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    • 2. 发明申请
    • LITHIUM COBALT OXIDE CATHODIC ACTIVE MATERIAL AND SECONDARY BATTERY USING THE SAME
    • 锂钴氧化物阴极活性材料及其二次电池
    • WO1997039489A1
    • 1997-10-23
    • PCT/JP1997001226
    • 1997-04-10
    • MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.INOUE, KaoruOURA, TakafumiMURAI, HiroyukiKOSHINA, Hizuru
    • MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.
    • H01M04/52
    • H01M10/0525H01M4/525
    • To obtain a secondary battery simultaneously having performances such as extremely large electric capacity, excellent discharge efficiency, high voltage, and freedom from fire in high temperature environments. The secondary battery of the invention comprises a positive electrode having lithium cobalt oxide composed of lithium, cobalt and oxygen, a negative electrode capable of intercalating and deintercalating lithium, and an electrolyte contacting with both of the positive electrode and the negative electrode. The lithium cobalt oxide is powder, and this powder has a mean particle size in a range of 5 mu m to 25 mu m. The lithium cobalt oxide has a chemical composition in which the molar ratio of said cobalt to said lithium is in a range of 0.96 to 1.04, and also has a crystallinity so that the full width of half maximum of 003 diffraction peak in X-ray diffraction using CuK alpha ray is in a range of 0.15 DEG to 0.18 DEG . The electrolyte is a non-aqueous electrolyte. The potential of the positive electrode in charged state is in a range of 4.2 V to 4.5 V to the redox potential of lithium.
    • 为了获得同时具有诸如极大电容,优异的放电效率,高电压和高温环境中的火灾的性能的二次电池。 本发明的二次电池包括由锂,钴和氧组成的锂钴氧化物的正电极,能够插入和脱嵌锂的负极以及与正电极和负电极接触的电解质。 锂钴氧化物为粉末,该粉末的平均粒径为5μm〜25μm的范围。 所述钴酸锂的化学组成为:所述钴与所述锂的摩尔比在0.96〜1.04的范围内,并具有结晶性,使得X射线衍射中的003衍射峰的半峰全宽 使用CuKα射线在0.15°至0.18°的范围内。 电解质是非水电解质。 正极在充电状态的电位在锂的氧化还原电位的4.2V至4.5V的范围内。