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1. 发明申请

WO1996005183A1 SACCHARINE DERIVATIVES AND THEIR USE AS HERBICIDES 审中-公开
标题翻译：糖精及其作为除草剂
公开(公告)号：WO1996005183A1
公开(公告)日：1996-02-22
申请号：PCT/EP1995002977
申请日：1995-07-27
申请人： BASF AKTIENGESELLSCHAFT , PLATH, Peter , VON DEYN, Wolfgang , ENGEL, Stefan , KARDORFF, Uwe , NÜBLING, Christoph , KÖNIG, Hartmann , RANG, Harald , GERBER, Matthias , WALTER, Helmut , WESTPHALEN, Karl-Otto
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D275/06
CPC分类号： C07D275/06 , A01N43/80
摘要： The invention concerns saccharine derivatives of the formula (I) in which the substituents are defined as follows: L, M hydrogen, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, chlorine, cyano, methylsulphonyl, nitro or trifluoromethyl; Z hydrogen, C1-C4 alkyl, C3-C8 cycloalkyl, C3-C6 alkenyl, C3-C5 alkinyl, C1-C4 acyl, benzyl or phenyl, wherein any of the phenyl rings may be substituted by halogen or C1-C4 alkyl; R cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tert.-butyl. The invention also concerns salts of such compounds usually used in agriculture.
摘要翻译：糖精的式（I）的衍生物，其中取代基具有以下含义：L，M是氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基，氯，氰基，甲基磺酰基，硝基或三氟甲基; Z是氢，C1-C4烷基，C3-C8环烷基，C3-C6烯基，C3-C5炔基，C1-C4酰基，苄基或苯基，其任选被卤素或C1-C4烷基取代的苯基，R <1>是环丙基，1-甲基环丙基，1- Methylthiocyclopropyl或叔丁基; 化合物（I）的和农业上常用盐。

2. 发明申请

WO1996003391A1 HERBICIDAL PYRAZINE DERIVATIVES 审中-公开
标题翻译：除草剂吡嗪
公开(公告)号：WO1996003391A1
公开(公告)日：1996-02-08
申请号：PCT/EP1995002924
申请日：1995-07-24
申请人： BASF AKTIENGESELLSCHAFT , ENGEL, Stefan , NÜBLING, Christoph , KARDORFF, Uwe , KAST, Jürgen , VON DEYN, Wolfgang , PLATH, Peter , WALTER, Helmut , WESTPHALEN, Karl-Otto , GERBER, Matthias
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07D241/24
CPC分类号： C07D241/24 , A01N43/60 , C07D413/04 , C07D417/04
摘要： Substituted pyrazine derivatives are disclosed of general formula I, wherein n, X and Z have the following meanings: X represents an oxygen or sulphur atom, or a sulphoxide or sulphone group; n is 0, 1 or 2; Z is a group (a), (b), (c) or (d), wherein Y represents oxygen or sulphur, R represents hydrogen, alkyl, alkoxy, a halogen or alkyl halide, and p is 0 or 1; and R , R , R , R and R have the meanings shown in claim 1. Also disclosed are salts of compounds (I) commonly used in agriculture.
摘要翻译：已取代的通式（I）中n，X和Z的含义如下的吡嗪衍生物：X为氧或硫原子或亚砜或砜; n为0，1或2; Z是基团（a），（b）中，（c）或（d），其中Y是氧或硫，R <6>是氢，烷基，烷氧基，卤素或卤代烷基，p表示0或1; 和R <1>，R <2>，R <3>，R <4>和R <5>具有权利要求中给出的含义I; 和landwirtschalftlich化合物（I）的常用盐。

3. 发明申请

WO1996035660A1 SYNTHESIS OF OPTICALLY ACTIVE AMINOINDANOL 审中-公开
标题翻译：合成光学活性氨基茚满醇的
公开(公告)号：WO1996035660A1
公开(公告)日：1996-11-14
申请号：PCT/EP1996001884
申请日：1996-05-07
申请人： BASF AKTIENGESELLSCHAFT , NÜBLING, Christoph , LADNER, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C07C213/08
CPC分类号： C07C213/10 , C07C2602/08
摘要： A process for preparing enantiomer-pure cis1-amino-2-hydroxyindane is characterised in that: (a) racemic trans1-aminoindan-2-ol is reacted according to known processes with acids or acid derivatives having the general formula RCOX, yielding type (A) amides, in which the substituents have the following meanings: R stands for hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl and phenyl, groups that may carry one to three halogen atoms and/or one to three among the following residues: cyano, C1-C6 alkoxy, C1-C6 alkylthio phenyl, phenylthio and phenoxy, the phenyl residues in turn carrying one to three among the following groups: C1-C4 alkyl, C1-C4 alkoxy, halogen, cyano and nitro; X stands for OH, halogen, OR and SR , in which R stands for alkyl C1-C6, phenyl and COR. In a second step (b), a supersaturated solution or melt of racemic amide (A) is blended with seed crystals of an enantiomer, then (c) the precipitated crystals are isolated and the remaining mother liquor or melt is again supersaturated, after separation of racemic amide (A), and blended with seed crystals of the other enantiomer in order to selectively crystallise said enantiomer. Finally (d), the thus obtained enantiomer-pure transamide is reacted according to known methods to yield enantiomer-pure cis1-amino-2-hydroxyindane.
摘要翻译：一种用于对映体纯CK1氨基-2-羟基茚的制备方法，通过通常已知的方法来类型的酰胺（A），其特征在于：a）外消旋反-1氨基茚满-2-醇与酸或通式RCOX的酸衍生物进行反应，其中的取代基具有下列含义：R是氢，C1-C6烷基，C3-C6环烷基和苯基，其中这些基团一至三个卤原子和/或可以带有1-3个下列基团：氰基，C1-C6烷氧基，C1-C6-烷硫基，苯基，苯硫基和苯氧基，其中在依次苯基基团可以带有1-3个下列基团：C1-C4烷基，C1-C4烷氧基，卤素，氰基和硝基。 X是OH，卤素，OR <1>和SR <1>，其中R <1> C1-C6烷基，苯基和COR，B）加入到过饱和溶液或外消旋酰胺（A）与一种对映体的晶种的熔融 c）中沉淀出的结晶分离并在剩余的母液或溶解外消旋酰胺（A熔化后）再次过饱和并与其它对映体，其中，该被选择性地结晶出的晶种混合，D）通过已知的方法获得的对映体纯transAmid到对映体纯进行反应CK1氨基-2-羟基茚。

4. 发明申请

WO2002018560A3 BUTINOL I ESTERASE 审中-公开
公开(公告)号：WO2002018560A3
公开(公告)日：2002-03-07
申请号：PCT/EP2001/010040
申请日：2001-08-30
申请人： BASF AKTIENGESELLSCHAFT , HAUER, Bernhard , FRIEDRICH, Thomas , NÜBLING, Christoph , STÜRMER, Rainer , LADNER, Wolfgang
发明人： HAUER, Bernhard , FRIEDRICH, Thomas , NÜBLING, Christoph , STÜRMER, Rainer , LADNER, Wolfgang
IPC分类号： C12N15/55
摘要： Die Erfindung betrifft neuartige Proteine mit Esterase-Aktivität, insbesondere Butinol I Esterase-Aktivität, aus Pseudomonas glumae, dafür kodierende Nukleinsäuresequenzen, Expressionskassetten, Vektoren und rekombinante Mikroorganismen; Verfahren zur Herstellung dieser Proteine und deren Verwendung zur enzymatischen, insbesondere enantioselektiven enzymatischen Esterhydrolyse oder Umesterung organischer Ester.

5. 发明申请

WO1996023894A1 RACEMATE SEPARATION OF PRIMARY AND SECONDARY HETEROATOM-SUBSTITUTED AMINE BY ENZYME-CATALYSED ACYLATION 审中-公开
标题翻译：解决中小学杂原子取代的胺BY酶催化酰化
公开(公告)号：WO1996023894A1
公开(公告)日：1996-08-08
申请号：PCT/EP1996000234
申请日：1996-01-20
申请人： BASF AKTIENGESELLSCHAFT , BALKENHOHL, Friedhelm , DITRICH, Klaus , NÜBLING, Christoph
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C12P13/02
CPC分类号： C12P41/007 , C12P13/02
摘要： A process for preparing optically active primary and secondary heteroatom-substituted amines from the corresponding racemates is characterised in that (a) a racemic heteroatom-substituted amine is enantioselectively acylated in the presence of a hydrolase with an ester whose acid component bear a fluorine, nitrogen, phosphorus, oxygen or sulphur atom next to the carbonyl carbon atom; (b) the mixture of optically active heteroatom-substituted amine and optically active acylated heteroatom-substituted amine is separated in order to produce an enantiomer of the heteroatom-substituted amine; (c) the other enantiomer of the heteroatom-substituted amine is optionally extracted from the acylated heteroatom-substituted amine by amide cleavage.
摘要翻译：公开了一种用于从相应的外消旋物，其特征在于：a）外消旋杂原子取代的胺与酯其酸组分具有氟，氮，磷，氧制备光学活性伯和仲杂原子取代的胺的方法或邻近羰基碳硫原子，对映选择性的水解酶的存在下酰化，b）分离光学活性的杂原子取代的胺和光学活性的酰化的杂原子取代的胺的混合物和所得到的杂原子取代的胺的因而一种对映体，c）如果需要，从酰化的杂原子取代的胺外，其他杂原子 - 取代的胺对映体获得通过酰胺裂解。

6. 发明申请

WO1995008636A1 RACEMATE CLEAVAGE OF PRIMARY AND SECONDARY AMINES BY ENZYME-CATALYSED ACYLATION 审中-公开
标题翻译：分辨率伯和仲胺BY酶催化酰化
公开(公告)号：WO1995008636A1
公开(公告)日：1995-03-30
申请号：PCT/EP1994003102
申请日：1994-09-16
申请人： BASF AKTIENGESELLSCHAFT , BALKENHOHL, Friedhelm , HAUER, Bernhard , LADNER, Wolfgang , PRESSLER, Uwe , NÜBLING, Christoph
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C12P13/02
CPC分类号： C12P13/02 , C12P41/007
摘要： A process for producing optically active primary and secondary amines from the corresponding racemates is characterised in that (a) a racemic amine is enantioselectively acylated in the presence of a hydrolase with an ester whose acid component bears a fluorine, nitrogen, oxygen or sulphur atom at the proximity of the carbonyl carbon atom; (b) the mixture of optically active amine and optically active acylated amine is separated so that an enantiomer of amine is produced; (c) if desired the other enantiomer of the amine is extracted from the acylated amine by amide cleavage.
摘要翻译：公开了一种用于从相应的外消旋物，其为外消旋胺，其特征在于：a）与酯其酸组分具有邻近氟，氮，氧或硫原子制备旋光的伯胺和仲胺的方法羰基碳在水解酶存在对映选择性酰化，b）分离光学活性胺和光学活性的酰化的胺，因此所述胺的对映体的混合物形式获得，c）如果需要，回收从酰化的胺的胺通过酰胺裂解另一对映体。

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