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1. 发明申请

WO2007130305A3 HAFNIUM COMPLEXES OF CARBAZOLYL SUBSTITUTED IMIDAZOLE LIGANDS 审中-公开
标题翻译：卡巴唑取代的咪唑配基的鳌合复合物
公开(公告)号：WO2007130305A3
公开(公告)日：2008-01-17
申请号：PCT/US2007010200
申请日：2007-04-26
申请人： DOW GLOBAL TECHNOLOGIES INC , BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , PEIL KEVIN P , VOSEJPKA PAUL C
发明人： BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , PEIL KEVIN P , VOSEJPKA PAUL C
IPC分类号： C07F7/00 , C08F4/659 , C08F10/00 , C08F210/00
CPC分类号： C07F7/00 , C07F7/006 , C08F10/00 , C08F110/06 , C08F4/64044
摘要： Hafnium complexes of carbazolyl substituted imidazol ligands and their use as components of olefin polymerization catalyst compositions are disclosed.
摘要翻译：公开了咔唑基取代的咪唑配体的铪络合物及其作为烯烃聚合催化剂组合物的组分的用途。

2. 发明申请

WO2007130307A2 IMPROVED HAFNIUM COMPLEXES OF HETEROCYCLIC ORGANIC LIGANDS 审中-公开
标题翻译：改进的杂环有机配体的高效复合物
公开(公告)号：WO2007130307A2
公开(公告)日：2007-11-15
申请号：PCT/US2007/010225
申请日：2007-04-26
申请人： DOW GLOBAL TECHNOLOGIES INC. , BOONE, Harold, W. , COALTER, Joseph, N., III , FRAZIER, Kevin, A. , IVERSON, Carl, N. , MUNRO, Ian, M. , VOSEJPKA, Paul, C.
发明人： BOONE, Harold, W. , COALTER, Joseph, N., III , FRAZIER, Kevin, A. , IVERSON, Carl, N. , MUNRO, Ian, M. , VOSEJPKA, Paul, C.
IPC分类号： C07F7/00 , C08F10/00 , C08F210/00
CPC分类号： C07F7/00 , C07F7/006 , C08F10/00 , C08F110/14 , C08F4/64144 , C08F2500/20 , C08F2500/03
摘要： Hafnium complexes of heterocyclic organic ligands containing internal orthometallation and their use as components of olefin polymerization catalysts, especially for gas-phase olefin polymerizations, are disclosed.
摘要翻译：公开了含有内部正金属化的杂环有机配体的铪络合物及其作为烯烃聚合催化剂的组分，特别是用于气相烯烃聚合的组分。

3. 发明申请

WO1997044371A1 POLYOLEFIN COMPOSITION WITH MOLECULAR WEIGHT MAXIMUM OCCURING IN THAT PART OF THE COMPOSITION THAT HAS THE HIGHEST COMONOMER CONTENT 审中-公开
标题翻译：具有分子量最大值的聚烯烃组合物在组合物的一部分具有最高的共同体含量
公开(公告)号：WO1997044371A1
公开(公告)日：1997-11-27
申请号：PCT/US1997008206
申请日：1997-05-16
申请人： THE DOW CHEMICAL COMPANY , CADY, Larry, D. , FRYE, Christopher, J. , HOWARD, Philip , KARJALA, Teresa, P. , MADDOX, Peter, J. , MUNRO, Ian, M. , PARIKH, Deepak, R. , PARTINGTON, S., Roy , PEIL, Kevin, P. , SPENCER, Lee , VAN VOLKENBURGH, William, R. , WILLIAMS, Peter, S , WILSON, David, R. , WINTER, J., Mark
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C08F210/16
CPC分类号： C08F210/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65927 , C08F210/16 , C08F2410/02 , C08J5/18 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2207/07 , C08L2308/00 , C08L2314/06 , Y10S526/901 , Y10S526/916 , Y10S526/943 , C08L2666/06 , C08F210/14 , C08F2500/09 , C08F2500/20 , C08L2666/04
摘要： This invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene complex in a single reactor in a process for the polymerization of an alpha -olefin monomer with one or more olefin comonomers, and a molecular weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning factor Cpf which is equal to or greater than 1.10 or molecular weight partitioning factor Mpf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.
摘要翻译：本发明涉及一种聚烯烃共聚物组合物，其在具有一种或多种烯烃共聚单体聚合α-烯烃单体的方法中，在单个反应器中具有茂金属络合物的催化剂，和分子量最大值在50％的组合物，其具有最高重量百分比的共聚单体含量。优选地，组合物具有等于或大于1.10的共聚单体分配因子Cpf或等于或大于1.15的分子量分配因子Mpf。优选的组合物也沿着聚合物主链每1000个碳原子具有至少0.01个长链分支。这些具有反分子工程的组合物具有优异的性能并且由于高分子量与高共聚单体含量和长链支化的缔合而同时存在，因此易于加工。

4. 发明申请

WO2012064630A2 SOLUTION POLYMERIZATION PROCESS AND PROCATALYST CARRIER SYSTEMS USEFUL THEREIN 审中-公开
标题翻译：溶液聚合方法和用于其中的催化剂载体系统
公开(公告)号：WO2012064630A2
公开(公告)日：2012-05-18
申请号：PCT/US2011/059522
申请日：2011-11-07
申请人： DOW GLOBAL TECHNOLOGIES LLC , OSWALD, Thomas , MUNRO, Ian, M.
发明人： OSWALD, Thomas , MUNRO, Ian, M.
IPC分类号： C08F210/16 , C08F4/42 , C08F4/76 , C08F4/52 , B01J31/14
CPC分类号： C08F210/16 , B01J31/0272 , B01J31/1608 , B01J31/1805 , B01J31/183 , B01J31/223 , B01J31/2243 , B01J31/2291 , B01J31/2295 , B01J2531/0244 , B01J2531/0288 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , C08F10/00 , C08F210/18 , C08F2/06 , C08F4/64193 , C08F4/64144 , C08F4/6592 , C08F4/65927 , C08F4/64048 , C08F4/64044 , C08F210/14 , C08F2500/02 , C08F2500/12 , C08F2500/17 , C08F210/06 , C08F236/20 , C08F2500/03 , C08F2500/25
摘要： A procatalyst carrier system which includes one or more paraffinic solvents, one or more paraffin-insoluble procatalysts, and optionally one or more cocatalysts wherein the carrier system is in the form of a slurry is provided. Also provided is a process including selecting one or more paraffin-insoluble organometallic procatalysts; adding the one or more procatalysts to a sufficient quantity of paraffmic solvent to form a slurry of the one or more procatalysts in the paraffmic solvent; introducing one or more first cocatalysts into a polymerization reactor; and introducing the slurry into the polymerization reactor; a reaction product of the process and articles made from the reaction product.
摘要翻译：包括一种或多种石蜡族溶剂，一种或多种石蜡不溶性前催化剂和任选的一种或多种助催化剂的前催化剂载体体系，其中载体体系呈浆料形式。还提供了一种方法，其包括选择一种或多种不含石蜡的有机金属前催化剂; 将一种或多种前催化剂添加到足量的链烷烃溶剂中以形成所述一种或多种前催化剂在链烷烃溶剂中的浆液; 将一种或多种第一助催化剂引入聚合反应器中; 并将淤浆引入聚合反应器中; 该方法的反应产物和由反应产物制成的制品。

5. 发明申请

WO2007130307A3 IMPROVED HAFNIUM COMPLEXES OF HETEROCYCLIC ORGANIC LIGANDS 审中-公开
标题翻译：改进的杂环有机配体的高效复合物
公开(公告)号：WO2007130307A3
公开(公告)日：2008-01-24
申请号：PCT/US2007010225
申请日：2007-04-26
申请人： DOW GLOBAL TECHNOLOGIES INC , BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , VOSEJPKA PAUL C
发明人： BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , VOSEJPKA PAUL C
IPC分类号： C07F7/00 , C08F10/00 , C08F210/00
CPC分类号： C07F7/00 , C07F7/006 , C08F10/00 , C08F110/14 , C08F4/64144 , C08F2500/20 , C08F2500/03
摘要： Hafnium complexes of heterocyclic organic ligands containing internal orthometallation and their use as components of olefin polymerization catalysts, especially for gas-phase olefin polymerizations, are disclosed.
摘要翻译：公开了含有内部正金属化的杂环有机配体的铪络合物及其作为烯烃聚合催化剂的组分，特别是用于气相烯烃聚合的组分。

6. 发明申请

WO2007130306A3 ORTHO-METALLATED HAFNIUM COMPLEXES OF IMIDAZOLE LIGANDS 审中-公开
公开(公告)号：WO2007130306A3
公开(公告)日：2007-11-15
申请号：PCT/US2007/010216
申请日：2007-04-26
申请人： DOW GLOBAL TECHNOLOGIES INC. , BOONE, Harold, W. , COALTER, Joseph, N., III , FRAZIER, Kevin, A. , IVERSON, Carl, N. , MUNRO, Ian, M. , PEIL, Kevin, P. , VOSEJPKA, Paul, C.
发明人： BOONE, Harold, W. , COALTER, Joseph, N., III , FRAZIER, Kevin, A. , IVERSON, Carl, N. , MUNRO, Ian, M. , PEIL, Kevin, P. , VOSEJPKA, Paul, C.
IPC分类号： C07F7/00 , C08F10/00 , C08F210/00 , C08F4/659
摘要： Hafnium complexes of heterocyclic organic imidazol-2-yl ligands containing internal orthometallation and their use as components of olefin polymerization catalyst compositions, especially supported catalyst compositions, are disclosed.

7. 发明申请

WO2013169359A1 POLYOLEFIN POLYMERIZATION PROCESS, SEMI-CRYSTALLINE ETHYLENE-BASED POLYMER MADE THEREFROM, AND ARTICLES MADE FROM THE POLYMER 审中-公开
标题翻译：聚烯烃聚合方法，半结晶乙烯基聚合物及其制备方法
公开(公告)号：WO2013169359A1
公开(公告)日：2013-11-14
申请号：PCT/US2013/031190
申请日：2013-03-14
申请人： DOW GLOBAL TECHNOLOGIES LLC , SLUIJTS, Ludovicus, JC , VAN PUTTEN, Armanda , MUNRO, Ian, M.
发明人： SLUIJTS, Ludovicus, JC , VAN PUTTEN, Armanda , MUNRO, Ian, M.
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/64 , C08F4/6426 , C08F4/6428 , C08F4/64193 , C08F210/14 , C08F2500/08 , C08F2500/12
摘要： A polymerization process comprising (A) polymerizing ethylene and optionally one or more α-olefins in the presence of a catalyst to form a semi-crystalline ethylene-based polymer in at least one reactor; the catalyst comprising an organometallic catalyst thereby forming an ethylene-based polymer composition in the at least one reactor, wherein the catalyst is a metal complex of a polyvalent aryloxyether corresponding to the formula: [Formula I] where M 3 is Ti, Hf or Zr, preferably Zr; Ar 4 is independently in each occurrence a substituted C 9-20 aryl group, wherein the substituents, independently in each occurrence, are selected from the group consisting of alkyl; cycloalkyl; and aryl groups; and halo-, trihydrocarbylsilyl- and halohydrocarbyl- substituted derivatives thereof, with the proviso that at least one substituent lacks co-planarity with the aryl group to which it is attached; T 4 is independently in each occurrence a C 2-20 alkylene, cycloalkylene or cycloalkenylene group, or an inertly substituted derivative thereof; R 21 is independently in each occurrence hydrogen, halo, hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di(hydrocarbyl)amino group of up to 50 atoms not counting hydrogen; R 3 is independently in each occurrence hydrogen, halo, hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino of up to 50 atoms not counting hydrogen, or two R 3 groups on the same arylene ring together or an R 3 and an R 21 group on the same or different arylene ring together form a divalent ligand group attached to the arylene group in two positions or join two different arylene rings together; and R D is independently in each occurrence halo or a hydrocarbyl or trihydrocarbylsilyl group of up to 20 atoms not counting hydrogen, or 2 R D groups together are a hydrocarbylene, hydrocarbadiyl, diene, or poly(hydrocarbyl)silylene group; wherein step (A) is conducted in the presence of from 5 to 20 mmol/m 3 triethylaluminum; and wherein step (A) is conducted in the presence of one or both of the following conditions: (i) from greater than 0:1 to 65:1 molar ratio of triethylaluminum to the catalyst; and (ii) from 0.1:0 to 5:1 molar ratio of triethylauminum to modified methylalumoxane is provided.
摘要翻译：一种聚合方法，包括（A）在催化剂存在下使乙烯和任选的一种或多种α-烯烃聚合以在至少一个反应器中形成半结晶的基于乙烯的聚合物; 所述催化剂包含有机金属催化剂，从而在所述至少一个反应器中形成乙烯基聚合物组合物，其中所述催化剂是对应于下式的多价芳氧基醚的金属络合物：[式I]其中M3是Ti，Hf或Zr，优选Zr; Ar 4在每次出现时独立地为取代的C 9-20芳基，其中各取代基各自独立地选自烷基; 环烷基; 和芳基; 和卤代，三烃基甲硅烷基和卤代烃基取代的衍生物，条件是至少一个取代基与其所连接的芳基缺乏共平面性; T4各自独立地为C2-20亚烷基，亚环烷基或环亚烯基或其惰性取代的衍生物; R21各自独立地为氢，卤素，烃基，三烃基甲硅烷基，三烃基甲硅烷基烃基，烷氧基或二（烃基）氨基，最多不含氢的50个原子; R3各自独立地为氢，卤素，烃基，三烃基甲硅烷基，三烃基甲硅烷基烃基，烷氧基或氨基，最多不超过50个氢原子，或同一亚芳基上的两个R3基团或相同或不同的R3和R21基团亚芳基环一起形成在两个位置连接到亚芳基上的二价配体基团或将两个不同的亚芳环连接在一起; 并且RD在每次出现时独立地为卤素或至多20个不计氢的原子的烃基或三烃基甲硅烷基，或2个RD基团一起为亚烃基，烃基，二烯或聚（烃基）亚甲硅基; 其中步骤（A）在5至20mmol / m3三乙基铝的存在下进行; 并且其中步骤（A）在以下条件之一或两者的存在下进行：（i）三乙基铝与催化剂的摩尔比大于0:1至65:1; 和（ii）提供0.1:0至5:1的三乙基铝与改性的甲基铝氧烷的摩尔比。

8. 发明申请

WO2012064630A3 SOLUTION POLYMERIZATION PROCESS AND PROCATALYST CARRIER SYSTEMS USEFUL THEREIN 审中-公开
标题翻译：溶液聚合方法和用于其中的催化剂载体系统
公开(公告)号：WO2012064630A3
公开(公告)日：2012-07-05
申请号：PCT/US2011059522
申请日：2011-11-07
申请人： DOW GLOBAL TECHNOLOGIES LLC , OSWALD THOMAS , MUNRO IAN M
发明人： OSWALD THOMAS , MUNRO IAN M
IPC分类号： C08F210/16 , C08F4/659 , C08F210/18
CPC分类号： C08F210/16 , B01J31/0272 , B01J31/1608 , B01J31/1805 , B01J31/183 , B01J31/223 , B01J31/2243 , B01J31/2291 , B01J31/2295 , B01J2531/0244 , B01J2531/0288 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , C08F10/00 , C08F210/18 , C08F2/06 , C08F4/64193 , C08F4/64144 , C08F4/6592 , C08F4/65927 , C08F4/64048 , C08F4/64044 , C08F210/14 , C08F2500/02 , C08F2500/12 , C08F2500/17 , C08F210/06 , C08F236/20 , C08F2500/03 , C08F2500/25
摘要： A procatalyst carrier system which includes one or more paraffinic solvents, one or more paraffin-insoluble procatalysts, and optionally one or more cocatalysts wherein the carrier system is in the form of a slurry is provided. Also provided is a process including selecting one or more paraffin-insoluble organometallic procatalysts; adding the one or more procatalysts to a sufficient quantity of paraffmic solvent to form a slurry of the one or more procatalysts in the paraffmic solvent; introducing one or more first cocatalysts into a polymerization reactor; and introducing the slurry into the polymerization reactor; a reaction product of the process and articles made from the reaction product.
摘要翻译：提供了包含一种或多种石蜡族溶剂，一种或多种石蜡不溶性前催化剂和任选的一种或多种助催化剂的前催化剂载体体系，其中载体体系呈浆液形式。还提供了一种方法，其包括选择一种或多种不含石蜡的有机金属前催化剂; 将一种或多种前催化剂添加到足量的链烷烃溶剂中以形成所述一种或多种前催化剂在链烷烃溶剂中的浆液; 将一种或多种第一助催化剂引入聚合反应器中; 并将淤浆引入聚合反应器中; 该方法的反应产物和由该反应产物制得的物品。

9. 发明申请

WO2012064630A4 SOLUTION POLYMERIZATION PROCESS AND PROCATALYST CARRIER SYSTEMS USEFUL THEREIN 审中-公开
标题翻译：解决方案聚合方法和方法有效的载体系统
公开(公告)号：WO2012064630A4
公开(公告)日：2012-08-23
申请号：PCT/US2011059522
申请日：2011-11-07
申请人： DOW GLOBAL TECHNOLOGIES LLC , OSWALD THOMAS , MUNRO IAN M
发明人： OSWALD THOMAS , MUNRO IAN M
IPC分类号： C08F210/16 , C08F4/659 , C08F210/18
CPC分类号： C08F210/16 , B01J31/0272 , B01J31/1608 , B01J31/1805 , B01J31/183 , B01J31/223 , B01J31/2243 , B01J31/2291 , B01J31/2295 , B01J2531/0244 , B01J2531/0288 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , C08F10/00 , C08F210/18 , C08F2/06 , C08F4/64193 , C08F4/64144 , C08F4/6592 , C08F4/65927 , C08F4/64048 , C08F4/64044 , C08F210/14 , C08F2500/02 , C08F2500/12 , C08F2500/17 , C08F210/06 , C08F236/20 , C08F2500/03 , C08F2500/25
摘要： A procatalyst carrier system which includes one or more paraffinic solvents, one or more paraffin-insoluble procatalysts, and optionally one or more cocatalysts wherein the carrier system is in the form of a slurry is provided. Also provided is a process including selecting one or more paraffin-insoluble organometallic procatalysts; adding the one or more procatalysts to a sufficient quantity of paraffmic solvent to form a slurry of the one or more procatalysts in the paraffmic solvent; introducing one or more first cocatalysts into a polymerization reactor; and introducing the slurry into the polymerization reactor; a reaction product of the process and articles made from the reaction product.
摘要翻译：提供了一种主催化剂载体体系，其包括一种或多种链烷烃溶剂，一种或多种不对称烷烃的前催化剂，以及任选的一种或多种助催化剂，其中载体体系为浆液形式。还提供了选择一种或多种不对称石蜡的有机金属前催化剂的方法; 将一种或多种前催化剂加入到足量的石蜡溶剂中以在石蜡溶剂中形成一种或多种前催化剂的浆液; 将一种或多种第一助催化剂引入聚合反应器中; 并将浆料引入聚合反应器中; 由反应产物制备的方法和制品的反应产物。

10. 发明申请

WO2007130306A2 ORTHO-METALLATED HAFNIUM COMPLEXES OF IMIDAZOLE LIGANDS 审中-公开
标题翻译：咪唑配位体的金属化铪复合物
公开(公告)号：WO2007130306A2
公开(公告)日：2007-11-15
申请号：PCT/US2007010216
申请日：2007-04-26
申请人： DOW GLOBAL TECHNOLOGIES INC , BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , PEIL KEVIN P , VOSEJPKA PAUL C
发明人： BOONE HAROLD W , COALTER JOSEPH N III , FRAZIER KEVIN A , IVERSON CARL N , MUNRO IAN M , PEIL KEVIN P , VOSEJPKA PAUL C
IPC分类号： C07F7/00 , C08F10/00 , C08F210/00
CPC分类号： C07F7/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F4/659 , C08F4/6411 , C08F2500/03
摘要： Hafnium complexes of heterocyclic organic imidazol-2-yl ligands containing internal orthometallation and their use as components of olefin polymerization catalyst compositions, especially supported catalyst compositions, are disclosed.
摘要翻译：公开了含有内部正金属化的杂环有机咪唑-2-基配位体的铪络合物及其作为烯烃聚合催化剂组合物，特别是负载型催化剂组合物的组分的用途。

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