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1. 发明申请

WO2005115704A2 COMPOSITION FOR WOOD TREATMENT COMPRISING AN INJECTABLE AQUEOUS WOOD PRESERVATIVE SLURRY HAVING SPARINGLY-SOLUBLE BIOCIDAL PARTICLES AND PIGMENTS 审中-公开
标题翻译：用于木材处理的组合物包含具有可分散的生物活性颗粒和颜料的可注入的水性木质防腐浆料
公开(公告)号：WO2005115704A2
公开(公告)日：2005-12-08
申请号：PCT/US2005017008
申请日：2005-05-17
申请人： PHIBRO TECH INC , RICHARDSON WAYNE H , HODGE RICHARD L , GLOVER DWIGHT W , POMPEO MICHAEL P , HAYDEN CHRISTOPHER G
发明人： RICHARDSON WAYNE H , HODGE RICHARD L , GLOVER DWIGHT W , POMPEO MICHAEL P , HAYDEN CHRISTOPHER G
IPC分类号： A01N59/20 , B27K3/00 , B27K3/08
CPC分类号： A01N59/20 , B27K3/005 , B27K3/08 , B27K3/22 , B27K3/52 , A01N59/26 , A01N59/16 , A01N59/14 , A01N53/00 , A01N51/00 , A01N47/38 , A01N47/22 , A01N47/12 , A01N47/02 , A01N43/653 , A01N43/42 , A01N37/34 , A01N25/08 , A01N25/04 , A01N2300/00
摘要： An aqueous wood-injectable particulate-based wood preservative comprising: 1) dispersants in an amount sufficient to maintain biocidal particles in a stable slurry; 2) injectable sub-micron biocidal particles comprising a solid phase of at least one of a sparingly soluble organic biocide, a sparingly soluble copper salt, copper(I)oxide, a sparingly soluble zinc salt, zinc oxide; a sparingly soluble nickel salt; and a sparingly soluble tin salt, wherein less than 2% by weight of the biocidal particles have an average diameter greater than 1 micron, and at least 20% by weight of the biocidal particles have an average diameter greater than 0.08 microns; and 3) at least one pigment particle or dye in an amount sufficient to impart a discernable color or hue to the wood, when compared to wood treated with the same particulate system but without the pigment.
摘要翻译：一种含木质木材可注射的颗粒状木材防腐剂，其包含：1）足够的量的分散剂，以将杀生物颗粒保持在稳定的浆料中; 2）可注射的亚微米杀生物颗粒，其包含微溶于有机杀生物剂，微溶铜盐，氧化铜（I），微溶锌盐，氧化锌中的至少一种的固相; 一种微溶的镍盐; 和小溶剂的锡盐，其中小于2重量％的杀生物颗粒的平均直径大于1微米，并且至少20重量％的杀生物颗粒的平均直径大于0.08微米; 和3）至少一种颜料颗粒或染料，其量足以赋予木材可辨别的颜色或色调，与用相同颗粒系统处理但不含颜料的木材相比较。

2. 发明申请

WO2005110692A3 COMPOSITION, METHOD OF MAKING, AND TREATMENT OF WOOD WITH AN INJECTABLE WOOD PRESERVATIVE SLURRY HAVING BIOCIDAL PARTICLES 审中-公开
标题翻译：含有杀菌颗粒的可注射木材防腐剂浆料的组合物，制造方法和处理木材
公开(公告)号：WO2005110692A3
公开(公告)日：2006-08-03
申请号：PCT/US2005017007
申请日：2005-05-17
申请人： PHIBRO TECH INC , RICHARDSON WAYNE H , HODGE RICHARD L , GLOVER DWIGHT W , POMPEO MICHAEL P , HAYDEN CHRISTOPHER G
发明人： RICHARDSON WAYNE H , HODGE RICHARD L , GLOVER DWIGHT W , POMPEO MICHAEL P , HAYDEN CHRISTOPHER G
IPC分类号： B27K3/08 , A01N25/04 , A01N25/14 , A01N25/26 , A01N59/20 , B27K3/00
CPC分类号： A01N59/20 , B27K3/005 , B27K3/08 , B27K3/22 , B27K3/52 , A01N59/26 , A01N59/16 , A01N59/14 , A01N53/00 , A01N51/00 , A01N47/38 , A01N47/22 , A01N47/12 , A01N47/02 , A01N43/653 , A01N43/42 , A01N37/34 , A01N25/08 , A01N25/04 , A01N2300/00
摘要： A method of preserving wood includes injecting into the wood an effective amount of a aqueous wood-injectable biocidal slurry, said a wood-injectable biocidal slurry containing dispersants and sub-micron biocidal particles selected from at least one of the following classes: 1) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble salts selected from copper salts, nickel salts, tin salts, and/or zinc salts; 2) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble metal hydroxides selected from copper hydroxide, nickel hydroxide, tin hydroxide, and/or zinc hydroxide; 3) a plurality of particles containing at least 25% by weight of a solid phase comprising a substantially-insoluble organic biocide selected from triazoles, chlorothalonil, iodo-propynyl butyl carbamate, copper-8-quinolate, fipronil, imidacloprid, bifenthrin, carbaryl, strobulurins, and indoxacarb; 4) a plurality of particles containing on the outer surface thereof a substantially-insoluble organic biocide; 5) a plurality of particles containing a solid phase of a biocidal, partially or fully glassified composition comprising at least one of Zn, B, Cu, and P. The particles may advantageously contain metallic copper, a leachability barrier, pigments, dyes, or other adjuvants disposed on the outer surface thereof.
摘要翻译：保存木材的方法包括向木材中注入有效量的水性木材可注射的生物杀伤剂浆液，所述可注射木材的生物杀伤剂浆液含有分散剂和选自以下类别中的至少一种的亚微米杀生物剂颗粒：1）a 包含至少25重量％的选自铜盐，镍盐，锡盐和/或锌盐的微溶盐的固相的多个颗粒; 2）包含至少25重量％的选自氢氧化铜，氢氧化镍，氢氧化锡和/或氢氧化锌的微溶金属氢氧化物的固相的多个颗粒; 3）包含至少25重量％固体相的多个颗粒，所述固体相包含选自三唑，百菌清，碘代丙炔基丁基氨基甲酸酯，铜-8-喹啉酸盐，氟虫腈，吡虫啉，联苯菊酯，西维因， strobulurins和茚虫威; 4）多个在其外表面上含有基本上不溶的有机杀生物剂的颗粒; 5）多个含有生物杀伤性，部分或完全玻璃化组合物的固相的颗粒，所述组合物包含Zn，B，Cu和P中的至少一种。所述颗粒可以有利地含有金属铜，可滤出性阻挡层，颜料，染料或其他佐剂置于其外表面上。

3. 发明申请

WO2006042128A3 TREATMENT OF WOOD WITH AN INJECTABLE WOOD PRESERVATIVE SLURRY HAVING BIOCIDAL PARTICLES 审中-公开
标题翻译：用具有生物体颗粒的可注射的木材防腐浆料处理木材
公开(公告)号：WO2006042128A3
公开(公告)日：2006-06-01
申请号：PCT/US2005036192
申请日：2005-10-07
申请人： PHIBRO TECH INC , RICHARDSON WAYNE H , HODGE ROBERT L
发明人： RICHARDSON WAYNE H , HODGE ROBERT L
IPC分类号： B27K3/08 , A01N25/04 , A01N25/14 , A01N25/26 , B27K3/22 , B27K3/52 , C09D5/14 , C09D5/16 , C09D7/12
CPC分类号： A01N59/20 , A01N25/00 , A01N25/02 , A01N25/04 , A01N25/08 , A01N25/12 , A01N29/10 , A01N31/08 , A01N31/14 , A01N33/00 , A01N33/26 , A01N43/00 , A01N57/00 , A01N57/06 , A01N57/10 , A01N57/14 , A01N57/16 , A01N59/00 , A01N59/16 , B27K3/005 , B27K3/08 , B27K3/22 , B27K3/52 , C08K3/22 , C08K9/02 , C09D5/14 , C09D5/1618 , C09D7/62 , C09D7/67 , C09D7/68 , Y10T428/31989 , A01N59/14 , A01N25/34 , A01N25/26 , A01N2300/00
摘要： A wood preservative includes injectable particles comprising one or more sparingly soluble copper salts. The copper-based particles are sufficiently insoluble so as to not be easily removed by leaching but are sufficiently soluble to exhibit toxicity to primary organisms primarily responsible for the decay of the wood. Exemplary particles contain for example copper hydroxide, basic copper carbonate, copper carbonate, basic copper sulfates including particularly tribasic copper sulfate, basic copper nitrates, copper oxychlorides , copper borates, basic copper borates, and mixtures thereof. The particles typically have a size distribution in which at least 50% of particles have a diameter smaller than 0.25 µm, 0.2 µm, or 0.15 µm. At least about 20% and even more than 75% of the weight of the particles may be composed of the substantially crystalline copper salt. Wood or a wood product may be impregnated with copper-based particles of the invention.
摘要翻译：木材防腐剂包括含有一种或多种微溶铜盐的可注射颗粒。铜基颗粒是足够不溶的，以便通过浸出不容易除去，但足够溶解以对主要负责木材腐烂的原生生物表现出毒性。示例性颗粒包含例如氢氧化铜，碱式碳酸铜，碳酸铜，碱式硫酸铜，特别是三硫酸铜，碱式硝酸铜，氯氧化铜，铜硼酸盐，碱式硼酸铜及其混合物。颗粒通常具有尺寸分布，其中至少50％的颗粒具有小于0.25μm，0.2μm或0.15μm的直径。至少约20％，甚至超过75％的颗粒重量可以由基本上结晶的铜盐组成。木材或木制品可以用本发明的铜基颗粒浸渍。

4. 发明申请

WO2006042129A1 GROUND SUBMICRON CHLOROTHALONIL AND USES THEREOF 审中-公开
标题翻译：地下盐酸氯龙胆及其用途
公开(公告)号：WO2006042129A1
公开(公告)日：2006-04-20
申请号：PCT/US2005/036193
申请日：2005-10-07
申请人： PHIBRO-TECH, INC. , RICHARDSON, Wayne, H. , HODGE, Robert, L.
发明人： RICHARDSON, Wayne, H. , HODGE, Robert, L.
IPC分类号： A01N25/12 , B27K3/34 , B27K3/52
CPC分类号： A01N25/12 , B27K3/005 , B27K3/22 , B27K3/34 , B27K3/52 , A01N59/20 , A01N37/34
摘要： A method of milling substantially insoluble solid organic biocides to form a micron or sub-micron product having a narrow particle size distribution is presented. The milling involves wet milling of the organic biocide with high density milling media having a diameter between 0.1 mm and 0.8 mm, preferably between 0.2 mm and 0.7 mm, and a density equal to or greater than 3.8 g/cc, preferably greater than 5.5 g/cc, in a ball mill using between about 40% and 80% loading of the mill volume with milling media, and having the organic biocide suspended in an aqueous milling liquid which comprises one or more surface active agents. The milling speed is preferably high, for example from about 1000 rpm to about 4000 rpm. The milled product can be used in foliar applications at a lower effective dosage than prior art formulations, can be used in improved antifouling paint formulations, and can be used in new applications such as the direct injection of solid organic biocide particulates in wood to act as a long lasting wood preservative.
摘要翻译：提出了一种研磨基本上不溶的固体有机杀生物剂以形成具有窄粒度分布的微米或亚微米级产品的方法。研磨涉及使用直径在0.1mm至0.8mm之间，优选在0.2mm至0.7mm之间的高密度研磨介质和等于或大于3.8g / cc，优选大于5.5g的密度的有机杀生物剂的湿法研磨 / cc，在研磨介质中使用约40％至80％的研磨体积的载体，并且将有机杀生物剂悬浮在含有一种或多种表面活性剂的水性研磨液中的球磨机中。研磨速度优选为高，例如约1000rpm至约4000rpm。研磨产品可以以比现有技术制剂低的有效剂量使用在叶面应用中，可用于改进的防污涂料配方中，并且可以用于新的应用中，例如在木材中直接注入固体有机杀生物微粒以充当一种持久的木材防腐剂。

5. 发明申请

WO2005007368A2 PARTICULATE WOOD PRESERVATIVE AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译：颗粒状木材保鲜剂及其生产方法
公开(公告)号：WO2005007368A2
公开(公告)日：2005-01-27
申请号：PCT/US2004/019659
申请日：2004-06-17
申请人： PHIBRO-TECH, INC. , RICHARDSON, H., Wayne , HODGE, Robert, L.
发明人： RICHARDSON, H., Wayne , HODGE, Robert, L.
IPC分类号： B27K3/00
CPC分类号： A01N59/20 , A01N25/12 , A01N25/26 , B27K3/005 , B27K3/007 , B27K3/22 , B27K3/32 , B27K3/52 , C09D15/00 , A01N25/00 , A01N25/04 , A01N25/34 , A01N2300/00
摘要： A wood preservative includes injectable particles comprising one or more sparingly soluble copper salts. The copper-based particles are sufficiently insoluble so as to not be easily removed by leaching but are sufficiently soluble to exhibit toxicity to primary organisms primarily responsible for the decay of the wood. Exemplary particles contain for example copper hydroxide, basic copper carbonate, copper carbonate, basic copper sulfates including particularly tribasic copper sulfate, basic copper nitrates, copper oxychlorides , copper borates, basic copper borates, and mixtures thereof. The particles typically have a size distribution in which at least 50 % of particles have a diameter smaller than 0.25 µm, 0.2 µm, or 0.15 µm. At least about 20 % and even more than 75% of the weight of the particles may be composed of the substantially crystalline copper salt. Wood or a wood product may be impregnated with copper-based particles of the invention.
摘要翻译：木材防腐剂包括含有一种或多种微溶铜盐的可注射颗粒。铜基颗粒是足够不溶的，以便通过浸出不容易除去，但足够溶解以对主要负责木材腐烂的原生生物表现出毒性。示例性颗粒包含例如氢氧化铜，碱式碳酸铜，碳酸铜，碱式硫酸铜，特别是三硫酸铜，碱式硝酸铜，氯氧化铜，铜硼酸盐，碱式硼酸铜及其混合物。颗粒通常具有尺寸分布，其中至少50％的颗粒具有小于0.25μm，0.2μm或0.15μm的直径。至少约20％，甚至超过75％的颗粒重量可以由基本上结晶的铜盐组成。木材或木制品可以用本发明的铜基颗粒浸渍。

6. 发明申请

WO2007130548A2 METHOD OF TREATING CROPS WITH SUBMICRON CHLOROTHALONIL 审中-公开
标题翻译：用亚硫酸氢钙处理作物的方法
公开(公告)号：WO2007130548A2
公开(公告)日：2007-11-15
申请号：PCT/US2007/010790
申请日：2007-05-04
申请人： PHIBRO-TECH, INC. , HODGE, Robert, L. , POMPEO, Michael, P. , RICHARDSON, Wayne, H.
发明人： HODGE, Robert, L. , POMPEO, Michael, P. , RICHARDSON, Wayne, H.
CPC分类号： A01N37/34 , A01N25/04 , A01N25/30 , A01N2300/00
摘要： Use of high density milling media in the preparation of chlorothalonil particles with unexpected particle size reduction and narrow particle size distribution, and the use of these particles in a variety of applications, especially for treating agricultural crops, ornamentals, and other vegetation including seeds, and for treating the "surface of newly milled wood as an anti-sapstam agent, and for use in paints, mold-resista intt rinses, and,o ther surface agents.
摘要翻译：使用高密度研磨介质制备具有出人意料的颗粒尺寸减小和窄粒度分布的百菌清颗粒，以及这些颗粒在各种应用中的应用，特别是用于处理农作物，观赏植物和其他植被，包括种子，以及用于处理“新研磨的木材的表面作为抗锯齿剂”，用于油漆，耐模压冲洗和其它表面剂。

7. 发明申请

WO2007092580A2 BIOCIDAL AZOLE EMULSION CONCENTRATES HAVING HIGH ACTIVE INGREDIENT CONTENT 审中-公开
标题翻译：具有高活性成分含量的生物活性氨基酸乳液浓度
公开(公告)号：WO2007092580A2
公开(公告)日：2007-08-16
申请号：PCT/US2007/003419
申请日：2007-02-08
申请人： PHIBRO-TECH INC.
发明人： POMPEO, Michael, P.
CPC分类号： A01N43/90 , A01N43/653 , A01N43/80 , B27K3/34 , B27K3/343 , A01N51/00 , A01N25/04 , A01N25/02 , A01N2300/00
摘要： A concentrated stable emulsifiable formulation includes A) an amide, B) a water-soluble non-ionic emulsifier, C) a water-insoluble anionic emulsifier, and D) a water-insoluble biocidal azole, wherein the concentrated stable emulsifiable formulation is a solution containing the water-insoluble biocidal azole in an amount greater than 20% by weight of the formulation. An aqueous wood treatment composition which can be made for example from the concentrated stable emulsifiable formulation includes emulsified droplets containing at least one water-insoluble biocidal azole s and an amide such as N,N- dialkyloctanamide, N,N-dialkyldecanamide, N-alkyloctanamide, N-alkyldecanamide, octanamide, decanamide, or mixture thereof, where the alkyl groups independently comprise between one and three carbon atoms.
摘要翻译：浓缩稳定的可乳化制剂包括A）酰胺，B）水溶性非离子乳化剂，C）水不溶性阴离子乳化剂，和D）水不溶性杀生物灭鼠剂，其中浓缩稳定的可乳化制剂是溶液其含有大于制剂重量的20％的量的水不溶性杀生物灭鼠剂。可以由例如浓缩稳定的可乳化制剂制成的水性木材处理组合物包括含有至少一种水不溶性杀生物唑的乳化液滴和酰胺如N，N-二苯基辛酰胺，N，N-二烷基癸酰胺，N-烷基辛酰胺，N-烷基癸酰胺，辛酰胺，癸酰胺或其混合物，其中烷基独立地包含一个和三个碳原子。

8. 发明申请

WO2005110692A9 COMPOSITION, METHOD OF MAKING, AND TREATMENT OF WOOD WITH AN INJECTABLE WOOD PRESERVATIVE SLURRY HAVING BIOCIDAL PARTICLES 审中-公开
标题翻译：组合物，制备和处理木材与具有生物颗粒的可注射木材防腐浆料的方法
公开(公告)号：WO2005110692A9
公开(公告)日：2006-01-19
申请号：PCT/US2005017007
申请日：2005-05-17
申请人： PHIBRO TECH INC , RICHARDSON WAYNE H , HODGE RICHARD L , GLOVER DWIGHT W , POMPEO MICHAEL P , HAYDEN CHRISTOPHER G
发明人： RICHARDSON WAYNE H , HODGE RICHARD L , GLOVER DWIGHT W , POMPEO MICHAEL P , HAYDEN CHRISTOPHER G
IPC分类号： A01N59/20 , B27K3/00 , B27K3/08
CPC分类号： A01N59/20 , B27K3/005 , B27K3/08 , B27K3/22 , B27K3/52 , A01N59/26 , A01N59/16 , A01N59/14 , A01N53/00 , A01N51/00 , A01N47/38 , A01N47/22 , A01N47/12 , A01N47/02 , A01N43/653 , A01N43/42 , A01N37/34 , A01N25/08 , A01N25/04 , A01N2300/00
摘要： A method of preserving wood includes injecting into the wood an effective amount of a aqueous wood-injectable biocidal slurry, said a wood-injectable biocidal slurry containing dispersants and sub-micron biocidal particles selected from at least one of the following classes: 1) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble salts selected from copper salts, nickel salts, tin salts, and/or zinc salts; 2) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble metal hydroxides selected from copper hydroxide, nickel hydroxide, tin hydroxide, and/or zinc hydroxide; 3) a plurality of particles containing at least 25% by weight of a solid phase comprising a substantially-insoluble organic biocide selected from triazoles, chlorothalonil, iodo-propynyl butyl carbamate, copper-8-quinolate, fipronil, imidacloprid, bifenthrin, carbaryl, strobulurins, and indoxacarb; 4) a plurality of particles containing on the outer surface thereof a substantially-insoluble organic biocide; 5) a plurality of particles containing a solid phase of a biocidal, partially or fully glassified composition comprising at least one of Zn, B, Cu, and P. The particles may advantageously contain metallic copper, a leachability barrier, pigments, dyes, or other adjuvants disposed on the outer surface thereof.
摘要翻译：一种保存木材的方法包括向木材中注入有效量的含木质木材可注射的杀生物泥浆，所述木材可注射的杀生物泥浆含有分散剂和亚微米级杀生物颗粒，其选自以下类别中的至少一种：1）多个颗粒含有至少25重量％的选自铜盐，镍盐，锡盐和/或锌盐的微溶盐的固相; 2）多个颗粒，其含有至少25重量％的选自氢氧化铜，氢氧化镍，氢氧化锡和/或氢氧化锌的微溶金属氢氧化物的固相; 3）多个颗粒，其含有至少25重量％的固相，其包含选自三唑，百菌清，碘 - 丙炔基丁基氨基甲酸酯，8-氰酸铜，氟虫腈，吡虫啉，联苯菊酯，甲氰菊酯，斑马鱼和吲哚卡沙; 4）在其外表面上含有基本上不溶的有机杀生物剂的多个颗粒; 5）包含含有Zn，B，Cu和P中的至少一种的杀生物，部分或完全玻璃化组合物的固相的多个颗粒。该颗粒可以有利地包含金属铜，可浸出性屏障，颜料，染料或其他辅助剂设置在其外表面上。

9. 发明申请

WO2005110692A2 COMPOSITION, METHOD OF MAKING, AND TREATMENT OF WOOD WITH AN INJECTABLE WOOD PRESERVATIVE SLURRY HAVING BIOCIDAL PARTICLES 审中-公开
标题翻译：组合物，制备和处理木材与具有生物颗粒的可注射木材防腐浆料的方法
公开(公告)号：WO2005110692A2
公开(公告)日：2005-11-24
申请号：PCT/US2005/017007
申请日：2005-05-17
申请人： PHIBRO-TECH, INC. , RICHARDSON, Wayne, H. , HODGE, Richard, L. , GLOVER, Dwight, W. , POMPEO, Michael, P. , HAYDEN, Christopher, G.
发明人： RICHARDSON, Wayne, H. , HODGE, Richard, L. , GLOVER, Dwight, W. , POMPEO, Michael, P. , HAYDEN, Christopher, G.
IPC分类号： B27K3/00
CPC分类号： A01N59/20 , B27K3/005 , B27K3/08 , B27K3/22 , B27K3/52 , A01N59/26 , A01N59/16 , A01N59/14 , A01N53/00 , A01N51/00 , A01N47/38 , A01N47/22 , A01N47/12 , A01N47/02 , A01N43/653 , A01N43/42 , A01N37/34 , A01N25/08 , A01N25/04 , A01N2300/00
摘要： A method of preserving wood includes injecting into the wood an effective amount of a aqueous wood-injectable biocidal slurry, said a wood-injectable biocidal slurry containing dispersants and sub-micron biocidal particles selected from at least one of the following classes: 1) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble salts selected from copper salts, nickel salts, tin salts, and/or zinc salts; 2) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble metal hydroxides selected from copper hydroxide, nickel hydroxide, tin hydroxide, and/or zinc hydroxide; 3) a plurality of particles containing at least 25% by weight of a solid phase comprising a substantially-insoluble organic biocide selected from triazoles, chlorothalonil, iodo-propynyl butyl carbamate, copper-8-quinolate, fipronil, imidacloprid, bifenthrin, carbaryl, strobulurins, and indoxacarb; 4) a plurality of particles containing on the outer surface thereof a substantially-insoluble organic biocide; 5) a plurality of particles containing a solid phase of a biocidal, partially or fully glassified composition comprising at least one of Zn, B, Cu, and P. The particles may advantageously contain metallic copper, a leachability barrier, pigments, dyes, or other adjuvants disposed on the outer surface thereof.
摘要翻译：一种保存木材的方法包括向木材中注入有效量的含木质木材可注射的杀生物泥浆，所述木材可注射的杀生物泥浆含有分散剂和亚微米级杀生物颗粒，其选自以下类别中的至少一种：1）多个颗粒含有至少25重量％的选自铜盐，镍盐，锡盐和/或锌盐的微溶盐的固相; 2）多个颗粒，其含有至少25重量％的选自氢氧化铜，氢氧化镍，氢氧化锡和/或氢氧化锌的微溶金属氢氧化物的固相; 3）多个颗粒，其含有至少25重量％的固相，其包含选自三唑，百菌清，碘 - 丙炔基丁基氨基甲酸酯，8-氰酸铜，氟虫腈，吡虫啉，联苯菊酯，甲氰菊酯，斑马鱼和吲哚卡沙; 4）在其外表面上含有基本上不溶的有机杀生物剂的多个颗粒; 5）包含含有Zn，B，Cu和P中的至少一种的杀生物，部分或完全玻璃化组合物的固相的多个颗粒。该颗粒可以有利地包含金属铜，可浸出性屏障，颜料，染料或其他辅助剂设置在其外表面上。

10. 发明申请

WO2005007368A3 PARTICULATE WOOD PRESERVATIVE AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译：颗粒木材防腐剂及其制备方法
公开(公告)号：WO2005007368A3
公开(公告)日：2005-05-12
申请号：PCT/US2004019659
申请日：2004-06-17
申请人： PHIBRO TECH INC , RICHARDSON H WAYNE , HODGE ROBERT L
发明人： RICHARDSON H WAYNE , HODGE ROBERT L
IPC分类号： A01N59/20 , B27K3/22 , B27K3/32 , B27K3/52 , C09D15/00
CPC分类号： A01N59/20 , A01N25/12 , A01N25/26 , B27K3/005 , B27K3/007 , B27K3/22 , B27K3/32 , B27K3/52 , C09D15/00 , A01N25/00 , A01N25/04 , A01N25/34 , A01N2300/00
摘要： A wood preservative includes injectable particles comprising one or more sparingly soluble copper salts. The copper-based particles are sufficiently insoluble so as to not be easily removed by leaching but are sufficiently soluble to exhibit toxicity to primary organisms primarily responsible for the decay of the wood. Exemplary particles contain for example copper hydroxide, basic copper carbonate, copper carbonate, basic copper sulfates including particularly tribasic copper sulfate, basic copper nitrates, copper oxychlorides , copper borates, basic copper borates, and mixtures thereof. The particles typically have a size distribution in which at least 50 % of particles have a diameter smaller than 0.25 µm, 0.2 µm, or 0.15 µm. At least about 20 % and even more than 75% of the weight of the particles may be composed of the substantially crystalline copper salt. Wood or a wood product may be impregnated with copper-based particles of the invention.
摘要翻译：木材防腐剂包括包含一种或多种微溶铜盐的可注射颗粒。铜基颗粒是足够不溶的，从而不易通过浸出去除，但是充分溶解以对主要负责木材腐烂的主要生物体显示毒性。示例性颗粒包含例如氢氧化铜，碱式碳酸铜，碳酸铜，碱式硫酸铜，特别包括三元硫酸铜，碱式硝酸铜，氯氧化铜，硼酸铜，碱式硼酸铜及其混合物。颗粒通常具有尺寸分布，其中至少50％的颗粒具有小于0.25μm，0.2μm或0.15μm的直径。颗粒重量的至少约20％甚至多于75％可以由基本上结晶的铜盐组成。木材或木制品可以用本发明的铜基颗粒浸渍。

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