, calcium oxide, calcium hydroxide, magnesium hydroxide and dolomite, in aqueous nitric acid, in an amount which is approximately stoichiometrically equivalent to the amount of nitrate ions in the solution, or dissolving at least one mineral selected from the group consisting of calcium nitrate and magnesium nitrate, in water; (b) dissolving at least one source for potassium chloride, in the solution obtained at step (a) at temperature higher than 40 DEG C, wherein the amount of the source is chosen such as to obtain an approximately stoichiometric ratio between potassium and nitrate ions and wherein the source is selected from the group consisting of KC1, carnallite, sylvinite, and a mixture of KC1 with MgC12, NaC1, CaC12 or a combination thereof; (c) cooling the solution obtained at step (b) to obtain a precipitate of potassium nitrate.
    • 通过从包含离子K +,C 1,M +和NO 3 - 的水溶液中的盐析产生硝酸钾的方法,其中M ++表示Ca ++ 和/或Mg ++,包括以下步骤: (a)在硝酸水溶液中溶解至少一种选自碳酸钙,碳酸镁,氧化镁,氧化钙,氢氧化钙,氢氧化镁和白云石的矿物,其量约等于化学计量的量 或将至少一种选自硝酸钙和硝酸镁的矿物溶解在水中; (b)在高于40℃的温度下将至少一种氯化钾源溶解在步骤(a)获得的溶液中,其中选择源的量以获得钾和硝酸根离子之间的近似化学计量比 并且其中所述源选自KCl,光卤石,硅镁石,和KCl与MgCl 2,NaCl,CaCl 2或它们的组合的混合物; (c)冷却步骤(b)获得的溶液,得到硝酸钾沉淀物。