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1. 发明申请

WO1998023553A1 CEMENT ADMIXTURE, CONCRETE, AND PROCESS FOR PRODUCING FLUOROOXYALYLENE COMPOUNDS 审中-公开
标题翻译：水泥混合料，混凝土和生产氟代亚甲基化合物的方法
公开(公告)号：WO1998023553A1
公开(公告)日：1998-06-04
申请号：PCT/JP1997004335
申请日：1997-11-27
申请人： ASAHI GLASS COMPANY LTD. , ENNA, Genichirou , FUKUDA, Hiroki , OHTSUKA, Yoshihiro
发明人： ASAHI GLASS COMPANY LTD.
IPC分类号： C04B24/32
CPC分类号： C08G65/2639 , C04B24/005 , C04B24/32 , C04B2103/34 , C08G65/007
摘要： A cement admixture which can combine the flowability of a fresh concrete with a high strength of a hardened concrete; and a concrete containing the same. The admixture comprises a mixture of a fluorine compound represented by the general formula (1): R -Q -O-(A -O)k-R and having a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio (Mw/Mn) of 1.1 or higher wherein R represents C1-22 aliphatic polyfluorohydrocarbyl optionally containing ethereal oxygen or thioethereal sulfur, Q represents C1-5 linear or branched alkylene, k is an integer of 1 to 100, A represents C2-4 linear alkylene, wherein at least one hydrogen atom may have been replaced with a hydrocarbon group optionally containing ethereal oxygen, provided that when k is 2 to 100, the A 's may be the same or different, and R represents hydrogen, C1-18 hydrocarbyl, or C1-18 acyl.
摘要翻译：一种可将新混凝土的流动性与硬化混凝土的高强度组合的水泥混合物; 和含有它的混凝土。该混合物包含由通式（1）表示的氟化合物：R f -Q 1 -O-（A 1 -O）k R 1和重均分子量（Mw）至数均分子量（Mn）比（Mw / Mn）为1.1或更高，其中R f表示任选含有醚氧或硫代醚硫的C 1-22脂族多氟烃基，Q 1表示C1-5直链或支链亚烷基，k为1至100的整数，A 1表示C 2-4直链亚烷基，其中至少一个氢原子可以被任选含有醚氧的烃基替代，条件是当k为2〜 100，A 1可以相同或不同，R 1表示氢，C 1-18烃基或C 1-18酰基。

2. 发明申请

WO1998022546A1 RESIN COMPOSITIONS FOR COATING 审中-公开
标题翻译：树脂组合物涂料
公开(公告)号：WO1998022546A1
公开(公告)日：1998-05-28
申请号：PCT/JP1996003386
申请日：1996-11-19
申请人： DAICEL CHEMICAL INDUSTRIES, LTD. , OHTSUKA, Yoshihiro , OSHINO, Yasuhiro
发明人： DAICEL CHEMICAL INDUSTRIES, LTD.
IPC分类号： C09D163/00
CPC分类号： C08G59/027 , C08J7/047 , C08J2463/00 , C09D163/08
摘要： A resin composition for coating suitable as, for example, a surface coating material capable of improving the coatability, etc., of olefin resin films, etc., which contains an epoxidized block copolymer (A) and an organic compound (B) carrying a functional group reacting with an epoxy group and having a number-average molecular weight of from 150 to 150,000, wherein the weight ratio (A)/(A + B) ranges from 1/100 to 99/100. Another resin composition for coating which contains an epoxidized block copolymer (A), an organic compound (B) carrying a functional group reacting with an epoxy group and having a number-average molecular weight of from 150 to 150,000, and an epoxy ring opening promoter (C), wherein the weight ratio (A)/(A + B) ranges from 1/100 to 99/100 and the content of the above component (C) ranges from 0.1 to 10 parts by weight per 100 parts by weight of (A + B).
摘要翻译：一种用于涂覆的树脂组合物，其适合于例如含有环氧化嵌段共聚物（A）和有机化合物（B）的烯烃树脂膜等的能够改善涂布性等的表面涂料，官能团与环氧基反应，数均分子量为150〜150,000，其中重量比（A）/（A + B）为1/100至99/100。另一种涂料用树脂组合物，其含有环氧化嵌段共聚物（A），带有与环氧基反应的数均分子量为150〜150,000的官能团的有机化合物（B）和环氧化开环促进剂（C）中，其中，重量比（A）/（A + B）为1/100〜99/100，上述成分（C）的含量为0.1〜10重量份，相对于100重量份（A + B）。

3. 发明申请

WO1998014323A1 METAL/SYNTHETIC RESIN LAMINATE AND SYNTHETIC RESIN-CLAD METALLIC PIPE 审中-公开
标题翻译：金属/合成树脂层压板和合成树脂层金属管
公开(公告)号：WO1998014323A1
公开(公告)日：1998-04-09
申请号：PCT/JP1997003512
申请日：1997-10-01
申请人： DAICEL CHEMICAL INDUSTRIES, LTD. , AIZAWA, Katsumi , OHTSUKA, Yoshihiro
发明人： DAICEL CHEMICAL INDUSTRIES, LTD.
IPC分类号： B32B15/08
CPC分类号： B32B15/08 , B32B1/08 , B32B7/12 , B32B2597/00 , F16L9/147 , Y10T428/1359 , Y10T428/24959 , Y10T428/31515 , Y10T428/31522 , Y10T428/31678 , Y10T428/31743 , Y10T428/31797 , Y10T428/31909 , Y10T428/31913 , Y10T428/31924
摘要： A metal/synthetic resin laminate comprising a metal substrate layer, an epoxy resin-based adhesive layer (a first adhesive layer), an adhesive layer (a second adhesive layer) comprising an epoxidized styrenic thermoplastic elastomer D prepared by epoxidizing a double bond derived from a conjugated diene compound of a block copolymer C comprising a polymer block A composed mainly of a styrenic compound and a polymer block B composed mainly of a conjugated diene compound or a partial hydrogenation product thereof, and a synthetic resin layer; and a synthetic resin-clad metallic pipe wherein the above metal substrate layer is tubular.
摘要翻译：一种金属/合成树脂层压体，其包含金属基材层，环氧树脂基粘合剂层（第一粘合剂层），粘合剂层（第二粘合剂层），其包含环氧化苯乙烯类热塑性弹性体D，其通过环氧化衍生自包含主要由苯乙烯类化合物组成的聚合物嵌段A和主要由共轭二烯化合物或其部分氢化产物组成的聚合物嵌段B的嵌段共聚物C的共轭二烯化合物和合成树脂层; 以及上述金属基材层为管状的合成树脂包覆金属管。

4. 发明申请

WO1997002296A1 EPOXIDIZED BLOCK COPOLYMER, PROCESS FOR THE PRODUCTION OF THE COPOLYMER, AND COMPOSITION CONTAINING THE COPOLYMER 审中-公开
标题翻译：环氧化嵌段共聚物，生产共聚物的方法和含有共聚物的组合物
公开(公告)号：WO1997002296A1
公开(公告)日：1997-01-23
申请号：PCT/JP1996001843
申请日：1996-07-03
申请人： DAICEL CHEMICAL INDUSTRIES, LTD. , OHTSUKA, Yoshihiro , OSHINO, Yasuhiro , TANAKA, Masaki
发明人： DAICEL CHEMICAL INDUSTRIES, LTD.
IPC分类号： C08F08/08
CPC分类号： C08L53/025 , C08F8/08 , C08F2800/20 , C08L53/02 , C08F297/04 , C08F8/04 , C08F297/046
摘要： An epoxidized block copolymer (E) produced by epoxidizing a block copolymer (C) comprising a polymer block (A) mainly made from an aromatic vinyl compound and a polymer block (B) mainly made from a conjugated diene compound or a product (D) of hydrogenation of the copolymer (C) and satisfying at least one of the following requirements (1), (2) and (3): (1) the molar ratio R is 0.001 to 0.1, R being defined by the formula: R = [hydroxyl]/[epoxy] (wherein [hydroxyl] is the number of moles of hydroxyl groups contained per unit weight of the epoxidized block copolymer and [epoxy] is that of epoxy groups); (2) the gel content is 5 wt.% or below; and (3) the chloride ion content is 7 ppm or below. The above copolymer (E) can be produced by epoxidizing the block copolymer (C) or (D) in an organic solvent and removing the solvent by evaporation. Compositions comprising the copolymer (E) and other compounds and/or resins are useful.
摘要翻译：通过环氧化嵌段共聚物（C）制备的环氧化嵌段共聚物（E），其包含主要由芳族乙烯基化合物制成的聚合物嵌段（A）和主要由共轭二烯化合物或产物（D）制成的聚合物嵌段（B）的共聚物（C）的氢化并满足以下要求（1），（2）和（3）中的至少一个：（1）摩尔比R为0.001至0.1，R由下式定义：R = [羟基] / [环氧基]（其中[羟基]是每单位重量的环氧化嵌段共聚物和[环氧基]含有的羟基的摩尔数，是环氧基的摩尔数）。（2）凝胶含量为5重量％以下; 和（3）氯离子含量为7ppm以下。上述共聚物（E）可以通过在有机溶剂中环氧化嵌段共聚物（C）或（D）并通过蒸发除去溶剂来制备。包含共聚物（E）和其它化合物和/或树脂的组合物是有用的。

5. 发明申请

WO1998024861A1 HOT-MELT ADHESIVE COMPOSITION WITH EXCELLENT HEAT AND COLD RESISTANCE 审中-公开
标题翻译：热熔胶组合物具有优异的耐热和耐寒性
公开(公告)号：WO1998024861A1
公开(公告)日：1998-06-11
申请号：PCT/JP1997004342
申请日：1997-11-27
申请人： DAICEL CHEMICAL INDUSTRIES, LTD. , OHTSUKA, Yoshihiro , NAKAO, Kazunori
发明人： DAICEL CHEMICAL INDUSTRIES, LTD.
IPC分类号： C09J163/08
CPC分类号： C08G59/027 , C08L91/06 , C09D153/025 , C09J163/08
摘要： A hot-melt adhesive composition which comprises a modified block copolymer, a paraffin wax having a melting point of 40 to 100 DEG C, a tackifier, and an antioxidant. The copolymer is obtained by epoxidizing carbon-carbon double bonds of conjugated diene units of a block copolymer having in the molecule at least one polymer block (A) formed mainly from a vinylaromatic compound and at least one polymer block (B) formed mainly from a conjugated diene compound. The modified block copolymer has satisfactory compatibility with the paraffin wax and the tackifier because it has epoxy groups, which are polar, in the molecule. Since the modified block copolymer and the paraffin wax are used in combination as the base, the composition has excellent heat and cold resistance and is highly heat-resistant despite its low melt viscosity.
摘要翻译：一种热熔粘合剂组合物，其包含改性嵌段共聚物，熔点为40-100℃的石蜡，增粘剂和抗氧化剂。该共聚物是通过在分子中环氧化共轭二烯单元的碳 - 碳双键获得的，所述嵌段共聚物在分子中具有至少一个主要由乙烯基芳族化合物形成的聚合物嵌段（A）和至少一个主要由共轭二烯化合物。改性嵌段共聚物与石蜡和增粘剂具有令人满意的相容性，因为它在分子中具有极性的环氧基。由于改性嵌段共聚物和石蜡作为基料组合使用，组合物具有优异的耐热和耐寒性，并且尽管其熔体粘度低，但耐热性高。

6. 发明申请

WO1997030095A1 PROCESS FOR PRODUCING EPOXIDIZED BLOCK COPOLYMER 审中-公开
标题翻译：生产环氧化嵌段共聚物的方法
公开(公告)号：WO1997030095A1
公开(公告)日：1997-08-21
申请号：PCT/JP1996000334
申请日：1996-02-16
申请人： DAICEL CHEMICAL INDUSTRIES, LTD. , OSHINO, Yasuhiro , OHTSUKA, Yoshihiro
发明人： DAICEL CHEMICAL INDUSTRIES, LTD.
IPC分类号： C08F08/08
CPC分类号： C08F8/08 , C08F297/04 , C08F8/04 , C08F297/046
摘要： A process for producing an epoxidized block copolymer appropriate for modifying agents or modifying aids for rubbery polymers or resinous polymers, adhesives, sealants, etc. The process comprises epoxidizing a block copolymer which may be partly hydrated and comprises a polymer block (A) containing a vinyl aromatic hydrocarbon compound as the main component and another polymer block (B) containing a conjugated diene compound as the main component to thereby synthesize an epoxidized block copolymer (C) and then recovering this polymer from a slurry or solution thereof in an organic solvent by steam stripping in the presence of a surfactant. It is preferably that the surfactant is a nonionic one, in particular, one represented by the general formula: HO(C2H4O)a(C3H6O)b(C2H4)cOH, wherein a, b and c represent each a number of 1 to 1,000, having an average molecular weight of 3,000 to 20,000 and containing 20 to 90 % by weight of polyoxyethylene. According to the process, the epoxidized block copolymer product can be easily recovered from the reaction mixture without giving any prolonged heat history and thus the epoxy group can be prevented from undergoing ring opening. Also, it is possible to obtain an epoxidized block copolymer having such an epoxy equivalent as to give a high elasticity and the characteristics of epoxy compounds.
摘要翻译：用于制备适于改性剂或用于橡胶状聚合物或树脂聚合物，粘合剂，密封剂等的改性助剂的环氧化嵌段共聚物的方法。该方法包括使可部分水合的嵌段共聚物环氧化，并且包含聚合物嵌段（A）乙烯基芳族烃化合物作为主要成分，另一种以共轭二烯化合物为主要成分的聚合物嵌段（B），由此合成环氧化嵌段共聚物（C），然后由有机溶剂中的浆料或其溶液中回收该聚合物，在表面活性剂存在下蒸汽汽提。优选表面活性剂是非离子表面活性剂，特别是由以下通式表示的表面活性剂：HO（C 2 H 4 O）a（C 3 H 6 O）b（C 2 H 4）c OH，其中a，b和c各自表示1至1,000个，平均分子量为3,000〜20,000，含有20〜90重量％的聚氧乙烯。根据该方法，可以容易地从反应混合物中回收环氧化嵌段共聚物产物，而不会产生任何长时间的热历史，从而可以防止环氧基发生开环。此外，可以获得具有这样的环氧当量的环氧化嵌段共聚物，以提供高弹性和环氧化合物的特性。

7. 发明申请

WO1990007537A1 PRODUCTION OF POLYETHER 审中-公开
标题翻译：聚醚的生产
公开(公告)号：WO1990007537A1
公开(公告)日：1990-07-12
申请号：PCT/JP1989001322
申请日：1989-12-28
申请人： ASAHI GLASS COMPANY LTD. , TAKEYASU, Hiromitsu , DOI, Takao , OHTSUKA, Yoshihiro , KUNII, Nobuaki
发明人： ASAHI GLASS COMPANY LTD.
IPC分类号： C08G65/30
CPC分类号： C08G65/2663 , C08G65/30
摘要： This invention relates to a method for producing a polyether comprising conducting ring-opening addition reaction between a hydroxyl-containing initiator and a number of monoepoxide molecules each having at least three carbon atoms, particularly alkylene oxide molecules, in the presence of a composite metal cyanide complex as a catalyst, treating the formed polyether containing the catalyst with a treatment comprising an alkali metal alcoholate to thereby deactivate the catalyst, and removing the deactivated catalyst and the remaining treatment from the polyether. The invention also relates to a method for producing a polyether comprising deactivating the catalyst with the treatment, reacting the formed polyether with ethylene oxide, and removing the deactivated catalyst and the remaining treatment from the polyether. The use of the treatment comprising an alkali metal alcoholate facilitates the removal of the composite metal cyanide complex from the polyether and the production of oxyethylene-terminated polyether.

8. 发明申请

WO1996028514A1 RECLAIMED THERMOPLASTIC RESIN COMPOSITIONS AND PROCESS FOR THE PRODUCTION THEREOF 审中-公开
标题翻译：回收的热塑性树脂组合物及其生产方法
公开(公告)号：WO1996028514A1
公开(公告)日：1996-09-19
申请号：PCT/JP1996000595
申请日：1996-03-11
申请人： DAICEL CHEMICAL INDUSTRIES, LTD. , OHTSUKA, Yoshihiro , AIZAWA, Katsumi , OSHINO, Yasuhiro
发明人： DAICEL CHEMICAL INDUSTRIES, LTD.
IPC分类号： C08L101/00
CPC分类号： C08J11/06 , B29B17/0026 , B29K2023/06 , B29K2105/26 , C08L23/02 , C08L101/00 , Y02W30/62 , Y02W30/701 , C08L2666/02 , C08L2666/04 , C08L2666/24
摘要： A reclaimed thermoplastic resin composition prepared by melt-kneading 100 parts by weight of regrinds (A) of molded articles made from a thermoplastic resin (A1) or a thermoplastic resin composition (A2) with 0.1 to 30 parts by weight of an epoxidized (partially hydrogenated) diene polymer (B). Another reclaimed thermoplastic resin composition comprising (a) 20 to 67 wt.% of a flexible polyethylene resin, (b) 30 to 77 wt.% of a waste material of a structure produced by laminating at least two thermoplastic resins selected from among polyamide resin, polyester resin, polypropylene resin, polyethylene resin and so on, and (c) 3 to 20 wt.% of an epoxidized (partially hydrogenated) diene polymer.
摘要翻译：通过将100重量份由热塑性树脂（A1）或热塑性树脂组合物（A2）制成的成型制品的回用料（A）以0.1-30重量份的环氧化（部分氢化）二烯聚合物（B）。另一种再生热塑性树脂组合物，其包含（a）20至67重量％的柔性聚乙烯树脂，（b）30至77重量％的通过层压至少两种选自聚酰胺树脂中的热塑性树脂制成的结构废料，聚酯树脂，聚丙烯树脂，聚乙烯树脂等，和（c）3〜20重量％的环氧化（部分氢化）二烯系聚合物。

9. 发明申请

WO1990005172A1 TETRAFLUOROETHANE COMPOSITION FOR A REGRIGERATOR 审中-公开
标题翻译：用于回流器的四氢呋喃组合物
公开(公告)号：WO1990005172A1
公开(公告)日：1990-05-17
申请号：PCT/JP1989001150
申请日：1989-11-09
申请人： ASAHI GLASS COMPANY LTD. , OHTSUKA, Yoshihiro , FUKUDA, Hiroki , TANABE, Kiyoshi , FUKUSHIMA, Masato , WATANABE, Nahohiro
发明人： ASAHI GLASS COMPANY LTD.
IPC分类号： C09K05/04
CPC分类号： C10M171/008 , C09K5/045 , C09K2205/24
摘要： A tetrafluoroethane composition for a refrigerator, which comprises a tetrafluoroethane and at least one polyether selected from the group consisting of: (I), (II) and (III), wherein R is an alkylene group, each of R , R , R , R , R , R and R which may be the same or different is a hydrogen atom, and alkyl group, an aralkyl group, an aryl group, an acyl group, a glycidyl group, -SO2R , alpha , beta or -Y -(OR )p-OR , wherein R is as defined above, each of R , R R and R is an alkyl group, an aralkyl group or an aryl, and Y is a residue of a dicarboxylic compound having at least 3 carbon atoms, provided that at least one of R and R and at least one of R and R are not hydrogen atoms, and when R is a hydrogen atom, an alkyl group for R has 1 or 2 carbon atoms, and when R is a hydrogen atom, an alkyl group for R has 1 or 2 carbon atoms, l, m, n and p which may be the same or different are integers which bring the kinematic viscosity of the compounds of the formulas (I) to (III) to a level of from 5 to 300 cSt at 40 DEG C, X is a residue obtained by removing hydroxyl groups from a dihydroxy compound or a dicarboxylic compound, and X is a residue obtained by removing hydroxyl groups from a trihydroxy compound or a tricarboxylic compound.
摘要翻译：一种用于冰箱的四氟乙烷组合物，其包含四氟乙烷和至少一种选自：（I），（II）和（III）的聚醚，其中R 1是亚烷基，每个R 2 R 3，R 4，R 5，R 6，R 7和R 8可以相同或不同，是氢原子，烷基，芳烷基，芳基，酰基，缩水甘油基，-SO 2 R 9，α，β或-Y 1 - （OR 1）p-OR 12，其中R 1如上定义 R 9，R 10 R 11和R 12各自为烷基，芳烷基或芳基，Y 1为具有至少3个碳原子的二羧酸化合物的残基碳原子，条件是R 2和R 3中的至少一个以及R 4和R 5中的至少一个不是氢原子，当R 2是氢原子时，烷基 R 3的基团具有1或2个碳原子，当R 3是氢原子时，R 2的烷基具有1或2个碳原子，l，m，n和p可以是相同或不同的是带有动力学的整数式（I）至（III）化合物的粘度在40℃下为5至300cSt，X 1是通过从二羟基化合物或二羧酸化合物除去羟基获得的残基， X 2是通过从三羟基化合物或三羧酸化合物除去羟基而获得的残基。

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