专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

WO1993024541A1 PROCESS FOR PRODUCING POLYOLEFIN 审中-公开
标题翻译：生产聚烯烃的方法
公开(公告)号：WO1993024541A1
公开(公告)日：1993-12-09
申请号：PCT/JP1993000727
申请日：1993-05-28
申请人： IDEMITSU KOSAN COMPANY LIMITED , NAKACHO, Kenji , FUNABASHI, Hideo
发明人： IDEMITSU KOSAN COMPANY LIMITED
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , Y02P20/52 , C08F4/646 , C08F4/6465 , C08F4/649
摘要： A process for producing a polyolefin by polymerizing an olefin in the presence of a catalyst, wherein the catalyst comprises a catalytic system composed of (A) a titanium compound, (B) a compound capable of forming an ionic complex by the reaction with a transition metal compound, (C) an organoaluminum compound, and optionally (D) a nonpolymerizable compound having pi -electrons. This process makes it possible to prepare a highly active catalytic system without the necessity for using a large amount of an organometallic compound and to produce a polyolefin, particulary a linear low-density polyoethylene efficiently.
摘要翻译：一种通过在催化剂存在下聚合烯烃制备聚烯烃的方法，其中催化剂包括催化剂体系，催化体系由（A）钛化合物，（B）能够通过与过渡反应形成离子络合物的化合物金属化合物，（C）有机铝化合物和任选的（D）具有π电子的不可聚合化合物。该方法使得可以制备高活性催化剂体系，而不需要使用大量的有机金属化合物并且有效地制备聚烯烃，特别是线性低密度聚乙烯。

2. 发明申请

WO1995018158A1 PROCESS FOR PRODUCING OLEFIN POLYMER AND ETHYLENE POLYMER 审中-公开
标题翻译：生产烯烃聚合物和乙烯聚合物的方法
公开(公告)号：WO1995018158A1
公开(公告)日：1995-07-06
申请号：PCT/JP1994002251
申请日：1994-12-27
申请人： IDEMITSU KOSAN CO., LTD. , TAZAKI, Toshinori , MACHIDA, Shuji , KAWASAKI, Nobuo , YABUNOUCHI, Nobuhiro , KADOI, Yasunori , TAKEUCHI, Mizutomo , NAKACHO, Kenji , SHIKUMA, Haruo , TANI, Noriyuki
发明人： IDEMITSU KOSAN CO., LTD.
IPC分类号： C08F04/642
CPC分类号： C08F10/02 , C08F4/6392 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/02 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F2500/17 , C08F2500/20 , C08F236/20 , C08F210/14 , C08F2500/14 , C08F212/08 , C08F2500/25
摘要： A process for producing an olefin polymer in an economically quite advantageous manner by polymerizing an olefin in the presence of a polymerization catalyst having a high activity and an excellent ability to effect copolymerization even when the amount of an expensive aluminum compound used as a promoter is reduced; and an ethylene polymer having an excellent moldability and good mechanical properties, heat-sealability and ESCR. The process comprises homo- or copolymerizing an olefin or olefins in the presence of a polymerization catalyst containing a transition metal compound (A) represented by the general formula CpMLx-1 (wherein M represents a group 4 metallic element, etc.; Cp represents a cyclic compound group having a cyclopentadienyl skeleton; L represents a sigma ligand; and x represents the valency of M) and an aluminumoxy compound (B) in such a proportion that the molar ratio, (B)/(A), is in the range of 2 to 500 (in terms of metallic element). The ethylene polymer is a homo- or copolymer of ethylene wherein (a) Mw/Mn ranges from 1.5 to 4 and Mw is 3,000 to 1,000,000; (b) the relationship of W>/=-24.9+2470/T holds between the half-value width (W) of the main peak and the temperature (T) in the compositional distribution curve; (c) the energy of activation of melt flow ranges from 7.5 to 20 kcal/mol; and (d) the density ranges from 0.85 to 0.97 g/cm .
摘要翻译：在具有高活性和优异的共聚能力的聚合催化剂的存在下，即使当用作助催化剂的昂贵的铝化合物的量减少时，通过聚合烯烃的经济上非常有利的方式生产烯烃聚合物的方法 ; 以及具有优异的成型性和良好的机械性能，热封性和ESCR的乙烯聚合物。该方法包括在含有由通式CpMLx-1（其中M表示第4族金属元素等）表示的过渡金属化合物（A）的聚合催化剂存在下使烯烃或烯烃均聚或共聚合; Cp表示具有环戊二烯基骨架的环状化合物基团; L表示σ配体; x表示M的化合价）和铝氧化合物（B）的摩尔比（B）/（A）为2至500（以金属元素计）。乙烯聚合物是乙烯的均聚物或共聚物，其中（a）Mw / Mn为1.5-4，Mw为3,000至1,000,000; （b）在主峰的半值宽度（W）和组成分布曲线中的温度（T）之间，W> / = - 24.9 + 2470 / T的关系成立; （c）熔体流动活化能为7.5至20kcal / mol; 和（d）密度在0.85至0.97g / cm 3之间。

3. 发明申请

WO1995014024A1 TRANSITION METAL COMPOUND, OLEFIN POLYMERIZATION CATALYST, AND PROCESS FOR PRODUCING OLEFIN POLYMER BY USING SAID CATALYST 审中-公开
标题翻译：过渡金属化合物，烯烃聚合催化剂，以及使用催化剂生产烯烃聚合物的方法
公开(公告)号：WO1995014024A1
公开(公告)日：1995-05-26
申请号：PCT/JP1994001939
申请日：1994-11-17
申请人： IDEMITSU KOSAN CO., LTD. , TAKEUCHI, Mizutomo , NAKACHO, Kenji , ABIKO, Toshiya , TAZAKI, Toshinori , KADOI, Yasunori
发明人： IDEMITSU KOSAN CO., LTD.
IPC分类号： C07F07/28
CPC分类号： C07F17/00 , C08F4/61912 , C08F4/6192 , C08F10/00
摘要： A transition metal compound useful as a component of an olefin polymerization catalyst, a highly active olefin polymerization catalyst containing the above compound, and an efficient process for producing an olefin polymer with a reduced content of residual metals by using the above catalyst. The transition metal compound is one having as a pi -ligand an indenyl group having on the 5-membered ring side thereof at least one substituted other than the one bonded to the transition metal element. The polymerization catalyst contains (A) the above metal compound, (B) at least one member selected from (a) an organoboron compound, (b) aluminoxane and (c) an ionic compound comprising a noncoordinating anion and a cation, and if necessary (C) a Lewis acid. Various olefin polymers can be produced economically and efficiently by homo- or copolymerizing an olefin in the presence of the above catalyst.
摘要翻译：可用作烯烃聚合催化剂组分的过渡金属化合物，含有上述化合物的高活性烯烃聚合催化剂，以及通过使用上述催化剂制备残留金属含量降低的烯烃聚合物的有效方法。过渡金属化合物是具有与在过渡金属元素上键合的化合物以外的至少一个取代基在其5元环侧上具有吡啶基和茚基的化合物。聚合催化剂含有（A）上述金属化合物，（B）选自（a）有机硼化合物，（b）铝氧烷和（c）包含非配位阴离子和阳离子的离子化合物的至少一种，如果需要（C）路易斯酸。各种烯烃聚合物可以通过在上述催化剂存在下使烯烃均聚或共聚而经济有效地制备。

4. 发明申请

WO1994004578A1 PROCESS FOR PRODUCING POLYOLEFIN 审中-公开
标题翻译：生产聚烯烃的方法
公开(公告)号：WO1994004578A1
公开(公告)日：1994-03-03
申请号：PCT/JP1992001071
申请日：1992-08-26
申请人： IDEMITSU PETROCHEMICAL CO., LTD. , NAKACHO, Kenji , TAKAKURA, Yutaka , FUNABASHI, Hideo
发明人： IDEMITSU PETROCHEMICAL CO., LTD.
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , Y10S526/943
摘要： A process for producing polyolefin by polymerizing olefin in the presence of a catalyst comprising a specified transition metal compound, aluminoxane and a specified magnesium compound or a catalyst comprising the above three compounds and an organoaluminum compound. The process serves to improve the polymer powder morphology and facilitate the regulation of the molecular weight distribution. Further it can provide a high-molecular polyolefin having excellent particle configuration stably and efficiently.
摘要翻译：在包含特定的过渡金属化合物，铝氧烷和特定的镁化合物或包含上述三种化合物的催化剂和有机铝化合物的催化剂存在下，使烯烃聚合制备聚烯烃的方法。该方法用于改善聚合物粉末的形态并促进分子量分布的调节。此外，可以稳定且高效地提供具有优异的粒子构型的高分子量聚烯烃。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式