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    • 1. 发明申请
    • METHOD OF BONDING ALUMINIUM SUBSTRATES WITH ANAEROBIC SEALANTS TO FORM A SEAL
    • 将铝基材与无机密封剂粘合以形成密封的方法
    • WO2008125539A1
    • 2008-10-23
    • PCT/EP2008/054173
    • 2008-04-07
    • LOCTITE (R & D) LIMITEDWROBEL, PeterO'DWYER, PatCONDRON, David
    • WROBEL, PeterO'DWYER, PatCONDRON, David
    • C09J4/00F16J15/00
    • C09J4/00C08F220/00C08F230/00
    • The invention relates to a method of providing a seal between an aluminium substrate and a second substrate, wherein the seal is exposed to engine fluids selected from oils and/or coolant mixtures at elevated temperatures in the range from 600C to 175°C. The method of the invention involves (a) applying to at least one of the substrates an anaerobic sealant composition made from (i) one or more polymerizable (meth)acrylate ester monomers, (ii) an anaerobic cure- inducing component, and (iii) 0.05 to 0.25 % by weight, based on the total composition, of an adhesion promoter comprising one or more phosphorus-containing compounds having the general formula (I), wherein: R 1 is H, CH 3 or C 2 H 5 , R 2 is -CH 2 -C 2 H 4 TC 3 H 6 -, or -CH 2 -CH-(CH 3 )-, R 3 is H, CH 3 or C 2 H 5 , n is an integer from 1 to 10, and m is an integer from 1 to 3; (b) bringing the substrates together face-to-face with a gap between the faces in the range from 0.1 to 0.25 mm, in at least part of the total face-to-face area, and (c) allowing or enabling the composition to cure at substantially ambient temperature.
    • 本发明涉及一种在铝基板和第二基板之间提供密封的方法,其中在600℃至175℃的高温下,密封件暴露于选自油和/或冷却剂混合物的发动机流体。 本发明的方法包括(a)向至少一个基底施加由(i)一种或多种可聚合(甲基)丙烯酸酯单体,(ii)厌氧固化诱导组分和(iii) )0.05至0.25重量%,基于总组合物,包含一种或多种具有通式(I)的含磷化合物的粘合促进剂,其中:R 1是H,CH 2, 或者C 2 H 5,R 2是-CH 2 CO 2, H 2 H 3 - , - CH 2 CH 2 - , - CH 2 CH 2 - , - CH 2 CH 2 - , - (CH 3) - ,R 3是H,CH 3或C H < / SUB,n为1〜10的整数,m为1〜3的整数。 (b)在总面对面区域的至少一部分中,使面对面与面之间的间隙为0.1至0.25mm,并且(c)允许或使组合物 在基本环境温度下固化。