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1. 发明申请

WO1994014822A1 POLYVALENT METAL SALTS OF PHOSPHORIC DIESTER AND ORGANO(POLY)SILOXANES MODIFIED WITH POLYVALENT METAL SALT OF PHOSPHORIC DIESTER 审中-公开
标题翻译：多价金属盐和磷酸盐（POLY）硅氧烷改性多价金属盐的磷酸盐金属盐
公开(公告)号：WO1994014822A1
公开(公告)日：1994-07-07
申请号：PCT/JP1993001924
申请日：1993-12-28
申请人： KAO CORPORATION , YANO, Shinji , FUKASAWA, Junichi , KAWASAKI, Hironori , OKUTSU, Munehisa , IHARA, Takeshi , KITA, Katsumi , FUJIKURA, Yoshiaki , AKAOGI, Akira
发明人： KAO CORPORATION
IPC分类号： C07F09/09
CPC分类号： C08G77/48 , A61K8/55 , A61K8/896 , A61Q1/02 , A61Q17/04 , A61Q19/00 , C07F9/091 , C07F9/092 , C07F9/6596 , C08G77/395
摘要： The present invention relates to polyvalent metal salts of a phosphoric diester represented by formula (1) and organo(poly)siloxanes modified with a polyvalent metal salt of a phosphoric diester having the structural units represented by formulae (9) and (10). In formula (1), R represents a C1 to C20 linear or branched alkyl group, R and R are the same or different and independently represent a C2 to C3 linear or branched alkylene group, R represents a C3 to C20 linear or C5 to C20 branched alkylene group, A represents a group -COO- or -O-, x and y are the same or different from each other and independently represent an integrer of 0 to 10, L represents a C1 to C40 linear or branched alkyl group or a group, R -(OR )x-A-R -(OR )y- wherein R , R , R , R , A, x and y have the same meaning as defined herein before, M represents a divalent or polyvalent metal atom, and m represents the same value as the valence of M. In formulae (9) and (10), R : a C2 to C20 alkylene group, R : a C1 to C50 linear or branched alkylene group which may optionally be substituted by a hydroxyl group, p: a number from 0 to 200, M: a divalent or polyvalent metal atom, n: a number same as the value of the valence of M. R , R , R , R independently represent hydrogen, alkyl, alkoxy, phenyl or a structural unit represented by formula (10), w: a number of 0 or 1. The compounds according to the present invention impart thixotropic rheology to oil bases and silicone oils which are used in various fields. They are very safe compounds and constitute transparent and excellent gels which provide favorable sensation during use, and thus they are especially useful as materials for preparing cosmetic compositions and perfume compositions.
摘要翻译：本发明涉及由式（1）表示的磷酸二酯的多价金属盐和用具有由式（9）和（10）表示的结构单元的磷酸二酯的多价金属盐改性的有机（聚）硅氧烷。在式（1）中，R 1表示C1至C20直链或支链烷基，R 2和R 4相同或不同，并且独立地表示C 2至C 3直链或支链亚烷基， 3>表示C3〜C20直链或C5〜C20支链亚烷基，A表示-COO-或-O-基团，x和y彼此相同或不同，独立地表示0〜10的整数，L 表示C1至C40直链或支链烷基或基团，R 1 - （OR 2）x AR 3 - （OR 4）y - ，其中R 1，R 2，R 3，R 4，A，x和y具有如前所定义的相同含义，M表示二价或多价金属原子，m表示与M的化合价相同的值。在式（9）和（10）R 5：C 2〜C 20亚烷基，R 6：可任意被羟基取代的C1〜C50直链或支链亚烷基，p：0〜200的数，M ：二价或多价金属原子，n：与M.R 7价，R 8，R 9，R 9， 10）独立地表示氢，烷基，烷氧基，苯基或由式（10）表示的结构单元，w：数为0或1.根据本发明的化合物赋予使用的油基和硅油的触变流变性在各个领域。它们是非常安全的化合物，并且构成透明和优异的凝胶，其在使用期间提供有利的感觉，因此它们特别可用作制备化妆品组合物和香料组合物的材料。

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