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    • 1. 发明申请
    • PROCESS OPERATING AT NORMAL PRESSURE FOR PRODUCING OXYGEN OR AIR ENRICHED WITH OXYGEN
    • 用于生产氧气或氧气的正常压力的工艺操作
    • WO2003038359A1
    • 2003-05-08
    • PCT/FI2002/000790
    • 2002-10-09
    • NURMIA, WendieNURMIA, Matti
    • NURMIA, Matti
    • F25J3/04
    • F25J3/04309F25J3/04066F25J3/0463F25J3/04939F25J5/007F25J2200/02F25J2200/04F25J2200/80F25J2210/40F25J2215/40F25J2215/50F25J2250/42F25J2250/50
    • The invention relates to a process for producing oxygen or air enriched with oxygen, in which process: The air entering the process is cooled in a heat exchanger (14) to near to the condensation point of air and the air is led to a separation unit (10) formed of two or more chambers connected thermally to each other and comprising A and B halves (11, 12), in which it is divided, using liquidization and evaporation processes, into two or more gaseous fractions. The process air is maintained at normal temperature, except for small pressure differences to maintain the flow of the air and to optimize the process. When the process air flows through the A half of the separation unit, the liquid oxygen concentrate separated from it is evaporated in the B half (12) of the separation unit at such a pressure, lower than normal pressure, that the desired composition is obtained for the oxygen concentrate and the heat of liquidization released in the A half (11) of the unit is transferred to the B half (12) of the unit and is bound in it to the evaporation of the oxygen concentrate. The low-oxygen-content process air leaving the A half (11) of the separation unit is led out of the process through the heat exchanger (14). The oxygen concentrate evaporated in the B half (12) of the separation unit exits at the lower than normal pressure prevailing in the half in question, either as such, or through a boosting and cooling process to the heat exchanger (14), and from there out of the process. The liquidization and evaporation processes are carried out in the said separation unit (10) in nearly reversible conditions, in such a way that the gas phase in each process and in each part of the separation unit is nearly in equilibrium with the liquid phase in the same part.
    • 本发明涉及一种生产富氧氧的氧气或空气的方法,其中进入该过程的空气在热交换器(14)中被冷却至靠近空气的冷凝点,并且空气被引导到分离单元 (10)由两个或更多个彼此热连接并且包括A和B半部(11,12)的室形成,其中使用液化和蒸发过程将其分成两个或更多个气体馏分。 工作空气维持在正常温度,除了小的压力差以保持空气的流动并优化过程。 当处理空气流过分离单元的一半时,从其分离出的液氧浓缩物在分离单元的B半部(12)中以低于常压的压力蒸发得到所需组合物 对于氧浓缩物,并且在该单元的一半(11)中释放的液化热量被转移到该单元的B半部(12)并且被结合到氧浓缩物的蒸发中。 离开分离单元的一半(11)的低氧含量的处理空气通过热交换器(14)被引出该过程。 在分离单元的B一半(12)中蒸发的氧浓缩物以低于所讨论的一半中的正常压力出口,或者通过对热交换器(14)的升压和冷却过程,以及从 出了这个过程。 液化和蒸发过程在几乎可逆的条件下在所述分离单元(10)中进行,使得每个过程中的气相和分离单元的每个部分中的气相几乎与液相中的液相平衡 同一部分。
    • 2. 发明申请
    • PROCESS FOR PRODUCING LIQUID CARBON DIOXIDE FROM COMBUSTION GAS AT NORMAL PRESSURE
    • 用于在正常压力下从燃烧气体生产二氧化碳的方法
    • WO2003035221A1
    • 2003-05-01
    • PCT/FI2002/000814
    • 2002-10-21
    • NURMIA, WendieNURMIA, Matti
    • NURMIA, Matti
    • B01D53/14
    • B01D53/1475B01D53/62C01B32/50Y02C10/04Y02C10/06Y02P20/152
    • The invention relates to a process for producing liquid carbon dioxide (CO 2 ) from combustion gas at normal pressure, in which process the CO 2 of combustion gas led to the lower part of an absorption column (11) is absorbed in an absorption solution that flows downwards from its upper part; the CO 2 -poor combustion gas is removed from the upper part of the absorption column (11); the said absorption solution is led to the upper part of a desorption column (12); the CO 2 is desorbed from the absorption solution led to the upper part of the desorption column (12) to form a gaseous CO 2 concentrate, which is removed from the upper part as the absorption solution flows to the lower part of the column (12), from which it is re-circulated to the upper part of the absorption column (11); the CO 2 concentrate obtained is brought to a high pressure, and most of the concentrate's CO 2 is liquidized. In the process, the CO 2 is transferred from the normal-pressure combustion gas using a nearly reversible absorption and desorption process, to the CO 2 concentrate at a lower pressure at a temperature near to that of the combustion gas being processed, preferably in the temperature range 35-75°C, in such a way that the absorption and desorption processes take place in columns (11, 12) at more or less the same temperature, preferably without importing external heat to the said processes.
    • 本发明涉及从常压燃烧气体生产液态二氧化碳(CO 2)的方法,在该方法中,导致吸收塔(11)下部的燃烧气体的二氧化碳被吸收在向下流动的吸收溶液中 从上部 从吸收塔(11)的上部除去二氧化碳贫乏的燃烧气体。 所述吸收溶液被引导到解吸塔(12)的上部; CO 2从吸收溶液中解吸,导致脱附塔(12)的上部,形成气态CO 2浓缩物,当吸收液流到塔(12)的下部时,CO 2浓缩物从上部被去除, 从其再循环到吸收塔(11)的上部; 所得到的二氧化碳浓缩物达到高压,大部分浓缩物的二氧化碳被液化。 在此过程中,CO 2从常压燃烧气体使用几乎可逆的吸收和解吸过程转移到CO 2浓缩物中,在较低压力下,在接近被处理燃烧气体的温度下,优选在温度范围内 35-75℃,使得吸收和解吸过程在或多或少相同的温度下在柱(11,12)中进行,优选不向所述方法引入外部热量。